Registration Dossier
Registration Dossier
Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.
The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.
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EC number: 235-101-0 | CAS number: 12068-53-0
Guidance on Safe Use
Administrative data
First-aid measures
General information:
Immediately remove any clothing soiled by the product.
Take note of the following instructions.
After inhalation:
Supply fresh air; consult doctor in case of complaints.
After skin contact:
Generally the product does not irritate the skin.
Immediately wash with water and soap and rinse thoroughly.
If skin irritation occurs, consult a doctor.
After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
After swallowing:
Rinse out mouth and then drink plenty of water.
If symptoms persist consult doctor.
Most important symptoms and effects, both acute and delayed:
No further relevant information available.
Indication of any immediate medical attention and special treatment needed:
No further relevant information available.
Fire-fighting measures
Suitable extinguishing agents:
Use fire extinguishing methods suitable to surrounding conditions.
Special hazards arising from the substance or mixture:
Metal oxide fume.
Advice for firefighters
Protective equipment:
Mount respiratory protective device.
Wear personal protective equipment.
Additional information:
Collect contaminated fire fighting water separately. It must not enter the sewage system.
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
Accidental release measures
Personal precautions, protective equipment and emergency procedures:
Wear protective clothing.
Environmental precautions:
Damp down dust with water spray.
Do not allow to enter into sewers, surface water and/or groundwater.
Keep contaminated washing water and dispose of appropriately.
Do not allow to penetrate the ground/soil.
Methods and material for containment and cleaning up:
Sweep the spill area; avoid raising dust.
Dispose of the material collected according to regulations.
References to other sections:
handling and storage
disposal information
Handling and storage
Precautions for safe handling:
Keep receptacles tightly sealed.
Prevent formation of dust.
Provide suction extractors if dust is formed.
Use appropriate industrial vacuum cleaners or central vacuum systems for dust removal.
Any unavoidable deposit of dust must be regularly removed.
Prevent static electric sparks.
Information about fire and explosion protection:
The product is not flammable.
Earth container to avoid electric sparks, especially in contact with flammable substances.
Requirements to be met by storerooms and receptacles:
Prevent any seepage into the ground.
Information about storage in one common storage facility:
Store away from foodstuffs.
Further information about storage conditions:
Store in dry conditions.
Specific end use(s):
No further relevant information available.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- UN3077
Shipping information
- Proper shipping name and description:
- 3077 ENVIRONMENTALLY HAZARDOUS
SUBSTANCE, SOLID, N.O.S. (zinc aluminium oxide)
- Labels:
- Symbol (fish and tree), 9
SpecialProvisionsopen allclose all
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- -
Shippingopen allclose all
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- UN3077
Shipping information
- Proper shipping name and description:
- ENVIRONMENTALLY HAZARDOUS
SUBSTANCE, SOLID, N.O.S. (zinc aluminium oxide),
MARINE POLLUTANT - Chemical name:
- -
- Labels:
- Symbol (fish and tree), 9
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- UN3077
Shipping information
- Proper shipping name and description:
- ENVIRONMENTALLY HAZARDOUS
SUBSTANCE, SOLID, N.O.S. (zinc aluminium oxide) - Chemical name:
- -
- Labels:
- Symbol (fish and tree), 9
Remarksopen allclose all
Additional transport information
Additional information
- Special provisions / remarks / other:
- ADR
· Excepted quantities (EQ): E1
· Limited quantities (LQ): 5 kg
· Transport category: 3
· Tunnel restriction code: E
· IATA
· Remarks: UN No. 3077
Special provisions: A97, A158, A179
Danger Code: 9L
UN packing group: III
PASSENGER AND CARGO AIRCRAFT:
Excepted Quantities: E1
Packing instruction: 956
max. net quantity per package: 400 kg
Limited Quantity:
Packing instruction: Y956
max. net quantity per package: 30 kg G
CARGO AIRCRAFT:
Packing instruction: 956
max. net quantity per package: 400 kg
GRACE recommends CARGO AIRCRAFT only.
Exposure controls / personal protection
Ingredients with limit values that require monitoring at the workplace:
1344-28-1 Aluminium oxide
WEL (Great Britain) Long-term value: 10* 4** mg/m³
*inhalable dust **respirable dust
DNELs:
1344-28-1 Aluminium oxide
Oral DNEL(long-systemic) 3.29 mg/kg bw /day (General population)
Inhalative DNEL(long-local) 15.63 mg/m³ (Worker)
1314-13-2 Zinc oxide
Oral DNEL(long-systemic) 0.83 mg/kg bw /day (General population) ECHA 2011
Dermal DNEL(long-systemic) 83 mg/kg bw /day (General population) ECHA 2011
83 mg/kg bw /day (Worker) ECHA 2011
Inhalative DNEL(long-systemic) 2.5 mg/m³ (General population) ECHA 2011
5 mg/m³ (Worker) ECHA 2011
PNECs:
1344-28-1 Aluminium oxide
PNEC 74.9 mg/l (aqua-freshwater)
20 mg/l (Sewage Treatment Plant)
1314-13-2 Zinc oxide
PNEC 20.6 mg/l (aqua-freshwater) ECHA 2011
6.1 mg/l (aqua-marine water) ECHA 2011
35.6 mg/kg (soil) ECHA 2011
117.8 mg/kg (sediment (freshwater) ECHA 2011
56.5 mg/kg (sediment (marine water) ECHA 2011
52 mg/l (Sewage Treatment Plant) ECHA 2011
Exposure controls / Personal protective equipment
General protective and hygienic measures:
The usual precautionary measures are to be adhered to when handling chemicals.
Respiratory protection:
If the WEL value is exceeded.
Recommended filter device for short term use: Filter P2
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device.
Protection of hands:
Protective gloves:
Check the permeability prior to each new use of the glove.
Wear gloves for protection against mechanical hazards according to EN 388.
Use gloves of stable material (e.g. Nitrile) - if necessary tricoted to improve the wearability.
Preventive skin protection by use of skin-protecting agents is recommended.
After use of gloves apply skin-cleaning agents and skin cosmetics.
Material of gloves:
EN 388: Minimum requirements for efficiency level 1 for all groups.
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer.
Butyl rubber, BR
Nitrile rubber, NBR
Leather gloves
Recommended thickness of the material: ≥ 0.35 mm
Penetration time of glove material:
EN 420: Minimum requirements for efficiency level 1 for all groups.
For the mixture of chemicals mentioned below the penetration time has to be at least 480 minutes
(Permeation according to EN 374 Part 3: Level 6).
Not suitable are gloves made of the following materials:
Strong material gloves (leather, cloth)
Eye protection:
Safety glasses.
Body protection:
Protective work clothing
Stability and reactivity
Chemical stability:
No decomposition if used according to specifications.
Possibility of hazardous reactions:
No dangerous reactions known.
Conditions to avoid:
In case of thermal decomposition caused by smouldering and incomplete combustion toxic fumes may be developed.
Incompatible materials:
Protect from contamination.
Hazardous decomposition products:
Toxic metal oxide smoke
Disposal considerations
Precautions for disposal / Waste treatment methods
Recommendation:
Disposal must be made according to official regulations.
Waste disposal key:
The disposal of the product has to be carried out in accordance with the legal requirements. EWC waste codes are strictly industry-oriented, therefore waste classification has to be done by the waste producer.
Uncleaned packaging
Recommendation:
Disposal must be made according to official regulations.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
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