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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Explosiveness

Currently viewing:

Administrative data

Endpoint:
explosiveness
Type of information:
experimental study
Adequacy of study:
supporting study
Study period:
2008-12-03 to 2008-12-12
Reliability:
1 (reliable without restriction)
Cross-referenceopen allclose all
Reason / purpose for cross-reference:
reference to same study
Reason / purpose for cross-reference:
reference to other study

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2008
Report date:
2008

Materials and methods

Test guideline
Qualifier:
according to guideline
Guideline:
EU Method A.14 (Explosive properties)
Deviations:
no
Principles of method if other than guideline:
NA
GLP compliance:
not specified

Test material

Constituent 1
Chemical structure
Reference substance name:
Butyllithium
EC Number:
203-698-7
EC Name:
Butyllithium
Cas Number:
109-72-8
Molecular formula:
C4H9Li
IUPAC Name:
butyllithium
Details on test material:
- Name of test material (as cited in study report): n-Butyllithium 90% in hexane
- Lot/batch No.: 145-0

Results and discussion

Small-scale preliminary testsopen allclose all
Parameter:
other: More sensitive to shock than m-dinitrobenzene
Remarks:
migrated information
Remarks on result:
not measured/tested
Parameter:
other: More sensitive to friction than m-dinitrobenzene
Remarks:
migrated information
Remarks on result:
not measured/tested
Parameter:
other: Explosive under influence of flame
Remarks:
migrated information
Remarks on result:
negative (not further specified)
Parameter:
other: Explosive (not specified)
Remarks:
migrated information
Remarks on result:
negative (not further specified)

Any other information on results incl. tables

No remarks

Applicant's summary and conclusion

Interpretation of results:
non explosive
Remarks:
Migrated information
Conclusions:
As the test item “n-Butyl lithium, 90 % in Hexane” was neither shock sensitive nor thermally sensitive it is not considered to present a danger of explosion according to the criteria of the EU classification scheme.
Executive summary:

The explosive properties of “n-Butyl lithium, 90% in hexane” were determined according to EU test method A.14. The test item is neither shock sensitive nor thermally sensitive according to the criteria of EU method A.14. Therefore it is not considered to present a danger of explosion in the sense of the EU classification scheme. All sample preparations for testing had to be performed using inert gas atmosphere (excluding of air) because of the self ignition properties of the material. These special condition could be applied to this OECD-test, which allowed a meaningful determination of this endpoint for n-Butyl lithium 90% in hexane.