Registration Dossier
Registration Dossier
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EC number: 203-401-0 | CAS number: 106-47-8
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
Eye Contact:
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at
least 15 minutes. Cold water may be used. Get medical attention.
Skin Contact:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated
clothing and shoes. Cover the irritated skin with an emollient. Cold water may be used.Wash clothing before
reuse. Thoroughly clean shoes before reuse. Get medical attention immediately.
Serious Skin Contact:
Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate
medical attention.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get
medical attention.
Serious Inhalation:
Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or
waistband. If breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth
resuscitation. WARNING: It may be hazardous to the person providing aid to give mouth-to-mouth resuscitation
when the inhaled material is toxic, infectious or corrosive. Seek medical attention.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an
unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight
clothing such as a collar, tie, belt or waistband.
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at
least 15 minutes. Cold water may be used. Get medical attention.
Skin Contact:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated
clothing and shoes. Cover the irritated skin with an emollient. Cold water may be used.Wash clothing before
reuse. Thoroughly clean shoes before reuse. Get medical attention immediately.
Serious Skin Contact:
Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate
medical attention.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get
medical attention.
Serious Inhalation:
Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or
waistband. If breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth
resuscitation. WARNING: It may be hazardous to the person providing aid to give mouth-to-mouth resuscitation
when the inhaled material is toxic, infectious or corrosive. Seek medical attention.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an
unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight
clothing such as a collar, tie, belt or waistband.
Fire-fighting measures
Classes of fires :
B Liquid or melting substances
Suitable extinguishing media :
Water (spray - not splash)
Extinguishing powder
Carbon dioxide
Fight large fire with alcohol resistant foam or water spray.
Instructions :
Seek immediate cover in case of sudden release and raising
of large quantities of dust.
Cool surrounding containers with water spray.
If possible, take container out of dangerous zone.
Shut off sources of ignition.
Stay on upwind side.
Do not allow runoff to get into the sewage system.
Special protective equipment :
Attention! Hazardous decomposition products may occur.
Nitrous gases (nitric oxides)
Hydrogen chloride
Wear self-contained breathing apparatus.
Wear a special tightly sealed suit.
B Liquid or melting substances
Suitable extinguishing media :
Water (spray - not splash)
Extinguishing powder
Carbon dioxide
Fight large fire with alcohol resistant foam or water spray.
Instructions :
Seek immediate cover in case of sudden release and raising
of large quantities of dust.
Cool surrounding containers with water spray.
If possible, take container out of dangerous zone.
Shut off sources of ignition.
Stay on upwind side.
Do not allow runoff to get into the sewage system.
Special protective equipment :
Attention! Hazardous decomposition products may occur.
Nitrous gases (nitric oxides)
Hydrogen chloride
Wear self-contained breathing apparatus.
Wear a special tightly sealed suit.
Accidental release measures
Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container.
Large Spill:
Poisonous solid.
Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water spray to
reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Eliminate all ignition
sources. Call for assistance on disposal.
Large Spill:
Poisonous solid.
Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water spray to
reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Eliminate all ignition
sources. Call for assistance on disposal.
Handling and storage
Precautions:
Keep locked up.. Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk,
evaporate the residue under a fume hood. Ground all equipment containing material. Do not ingest. Do not
breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory
equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid contact with
skin and eyes. Keep away from incompatibles such as oxidizing agents, acids.
Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. Do not store above 24°C (75.2°F).
Keep locked up.. Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk,
evaporate the residue under a fume hood. Ground all equipment containing material. Do not ingest. Do not
breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory
equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid contact with
skin and eyes. Keep away from incompatibles such as oxidizing agents, acids.
Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. Do not store above 24°C (75.2°F).
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- UN2018
Shipping information
- Proper shipping name and description:
- Chloroanilines, solid
- Chemical name:
- 4-Chloroaniline
- Language:
- English
- Labels:
- 6.1 (Toxic Substances)
SpecialProvisionsopen allclose all
Shippingopen allclose all
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- UN2018
Shipping information
- Proper shipping name and description:
- Chloroanilines, solid
- Chemical name:
- p-Chloroaniline
- Labels:
- Required Label(s): 6.1
- Marine pollutant
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- UN2018
Shipping information
- Proper shipping name and description:
- CHLOROANILINE, SOLID
- Chemical name:
- 4-Chloroaniline
- Labels:
- Required Label(s): 6.1
Remarksopen allclose all
SpecialProvisionsopen allclose all
Exposure controls / personal protection
Exposure controls
Evacuate area. Warn affected surroundings.
