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Diss Factsheets

Administrative data

Link to relevant study record(s)

Reference
Endpoint:
explosiveness
Type of information:
experimental study
Adequacy of study:
key study
Study period:
March 05, 2015 - March 09, 2015
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: guideline study (EC A.14.) guideline study, OECD 113 Screening test for thermal stability and stability in air
Qualifier:
according to guideline
Guideline:
EU Method A.14 (Explosive properties)
Deviations:
no
Qualifier:
according to guideline
Guideline:
other: OECD 113
Deviations:
no
GLP compliance:
no
Parameter:
other: Explosive (not specified)
Remarks:
migrated information
Remarks on result:
negative (not further specified)
Remarks:
screening method: differential scanning calorimetry.

The test item was tested as received. No further preliminary treatment such as drying or milling was performed.

Thermal stability

Two DSC measurements in a closed glass crucible with the test item showed an exothermal effect in the temperature range of 330 – 410 °C and 320 – 410 °C in the first and second measurement, respectively. The results of the DSC measurement are summarised in Table1.

Table1: Thermal stability (DSC-measurement)

Ident-No.

Weight [mg]

Final temperature [°C]

Type of effect

Temperature range [°C]

Enthalpy [J/g]

Crucible

34887

11.16

500

Exothermal

330 - 410

103

closed glass crucible

34893

11.03

500

Exothermal

320 - 410

76

closed glass crucible

 

The heat of decomposition was below 500 J/g. Therefore, the main test on explosive properties was not necessary.

Interpretation of results:
non explosive
Remarks:
Migrated information
Executive summary:

The test item has no explosive properties in the sense of the European Commission Regulation (EC) No. 440/2008, Method A.14. Explosive properties. The test item has no explosive properties in the sense of UN Recommendations on the Transport of Dangerous Goods, Manual of Test and Criteria, Appendix 6: Screening Procedures. Due to these results, the test item does not have to be classified as “explosive”, class 1 of the UN Recommendations on the Transport of Dangerous Goods, Manual of test and criteria.

Due to these results, the test item does not have to be classified as “explosive” according to chapter 2.1 of the GHS (CLP) regulations.

Description of key information

The explosiveness of the test item was determined according to the European Commission Regulations (EC) No. 440/2008,
A.14. Explosive properties and according to and OECD test guideline, OECD 113 Screening test for thermal stability and stability in air.
.

Key value for chemical safety assessment

Explosiveness:
non explosive

Additional information

Justification for classification or non-classification

The test item had no explosive properties in the sense of the UN Recommendations on the Transport of Dangerous Goods, Manual of Test and Criteria, Appendix 6: Screening Procedures and in the sense of the EuropeanCommission Regulation (EC) No. 440/2008, Method A.14.