Registration Dossier

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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

First-aid measures

General Information:
Seek medical assistance if discomfort continues. First aider needs to protect himself.
Immediately remove contaminated clothing.

After Inhalation:
If breathing stops immediately apply artificial respiration. Call a physician immediately.

After contact with skin:
In case of contact with skin, clean with soap and plenty of water. Call a physician immediately.

After contact with eyes:
Rinse the affected eye with plenty of water, at the same time keep the unaffected eye well protected. Call a physician immediately.

After ingestion:
Give water to drink. Seek medical advice immediately and show the safety data sheet or label.

Most important symptoms and effects, both acute and delayed:
Aromatic nitro compounds: methaemoglobinaemia, cyanosis

Indication of any immediate medical attention and special treatment needed:
Treat symtomatically.

Fire-fighting measures

Suitable extinguishing media:
water spray jet
foam

Extinguishing media that must not be used for safety reasons:
Full water jet


Special hazards arising from the substance:
In case of fires hazardous combustion gases are formed:
carbon monoxide
carbon dioxide
nitrogene oxides
hydrogen chloride

Advice for firefighters:
Use self-contained breathing apparatus.
Wear protective equipment.

Accidental release measures

Personal precautions, protective equipment and emergency procedures:
Avoid contact with substance. Wear suitable personal protective equipment.

Environmental precautions:
Do not allow entry to drains, water courses or soil.

Methods and material for containment and cleaning up:
Take up mechanically.
Avoid dust formation and electrical charging (sparking) because dust explosion might occur.
When picked up, treat material as prescribed under heading "Disposal considerations".

Handling and storage

Advice on safe handling:

Avoid dust formation and inhalation and contact with substance.

Advice on protection against fire and explosion:
Take precautionary measures against electrostatic charges - earthing necessary during loading operations.
Keep away from sources of ignition
Dust can form an explosive mixture with air.

Further information on storage conditions
Keep container tightly closed and locked up.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
2237
Shippingopen allclose all
Labels:
6.1, environmentally hazardous substance
SpecialProvisionsopen allclose all

Inland waterway transport (UN RTDG/ADN(R))

UN number:
2237
Shippingopen allclose all
Remarksopen allclose all

Marine transport (UN RTDG/IMDG)

UN number:
2237
Shipping information
Proper shipping name and description:
Chloronitroanilines
Chemical name:
4-chlor-2-nitroaniline
Labels:
6.1, Marine Pollutant
Marine pollutant
Remarksopen allclose all

Air transport (UN RTDG/ICAO/IATA)

UN number:
2237
Shipping information
Proper shipping name and description:
Chloronitroanilines
Chemical name:
4-chlor-2-nitroaniline
Labels:
6.1, environmentally hazardous substance
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Control parameters:
Exposure limit values are not available.
DNEL/DMEL values are not available
PNEC values are not available.

Exposure controls:
Observe the usual precautions for handling chemicals.
Wash hands before breaks and after work.
Use barrier skin cream.
Remove soiled or soaked clothing immediately and clean thoroughly before using again.

Respiratory protection:
Wear dust mask when dusts are generated

Hand protection :
Nitrile rubber gloves.
Minimum breakthrough time (glove): not determined
Minimum thickness (glove): not determined
Observe the information of the glove manufacturers on
permeability and breakthrough times and other workplace requirements

Eye protection :
safety glasses

Body protection :
working clothes

Stability and reactivity

Chemical stability:
stable

Possibility of hazardous reactions:
When handled and stored appropriately no dangerous reactions are known.
Violent reactions are possible with bases, strong oxidizing agents, acid anhydrides and acid halides.

Conditions to avoid:
strong heating.

Incompatible materials:
Not known.

Disposal considerations