Registration Dossier

Administrative data

First-aid measures

Emergency measure - Inhalation: Remove to fresh air if effects occur. Consult a physician.
Emergency measure - Eyes: Wash immediately and continously with flowing water for at
least 30 minutes. Remove contact lenses after the first 5
minutes and continue washing. Obtain prompt medical
consultation, preferably an ophtalmologist.
Emergency measure - Skin: Immediately wash thoroughly any size exposure with non-
abrasive soap and large quantities of water for 30 minutes
while removing contaminated clothing and shoes. Destroy
contaminated leather items such as shoes, belts and
watchbands.
Emergency measure - Ingestion: If swallowed, seek medical attention. Do not induce
vomitting unless directed to do so by a medical personnel.

Fire-fighting measures

Recommended extinguishing agent: Carbon dioxide, dry chemical. Dry foundry sand. Avoid using
water which may not be effective in extinguishing fire.

Product arising from burning: NOx, CO, CO2, H2O, TiO2

Product determined by test: N

Protective equipment: Wear positive-pressure self contained breathing equipment
and protective fire fighting clothing (including fire
fighting helmet, coat, trousers, boots and gloves)

Accidental release measures

Emergency measures in case of spillage: Cover and soak up with a suitable absorbent material.
Dispose of according to applicable regulations. The
substance should be neutralised with isopropanol. Incinerate
under controlled conditions in accordance with all local
and national laws and regulations. Do not dump into sewers,
on the ground or into any body of water.


Contain and sweep up material. Collect in suitable and
properly labelled containers.


To minimise exposure of workers during clean up, the use of
industry vacuum cleaners is recommended.


Empty containers are shipped back to the supplier for refill
.

Handling and storage

Handling: Do not get in eyes, on skin or on clothing. Avoid prolonged
or repeated contact with skin. Wash thoroughly after
handling. Avoid breathing vapour. Use with adequate
ventilation. Keep container tightly closed.

Storage: Store in a dry place. Protect from atmospheric moisture.
Store in accordance with good manufacturing practices.

Packaging of the substance and or preparation: Material will be shipped in C-430 tanks, which are 208 cm x
107cm x 122cm, have a 2.71 cubic metric shipping cube, a
tare weight of 635-816kg and hold 1465L (ca. 90% full). A C-
430 full of the preparation containing the substance at <5%
will therefore roughly weigh 1800-2100kg.

Transport information

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Marine transport (IMDG)

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Air transport ICAO/IATA

Remarks
Transport code: UN 1759
Transport: ROAD & RAIL

Proper Shipping Name: CORROSIVE SOLIDS, N.O.S.

Technical Name: TITANIUM METALLORGANIC COMPOUND

Hazard Class: 8 ID Number: UN1759 Packaging group: PG III


OCEAN

Proper Shipping Name: CORROSIVE SOLIDS, N.O.S.

Technical Name: TITANIUM METALLORGANIC COMPOUND

Hazard Class: 8 ID Number: UN1759 Packaging group: PG III

EMS Number: F-A, S-B


AIR

Proper Shipping Name: CORROSIVE SOLIDS, N.O.S.

Technical Name: TITANIUM METALLORGANIC COMPOUND

Hazard Class: 8 ID Number: UN1759 Packaging group: PG III

Cargo Packaging instructions: 822


INLAND WATERWAYS

Proper Shipping Name: CORROSIVE SOLIDS, N.O.S.

Technical Name: TITANIUM METALLORGANIC COMPOUND

Hazard Class: 8 ID Number: UN1759 Packaging group: PG III
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Exposure controls / personal protection

Stability and reactivity

Danger other than fire: Avoid exposure to water or moist air. Deactivates in contact
with water. Should be stored under an inert atmosphere.

Incompatibility

Water,other protic solvents, oxidizing agents

Chemical reaction with water: The substance breaks down immediately in contact with water
or moisture.

Dust explosion: Not applicable

Dust explosion determined by test: N

Disposal considerations

Industry - Possibility of recovery/recycling: After use the substance cannot be traced in the final
product as such, therefore cannot be recycled or recovered.

Industry - Possibility of neutralisation: The substance should be neutralised with isopropanol.

Industry - Possibility of destruction: controlled discharge: The substance should not be disposed of by landfill

Industry - Possibility of destruction - incineration: 661 Incineration: Incineration with flue gas scrubbing

Industry - Possibility of destruction - water purification: The substance should not be discharged directly to the
sewage system or aqueous environment.

Industry - Possibility of destruction - other: Not applicable

Public at large - Possibility of recovery/recycling: Not applicable

Public at large - Possibility of neutralisation: Not applicable

Public at large - Possibility of destruction: controlled discharge: Not applicable

Public at large - Possibility of destruction - incineration: Not applicable

Public at large - Possibility of destruction - water purification: Not applicable

Public at large - Possibility of destruction - others: Not applicable