The hazardous area may only be entered once suitable
protective measures are implemented. Only then can the
hazardous situation be removed.
Wear respiratory protection, eye protection, hand
protection and body protection (see chapter Personal
Protection).
Carefully sweep up, gather and remove. Avoid rising dust.
Afterwards ventilate area and wash spill site.
Endangerment of drinking water and environment:
Prevent escape into water, drainage, sewer, or the ground.
A hazard for drinking water sources when only small
quantities get into groundwater.
Inform the responsible authorities.
Maybe a hazard to the surrounding atmosphere if larger
quantities of the substance escape. Inform the authorities.
Personal Protection
Body protection :
Depending on the risk, wear a tight, long apron and boots
or suitable chemical protection clothing.
Respiratory protection :
In an emergency (e.g.: unintentional release of the
substance) respiratory protection must be worn. Consider
the maximum period for wear.
Respiratory protection: Gas filter A
Colour code: brown
For details on the requirements and the maximum
concentrations for use, consult the "Regeln für den Einsatz
von Atemschutzgeräten" (BGR 190).
Perhaps also necessary for improved protection:
Respiratory protection: Combination filter A - P2 or A - P3,
recommended A - P3
Colour code: brown-white
For details on the requirements and the maximum
concentrations for use, consult the "Regeln für den Einsatz
von Atemschutzgeräten" (BGR 190).
Respiratory protection: insulating device
Use for concentrations above the usage limits for filter
devices, for oxygen concentrations below 17% volume, or
in circumstances which are unclear.
Eye protection :
Sufficient eye protection should be worn.
Wear glasses with side protection.
Hand protection :
Use protective gloves. The glove material must be
sufficiently impermeable and resistant to the substance.
Check the tightness before wear. Gloves should be well
cleaned before being removed, then stored in a well
ventilated location. Pay attention to skin care.
Textile or leather gloves are completely unsuitable.
The following materials are suitable for protective gloves
(Permeation time >= 8 hours):
Butyl rubber - Butyl (0,5 mm)
Fluoro carbon rubber - FKM (0,4 mm)
The times listed are suggested by measurements taken at
22 degree C and constant contact. Temperatures raised
by warmed substances, body heat, etc. and a weakening of
the effective layer thickness caused by expansion can lead
to a significantly shorter breakthrough time.
In case of doubt contact the gloves' manufacturer.
A 1.5-times increase / decrease in the layer thickness
doubles / halves the breakthrough time. This data only
applies to the pure substance. Transferred to mixtures of
substances, these figures should only be taken as an aid
to orientation.
Skin protection :
Skin protection preparations do not protect sufficiently
against the substance. Wear protective gloves.
The skin must be washed with soap and water before breaks
and at the end of work.
Apply fatty skin-care products after washing.
Industrial hygiene :
If at risk of contamination, foods, beverages and other
articles of consumption must not be stored or consumed at
the work areas. Special areas are to be designated for
these purposes.
Avoid contact with skin. Do not allow the substance or its
solution to dry on the skin. In case of contact wash skin.
Avoid contact with eyes. In case of contact rinse the
affected eye(s).
Avoid inhalation of dust.
If it is possible that there has been any contact with the
substance, then do not consume any alcohol even after work.
Avoid contact with clothing. Contaminated clothes must be
exchanged and cleaned carefully.
Before a break it might be necessary to change clothes.
Provide washrooms with showers and if possible rooms with
separate storage for street clothing and work clothing.
Evacuate area. Warn affected surroundings.
The hazardous area may only be entered once suitable
protective measures are implemented. Only then can the
hazardous situation be removed.
Wear respiratory protection, eye protection, hand
protection and body protection (see chapter Personal
Protection).
Carefully sweep up, gather and remove. Avoid rising dust.
Afterwards ventilate area and wash spill site.
