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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Flammability

Currently viewing:

Administrative data

Endpoint:
substances / mixtures which in contact with water emit flammable gases
Type of information:
experimental study
Adequacy of study:
weight of evidence
Reliability:
1 (reliable without restriction)
Cross-reference
Reason / purpose for cross-reference:
reference to other study

Data source

Referenceopen allclose all

Reference Type:
other company data
Title:
Unnamed
Year:
2002
Report date:
2002
Reference Type:
review article or handbook
Title:
Haz Mat Data, For First Response, Transportation, Storage, and Security
Author:
Pohanish, R.; Haber, S.
Year:
2004
Bibliographic source:
Second Rev ed Edition, John Wiley and Sons Ltd, March 2004, ISBN: 978-0-4712-7328-8
Reference Type:
review article or handbook
Title:
Prudent Practices in the laboratory Handling and Disposal of Chemicals
Author:
National Research Council (U.S.)
Year:
1995
Bibliographic source:
NATIONAL ACADEMY PRESS Washington, D.C.

Materials and methods

Test guideline
Qualifier:
according to guideline
Guideline:
EU Method A.12 (Flammability (Contact with Water))
Deviations:
not specified

Test material

Constituent 1
Chemical structure
Reference substance name:
Butyllithium
EC Number:
203-698-7
EC Name:
Butyllithium
Cas Number:
109-72-8
Molecular formula:
C4H9Li
IUPAC Name:
butyllithium

Results and discussion

Pyrophoric solids
Test procedure:
ignition time on contact with air
Remarks:
Ignition on contact with air refers to either Pyrophoric solids or Pyrophoric liquids depending on physical state (migrated information).
Remarks on result:
ignition on contact with air (not further specified)
Remarks:
corresponding to 'yes' in migrated source record.
Pyrophoric liquids
Test procedure:
ignition time on contact with air
Remarks:
Ignition on contact with air refers to either Pyrophoric solids or Pyrophoric liquids depending on physical state (migrated information).
Remarks on result:
ignition on contact with air (not further specified)
Remarks:
corresponding to 'yes' in migrated source record.

Applicant's summary and conclusion

Conclusions:
n-Butyl lithium may ignite spontaneously on exposure to air. The substance reacts violently with water and air humidity to form butane and lithium hydroxide.
Executive summary:

n-Butyl lithium may ignite spontaneously on exposure to air. The substance reacts violently with water and air humidity to form butane and lithium hydroxide.