Registration Dossier
Registration Dossier
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EC number: 210-279-2 | CAS number: 611-74-5
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
· General information:
Take affected persons out of danger area and lay down.
Take note of the following instructions:
Immediately remove any clothing soiled by the product.
Symptoms of poisoning may even occur after several hours; therefore medical observation for at
least 48 hours after the accident.
· After inhalation:
In case of unconsciousness place patient stably in the recovery position for transportation.
Supply fresh air or oxygen; call for doctor.
· After skin contact:
Cover wound with a sterile dressing.
Remove contaminated clothing immediately.
Seek medical treatment.
Immediately wash with water and soap and rinse thoroughly.
· After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
· After swallowing:
Do not induce vomiting; call for medical help immediately.
Drink plenty of water and provide fresh air. Call for a doctor immediately.
Take affected persons out of danger area and lay down.
Take note of the following instructions:
Immediately remove any clothing soiled by the product.
Symptoms of poisoning may even occur after several hours; therefore medical observation for at
least 48 hours after the accident.
· After inhalation:
In case of unconsciousness place patient stably in the recovery position for transportation.
Supply fresh air or oxygen; call for doctor.
· After skin contact:
Cover wound with a sterile dressing.
Remove contaminated clothing immediately.
Seek medical treatment.
Immediately wash with water and soap and rinse thoroughly.
· After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
· After swallowing:
Do not induce vomiting; call for medical help immediately.
Drink plenty of water and provide fresh air. Call for a doctor immediately.
Fire-fighting measures
Extinguishing media
· Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· For safety reasons unsuitable extinguishing agents: Water with full jet
· Special hazards arising from the substance or mixture
Formation of toxic gases is possible during heating or in case of fire.
Carbon monoxide and carbon dioxide
Nitrogen oxides (NOx)
· Advice for firefighters
· Protective equipment:
Wear self-contained respiratory protective device.
Wear personal protective equipment.
Do not inhale explosion gases or combustion gases.
· Additional information
Collect contaminated fire fighting water separately. It must not enter the sewage system.
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
· Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· For safety reasons unsuitable extinguishing agents: Water with full jet
· Special hazards arising from the substance or mixture
Formation of toxic gases is possible during heating or in case of fire.
Carbon monoxide and carbon dioxide
Nitrogen oxides (NOx)
· Advice for firefighters
· Protective equipment:
Wear self-contained respiratory protective device.
Wear personal protective equipment.
Do not inhale explosion gases or combustion gases.
· Additional information
Collect contaminated fire fighting water separately. It must not enter the sewage system.
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
Accidental release measures
· Personal precautions, protective equipment and emergency procedures
Wear personal protective equipment. Keep unprotected persons away.
Mount respiratory protective device.
Keep away from ignition sources.
· 6.2 Environmental precautions:
Do not allow product to reach sewage system or any water course.
Inform respective authorities in case of seepage into water course or sewage system.
· Methods and material for containment and cleaning up:
Ensure adequate ventilation.
Do not flush with water or aqueous cleansing agents
Dispose contaminated material as waste according to item Disposal considerations
Pick up mechanically.
Wear personal protective equipment. Keep unprotected persons away.
Mount respiratory protective device.
Keep away from ignition sources.
· 6.2 Environmental precautions:
Do not allow product to reach sewage system or any water course.
Inform respective authorities in case of seepage into water course or sewage system.
· Methods and material for containment and cleaning up:
Ensure adequate ventilation.
Do not flush with water or aqueous cleansing agents
Dispose contaminated material as waste according to item Disposal considerations
Pick up mechanically.
Handling and storage
· Precautions for safe handling Open and handle receptacle with care.
· Information about fire - and explosion protection: Keep ignition sources away - Do not smoke.
Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles:
Store in a cool location.
Store only in unopened original receptacles.
Prevent any seepage into the ground.
· Information about storage in one common storage facility:
Store away from foodstuffs.
Store away from water.
Do not store together with acids.
Do not store together with alkalis (caustic solutions).
· Further information about storage conditions:
Protect from humidity and water.
Protect from heat and direct sunlight.
Store in cool, dry conditions in well sealed receptacles.
Keep container tightly sealed.
· Information about fire - and explosion protection: Keep ignition sources away - Do not smoke.
Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles:
Store in a cool location.
Store only in unopened original receptacles.
Prevent any seepage into the ground.
· Information about storage in one common storage facility:
Store away from foodstuffs.
Store away from water.
Do not store together with acids.
Do not store together with alkalis (caustic solutions).
· Further information about storage conditions:
Protect from humidity and water.
Protect from heat and direct sunlight.
Store in cool, dry conditions in well sealed receptacles.
Keep container tightly sealed.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- None
Shipping information
- Proper shipping name and description:
- None
SpecialProvisionsopen allclose all
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- None
Shippingopen allclose all
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- None
Shippingopen allclose all
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- None
Shippingopen allclose all
Special provisions / remarks
- Remarks:
- GRACE recommends CARGO AIRCRAFT only.
SpecialProvisionsopen allclose all
Exposure controls / personal protection
· Additional information about design of technical facilities: No further data; see item Handling and storage
· Control parameters
· Ingredients with limit values that require monitoring at the workplace: Not required.
