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Physical & Chemical properties

Surface tension

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Reference
Endpoint:
surface tension
Type of information:
experimental study
Adequacy of study:
key study
Study period:
1990-08-15 to 1990-12-13
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.5 (Surface Tension)
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Type of method:
OECD harmonised ring method
Key result
Surface tension:
46.6 mN/m
Temp.:
20 °C
Conc.:
2 mg/L

( a ) Summary 

The surface tension of a saturated test item solution at 20 °C in water was determined to be 46.6 mN/m.

 

(b) presentation of the results including calculation and statistical methods 

I) calibration of the apparatus 

1. measurement:          73.5 mN/m

2. measurement:          73.5 mN/m

3. measurement:          73.5 mN/m

The reference value of water at 20 °C was 72.75 mN/m. Thus the calibration factor was determined to be 0.9898.

 

II) measurement of the test item solution 

The measurement was performed 2 hours after preparation of the test item solution. The concentration of the saturated aqueous solution was approx. 2 mg/mL. The measurement was performed at 20 °C. 

 

1. measurement

2. measurement

3. measurement

Mean

After 5 min

48.7 mN/m

48.4 mN/m

48.6 mN/m

48.6 mN/m

After 10 min

48.5 mN/m

48.7 mN/m

48.6 mN/m

48.6 mN/m

After 15 min

48.5 mN/m

48.7 mN/m

48.6 mN/m

48.6 mN/m

After 20 min

48.5 mN/m

48.8 mN/m

48.6 mN/m

48.6 mN/m

After 25 min

48.5 mN/m

48.7 mN/m

48.6 mN/m

48.6 mN/m

After 30 min

48.5 mN/m

48.7 mN/m

48.6 mN/m

48.6 mN/m

 

The value was corrected using the correction factor of 0.9898 according to Harkins und Jordan" to be 46.6 mN/m.

Conclusions:
The surface tension was determined to be 46.6 mN/m at 20 °C. Thus, the substance was regarded as surface active.
Executive summary:

A study was conducted according to Regulation (EC) No 440/2005 Part A, A.5 to determine the surface tension of an aqueous solution of the test item using the ring method. Therefore a saturated solution of the test substance in ultrapure water was prepared at 2 mg/mL. The solution was allowed to stabilising at the test temperature of 20 °C. The surface tension was determined to be 46.6 mN/m at 20 °C. It was considered that the test item was surface active as the surface tension is below 60 mN/m.

Description of key information

The surface tension was determined to be 46.6 mN/m at 20 °C. Thus, the substance was regarded as surface active (reference 4.10 -1).

Key value for chemical safety assessment

Surface tension:
46.6
in mN/m at 20°C and concentration in mg/L:
2

Additional information

A study was conducted according to Regulation (EC) No 440/2005 Part A, A.5 to determine the surface tension of an aqueous solution of the test item using the ring method (reference 4.10 -1). Therefore a saturated solution of the test substance in ultrapure water was prepared at 2 mg/mL. The solution was allowed to stabilising at the test temperature of 20 °C. The surface tension was determined to be 46.6 mN/m at 20 °C. It was concluded that the test item was surface active as the surface tension is below 60 mN/m.