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The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Auto flammability

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Administrative data

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Endpoint:
auto-ignition temperature (liquids)
Type of information:
experimental study
Adequacy of study:
supporting study
Study period:
19-21 Feb 2001
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
other: GLP guideline study with the substance in a liquid state, purity 353 g/kg.
Qualifier:
according to guideline
Guideline:
EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
Principles of method if other than guideline:
Auto flammabiiity apparatus (ISL V07903) built in accordance with NF T 20-037 and DIN 51 794 standards.
GLP compliance:
yes
Auto-ignition temperature:
340 °C
Atm. press.:
>= 1 004 - <= 1 010 hPa

Room temperature: 20 °C.

Results:

Test series no.

Barometric pressure [hPa]

Self ignition temperature [°C]

Injection volume [mL]

Time lag [s]

1

1004-1006

342

150

100

2

1010

346

150

120

3

1010

346

150

157

The result was rounded down to 340 °C.

Endpoint:
relative self-ignition temperature (solids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
27 Jul - 14 Aug 2015
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
test procedure in accordance with national standard methods with acceptable restrictions
Principles of method if other than guideline:
HCR-H032-1 Chemical solid substance relative self-ignition temperature measurement instrument according to GB/T 21756-2008 method
GLP compliance:
no
Relative self-ignition temperature:
> 400 °C
Remarks on result:
no self ignition observed under the test conditions

Description of key information

> 400 °C (solid state)

340 °C (aqueous solution)

Key value for chemical safety assessment

Additional information

No self-heating was observed for the substance in a solid state.

The auto-ignition temperature of the aqueous solution of the substance (353 g/kg solution in water) was determined according to EU Method A.15.