· Additional information: Valid lists at time of creation were used as basis.
· Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes and skin.
· Respiratory protection:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer
exposure use self-contained respiratory protective device.
· Recommended filter device for short term use: Combination filter A-P2
· Protection of hands:
Protective gloves.
Avoid direct contact with the chemical/ the product/ the preparation by organisational measures.
Check the permeability prior to each anew use of the glove.
Check the condition of the gloves prior to each use.
The glove material has to be impermeable and resistant to the product/ the substance/ the
preparation.
Use gloves of stable material (e.g. Nitrile) - if necessary tri-coted to improve the wearability.
Preventive skin protection by use of skin-protecting agents is recommended.
After use of gloves apply skin-cleaning agents and skin cosmetics.
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks
of quality and varies from manufacturer to manufacturer.
Nitrile rubber, NBR
46.0.7
Fluorocarbon rubber (Viton)
Recommended thickness of the material: >= 0.4 mm
· Penetration time of glove material
The exact break through time has to be obtained from the manufacturer of the protective gloves and
has to be observed.
For the mixture of chemicals mentioned below the penetration time has to be at least 480 minutes
(Permeation according to EN 374 Part 3: Level 6).
· For the permanent contact in work areas without heightened risk of injury (e.g. Laboratory) gloves made of the following material are suitable:
Nitrile rubber, NBR
Fluorocarbon rubber (Viton)
· For the permanent contact gloves made of the following materials are suitable:
Nitrile rubber, NBR
Fluorocarbon rubber (Viton)
· For the permanent contact of a maximum of 15 minutes gloves made of the following materials are suitable:
Natural rubber, NR
PVC gloves
Butyl rubber, BR
· Not suitable are gloves made of the following materials:
Leather gloves
cloth gloves
· Eye protection:
Tightly sealed goggles
· Body protection: Protective work clothing.
· Control parameters
· Ingredients with limit values that require monitoring at the workplace: Not required.
· Additional information: Valid lists at time of creation were used as basis.
· Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes and skin.
· Respiratory protection:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer
exposure use self-contained respiratory protective device.
· Recommended filter device for short term use: Combination filter A-P2
· Protection of hands:
Protective gloves.
Avoid direct contact with the chemical/ the product/ the preparation by organisational measures.
Check the permeability prior to each anew use of the glove.
Check the condition of the gloves prior to each use.
The glove material has to be impermeable and resistant to the product/ the substance/ the
preparation.
Use gloves of stable material (e.g. Nitrile) - if necessary tri-coted to improve the wearability.
Preventive skin protection by use of skin-protecting agents is recommended.
After use of gloves apply skin-cleaning agents and skin cosmetics.
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks
of quality and varies from manufacturer to manufacturer.
Nitrile rubber, NBR
46.0.7
Fluorocarbon rubber (Viton)
Recommended thickness of the material: >= 0.4 mm
· Penetration time of glove material
The exact break through time has to be obtained from the manufacturer of the protective gloves and
has to be observed.
For the mixture of chemicals mentioned below the penetration time has to be at least 480 minutes
(Permeation according to EN 374 Part 3: Level 6).
· For the permanent contact in work areas without heightened risk of injury (e.g. Laboratory) gloves made of the following material are suitable:
Nitrile rubber, NBR
Fluorocarbon rubber (Viton)
· For the permanent contact gloves made of the following materials are suitable:
Nitrile rubber, NBR
Fluorocarbon rubber (Viton)
· For the permanent contact of a maximum of 15 minutes gloves made of the following materials are suitable:
Natural rubber, NR
PVC gloves
Butyl rubber, BR
· Not suitable are gloves made of the following materials:
Leather gloves
cloth gloves
· Eye protection:
Tightly sealed goggles
· Body protection: Protective work clothing.
Stability and reactivity
· Reactivity No further relevant information available.
· Chemical stability
No decomposition if used according to specifications.
No decomposition if used and stored according to specifications.
· Possibility of hazardous reactions No dangerous reactions known.
· Conditions to avoid
In case of thermal decomposition caused by smouldering and incomplete combustion toxic fumes may be developed.
· Incompatible materials: Protect from contamination.
· Hazardous decomposition products:
Carbon monoxide and carbon dioxide
Nitrogen oxides
· Chemical stability
No decomposition if used according to specifications.
No decomposition if used and stored according to specifications.
· Possibility of hazardous reactions No dangerous reactions known.
· Conditions to avoid
In case of thermal decomposition caused by smouldering and incomplete combustion toxic fumes may be developed.
· Incompatible materials: Protect from contamination.
· Hazardous decomposition products:
Carbon monoxide and carbon dioxide
Nitrogen oxides
Disposal considerations
· 13.1 Waste treatment methods
· Recommendation: Disposal must be made according to official regulations.
· Waste disposal key:
The disposal of the product has to be carried out in accordance with the legal requirements. EWC
waste codes are strictly industry-oriented, therefore waste classification has to be done by the waste
producer.
· Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.
· Recommendation: Disposal must be made according to official regulations.
· Waste disposal key:
The disposal of the product has to be carried out in accordance with the legal requirements. EWC
waste codes are strictly industry-oriented, therefore waste classification has to be done by the waste
producer.
· Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
