Registration Dossier

Data platform availability banner - registered substances factsheets

Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Endpoint:
relative self-ignition temperature (solids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
August 2004
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2004
Report date:
2004

Materials and methods

Test guideline
Qualifier:
according to guideline
Guideline:
EU Method A.16 (Relative Self-Ignition Temperature for Solids)
Version / remarks:
1992
Deviations:
no
GLP compliance:
not specified

Test material

Constituent 1
Chemical structure
Reference substance name:
sodium;2-hexadecylsulfanyl-1H-benzimidazole-5-sulfonate
EC Number:
616-081-6
Cas Number:
743423-33-8
Molecular formula:
C23 H37 N2 Na O3 S2
IUPAC Name:
sodium;2-hexadecylsulfanyl-1H-benzimidazole-5-sulfonate
impurity 1
Chemical structure
Reference substance name:
1-hexadecyl-2-hexadecylsulfanyl-benzimidazole-5-sulfonate sodium salt
Molecular formula:
C39 H69 N2 Na O3 S2
IUPAC Name:
1-hexadecyl-2-hexadecylsulfanyl-benzimidazole-5-sulfonate sodium salt
impurity 2
Chemical structure
Reference substance name:
N,N-dimethylacetamide
EC Number:
204-826-4
EC Name:
N,N-dimethylacetamide
Cas Number:
127-19-5
Molecular formula:
C4H9NO
IUPAC Name:
N,N-dimethylacetamide
impurity 3
Chemical structure
Reference substance name:
Ethyldiisopropylamine
EC Number:
230-392-0
EC Name:
Ethyldiisopropylamine
Cas Number:
7087-68-5
Molecular formula:
C8H19N
IUPAC Name:
N-ethyl-N-isopropylpropan-2-amine
Test material form:
solid: particulate/powder
Remarks:
off-white powder with lumps
Details on test material:
Traces of 1-bromohexadecane

Results and discussion

Relative self-ignition temperature (solids)
Remarks on result:
no self ignition observed under the test conditions

Any other information on results incl. tables

At oven temperatures between 250°C and 315°C, an exothermic effect (< 25°C) was observed. This effect might be due to decomposition and/or reaction but is of no relevance for the selfignition study. No self-ignition of the test substance was observed.

After the experiment, the test substance appeared to have been molten and had been collected in a container placed below the suspended cube. The test substance sample had changed into a black residue (original it was off-white). There was no test Substance left in the Cube itself. The change of colour is an indication for decomposition or reaction.


Applicant's summary and conclusion

Conclusions:
v182675 is not self-ignitable according to the criteria as described in the method A. 16 of EEC-Directive 92.69 EEC.
Executive summary:

The determination of the relative self-ignition temperature of V182675 was performed in accordance with EEC-Directive 92/69 EEC, A. 16 "Relative self-ignition temperature for solids" (1992).

Approximately 8 cm test substance was heated in an oven. The temperatures of the oven and test substance were continuously recorded while the temperature of the oven was increased from about 20°C to 400°C at a rate of 0.5°C/minute. At oven temperatures between 250°C and 315°C, an exothermic effect (< 25°C) was observed. This effect might be due to decomposition and/or reaction but is of no relevance for the selfignition study.

No self-ignition of the test substance was observed.

In conclusion, v182675 is not self-ignitable according to the criteria as described in the method A. 16 of EEC-Directive 92.69 EEC.