Endangerment of drinking water and environment:
Prevent escape into water, drainage, sewer, or the ground.
A hazard for drinking water sources when only small
quantities get into groundwater.
Inform the responsible authorities.
Maybe a hazard to the surrounding atmosphere if larger
quantities of the substance escape. Inform the authorities.
Personal Protection
Body protection :
Depending on the risk, wear a tight, long apron and boots
or suitable chemical protection clothing.
Respiratory protection :
In an emergency (e.g.: unintentional release of the
substance) respiratory protection must be worn. Consider
the maximum period for wear.
Respiratory protection: Gas filter A
Colour code: brown
For details on the requirements and the maximum
concentrations for use, consult the "Regeln für den Einsatz
von Atemschutzgeräten" (BGR 190).
Perhaps also necessary for improved protection:
Respiratory protection: Combination filter A - P2 or A - P3,
recommended A - P3
Colour code: brown-white
For details on the requirements and the maximum
concentrations for use, consult the "Regeln für den Einsatz
von Atemschutzgeräten" (BGR 190).
Respiratory protection: insulating device
Use for concentrations above the usage limits for filter
devices, for oxygen concentrations below 17% volume, or
in circumstances which are unclear.
Eye protection :
Sufficient eye protection should be worn.
Wear glasses with side protection.
Hand protection :
Use protective gloves. The glove material must be
sufficiently impermeable and resistant to the substance.
Check the tightness before wear. Gloves should be well
cleaned before being removed, then stored in a well
ventilated location. Pay attention to skin care.
Textile or leather gloves are completely unsuitable.
The following materials are suitable for protective gloves
(Permeation time >= 8 hours):
Butyl rubber - Butyl (0,5 mm)
Fluoro carbon rubber - FKM (0,4 mm)
The times listed are suggested by measurements taken at
22 degree C and constant contact. Temperatures raised
by warmed substances, body heat, etc. and a weakening of
the effective layer thickness caused by expansion can lead
to a significantly shorter breakthrough time.
In case of doubt contact the gloves' manufacturer.
A 1.5-times increase / decrease in the layer thickness
doubles / halves the breakthrough time. This data only
applies to the pure substance. Transferred to mixtures of
substances, these figures should only be taken as an aid
to orientation.
Skin protection :
Skin protection preparations do not protect sufficiently
against the substance. Wear protective gloves.
The skin must be washed with soap and water before breaks
and at the end of work.
Apply fatty skin-care products after washing.
Industrial hygiene :
If at risk of contamination, foods, beverages and other
articles of consumption must not be stored or consumed at
the work areas. Special areas are to be designated for
these purposes.
Avoid contact with skin. Do not allow the substance or its
solution to dry on the skin. In case of contact wash skin.
Avoid contact with eyes. In case of contact rinse the
affected eye(s).
Avoid inhalation of dust.
If it is possible that there has been any contact with the
substance, then do not consume any alcohol even after work.
Avoid contact with clothing. Contaminated clothes must be
exchanged and cleaned carefully.
Before a break it might be necessary to change clothes.
Provide washrooms with showers and if possible rooms with
separate storage for street clothing and work clothing.
Stability and reactivity
Stable. Combustible. Incompatible with strong oxidizing agents, acids, acid chlorides, acid anhydrides, chloroformates, nitrous acid. May be light sensitive.
Disposal considerations
Hazardous waste according to Waste Catalogue Ordinance
(AVV).
If there is no way of recycling it must be disposed of in
compliance with the respective national and local
regulations.
Collection of small amounts of substance:
Collect in container for toxic, flammable compounds.
Collection vessels must be clearly labelled with a
systematic description of their contents and with the
hazard symbol and the R and S phrases. Store the vessels in
a well-ventilated location. Entrust them to the appropriate
authorities for disposal.
(AVV).
If there is no way of recycling it must be disposed of in
compliance with the respective national and local
regulations.
Collection of small amounts of substance:
Collect in container for toxic, flammable compounds.
Collection vessels must be clearly labelled with a
systematic description of their contents and with the
hazard symbol and the R and S phrases. Store the vessels in
a well-ventilated location. Entrust them to the appropriate
authorities for disposal.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
