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Diss Factsheets

Physical & Chemical properties

Boiling point

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Administrative data

Endpoint:
boiling point
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
guideline study with acceptable restrictions

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2011
Report date:
2011

Materials and methods

Test guideline
Qualifier:
according to guideline
Guideline:
OECD Guideline 103 (Boiling point/boiling range)
Deviations:
not specified
GLP compliance:
no
Type of method:
ebulliometer

Test material

Constituent 1
Chemical structure
Reference substance name:
4-tert-butyl-2-(5-tert-butyl-2-oxo-2,3-dihydro-1-benzofuran-3-yl)phenyl 3,5-di-tert-butyl-4-hydroxybenzoate
EC Number:
700-641-2
Cas Number:
1261240-30-5
Molecular formula:
C37H46O5
IUPAC Name:
4-tert-butyl-2-(5-tert-butyl-2-oxo-2,3-dihydro-1-benzofuran-3-yl)phenyl 3,5-di-tert-butyl-4-hydroxybenzoate
Test material form:
solid: crystalline
Details on test material:
CAS No.: 1261240-30-5
Appearance: White crystalline substance
The sample supplied for testing is placed in HDPE container (500 ml) in the amount ca. 500 g. It is stored at laboratory temperature.

Results and discussion

Boiling point
Key result
Decomposition:
yes
Decomp. temp.:
290 °C

Any other information on results incl. tables

THe behaviour of the test sample during measurement was as follows:

(1) At the pressure 101.325 kPa

The boiling point of the sample in the liquid phase was not constant. The sample began to boil at the temperature 331.5°C. During measurement the boiling temperature of tested sample in liquid phase fell gradually from 331.5 to 319.5°C. Simultaneously it was observed that gradual increase of intensity condensed vapour.

(2) At the pressure 6.7 kPa

The boiling point of the sample in the liquid phase was not constant. The sample began to boil at the temperature 293°C. During measurement the boiling temperature of tested sample in liquid phase fell gradually from 293 to 280°C

Simultaneously it was observed that gradual increase of intensity condensed vapour.

The decomposition temperature the tested sample begins approximately about 290°C.

Applicant's summary and conclusion

Conclusions:
From measurement boiling temperature follows:
- the boiling temperature was not constant
- the boiling temperature drop in liquid phase was 12°C at the pressure 101.325 kPa
- the boiling temperature drop in liquid phase was 13°C at the pressure 6.7 kPa
- gradual increase of intensity condensed vapour
The decompostion temperature the tested sample begins approximately about 290°C.