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Physical & Chemical properties

Auto flammability

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Reference
Endpoint:
auto-ignition temperature (liquids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
The study was conducted between 8 December 2016 and 13 July 2017
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: The study is considered to be a reliability 1 as it has been conducted according to EU Method A.15 and in compliance with GLP.
Qualifier:
according to guideline
Guideline:
EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
GLP compliance:
yes
Specific details on test material used for the study:
Identification: FRET 11-0078
Appearance/Physical state: Clear colorless liquid
Storage conditions: Approximately 4 °C in the dark
Auto-ignition temperature:
252 °C
Atm. press.:
>= 100.7 - <= 102 Pa

Results of the auto-ignition temperature determination are shown in the following table:

Temperature (ºC)

Clean Flask (Yes/No)

Volume (µL)

Ignition Delay (s)

Observations

200

Yes

70

>300

No ignition. Grey fumes were emitted.

250

Yes

70

>300

No ignition. Grey fumes were emitted.

300

Yes

70

5

An orange flame. Grey fumes were emitted.

290

No

70

10

An orange/yellow flame. Grey fumes were emitted.

280

No

70

15

An orange/yellow flame. Grey fumes were emitted.

270

No

70

28

An orange/yellow flame. Grey fumes were emitted.

260

No

70

>300

No ignition. Grey fumes were emitted.

266

Yes

70

>300

No ignition. Grey fumes were emitted.

268

Yes

70

>300

No ignition. Grey fumes were emitted.

268

Yes

200

21

An orange flame. Grey fumes were emitted.

266

Yes

200

19

An orange flame. Grey fumes were emitted.

260

Yes

200

28

An orange flame. Grey fumes were emitted.

254

Yes

200

46

An orange flame. Grey fumes were emitted.

248

Yes

200

>300

No ignition. Grey fumes were emitted.

252

Yes

200

47

An orange flame. Grey fumes were emitted.

250

Yes

200

>300

No ignition. Grey fumes were emitted.

250

Yes

400

>300

No ignition. Grey fumes were emitted.

250

Yes

600

>300

No ignition. Grey fumes were emitted.

250

Yes

800

>300

No ignition. Grey fumes were emitted.

250

Yes

1000

>300

No ignition. Grey fumes were emitted.

Room temperature: 19 to 20 °C
Atmospheric pressure: 100.7 to 102.0 kPa

The test item has been determined to have an auto-ignition temperature of 252 ± 5 °C.

Conclusions:
The substance FRET 11-0078 has a self-ignition temperature of 252 ± 5 °C according to EU Method A.15 in compliance with GLP.
Executive summary:

The substance FRET 11-0078 has a self-ignition temperature of 252 ± 5 °C according to EU Method A.15.

Description of key information

The substance FRET 11-0078 has a self-ignition temperature of 252 ± 5 °C according to EU Method A.15.

Key value for chemical safety assessment

Autoflammability / Self-ignition temperature at 101 325 Pa:
252 °C

Additional information