Registration Dossier
Registration Dossier
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EC number: 212-591-4 | CAS number: 829-85-6
Guidance on Safe Use
Administrative data
First-aid measures
In case of inhalation
- Move to fresh air.
- Get medical attention immediately if symptoms occur.
In case of skin contact
- Use appropriate protective equipment when treating a contaminated person.
In case of eye contact
- Rinse with running water whilst keeping the eyes wide open.
In case of ingestion
- Do NOT induce vomiting.
- Rinse mouth with water.
Most important symptoms and effects, both acute and delayed
Effects
- No hazards to be specially mentioned.
Repeated or prolonged exposure
- slight irritation
- Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhoea.
Symptoms
- At high concentrations:
- slight irritation
- Redness
- Redness of the conjunctiva
Indication of any immediate medical attention and special treatment needed
Notes to physician
- When symptoms persist or in all cases of doubt seek medical advice.
Fire-fighting measures
Extinguishing media
Suitable extinguishing media
- Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Special hazards arising from the substance or mixture
- Under fire conditions:
- Will burn
- On combustion, toxic gases are released.
Advice for firefighters
Special protective equipment for firefighters
- In the event of fire, wear self-contained breathing apparatus.
Specific fire fighting methods
- Cool containers/tanks with water spray.
- Do not use a solid water stream as it may scatter and spread fire.
Further information
- Standard procedure for chemical fires.
- Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
- Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.
Accidental release measures
Personal precautions, protective equipment and emergency procedures
- For further information refer to section 8 "Exposure controls/personal protection".
Environmental precautions
- Stop the leak. Turn leaking containers leak-side up to prevent the escape of liquid.
- Contain the spilled material by bunding.
- Do not let product enter drains.
- Do not allow uncontrolled discharge of product into the environment.
Methods and materials for containment and cleaning up
- Stop leak if safe to do so.
- Sweep up and shovel into suitable containers for disposal.
- Keep in properly labelled containers.
- Keep in suitable, closed containers for disposal.
- Wash non-recoverable remainder with large amounts of water.
- Soak up with inert absorbent material.
- Decontaminate tools, equipment and personal protective equipment in a segregated area.
- Dispose of in accordance with local regulations.
- Never return spills in original containers for re-use.
Handling and storage
Precautions for safe handling
Hygiene measures
- Handle in accordance with good industrial hygiene and safety practice.
- Wash hands before breaks and at the end of workday.
- When using do not eat, drink or smoke.
- Eye wash bottles or eye wash stations in compliance with applicable standards.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- 2845
Shippingopen allclose all
SpecialProvisionsopen allclose all
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Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- 2845
Shipping information
- Proper shipping name and description:
- Pyrophoric liquids, organic, n.o.s.
- Chemical name:
- Diphenylphosphine
- Marine pollutant
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- 2845
Shipping information
- Proper shipping name and description:
- Pyrophoric liquid, organic, n.o.s.
- Chemical name:
- Diphenylphosphine
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Additional transport information
Additional information
- Special provisions / remarks / other:
- DOT (US)
UN number: 2845 Class: 4.2 Packing group: I
Proper shipping name: Pyrophoric liquids, organic, n.o.s. (Diphenylphosphine)
Poison Inhalation Hazard: No
Exposure controls / personal protection
Exposure controls
Control measures
Engineering measures
- Ensure adequate ventilation.
- Apply technical measures to comply with the occupational exposure limits.
Individual protection measures
Respiratory protection
- Keep in a well-ventilated place.
Hand protection
- Take note of the information given by the producer concerning permeability and break through times, and of special workplace conditions (mechanical strain, duration of contact).
- Impervious gloves
Eye protection
- If splashes are likely to occur, wear:
- Chemical resistant goggles must be worn.
Skin and body protection
- If splashes are likely to occur, wear:
- Protective suit
Hygiene measures
- Handle in accordance with good industrial hygiene and safety practice.
- Wash hands before breaks and at the end of workday.
- When using do not eat, drink or smoke.
- Eye wash bottles or eye wash stations in compliance with applicable standards.
Environmental exposure controls
- Dispose of rinse water in accordance with local and national regulations.
This substance is handled under Strictly Controlled Conditions in accordance with REACH regulation Article 17(3) for on-site isolated intermediates and, in case the substance is transported to other sites for further processing, the substance should be handled at these sites under the Strictly Controlled Conditions as specified in REACH regulation Article 18(4). Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at each manufacturing site. Written confirmation of the application of Strictly Controlled Conditions has been received from every affected distributor and downstream manufacturer/user of the registrant’s intermediate.
Stability and reactivity
Reactivity: The substance or mixture is pyrophoric with the category 1.
Stability: Decomposes upon contact with air. Stable under recommended storage conditions.
Incompatibility: Strong oxidizing agents, air
Disposal considerations
Product Disposal
- The Company encourages the recycle, recovery and reuse of materials, where permitted. If disposal is necessary, The Company recommends that organic materials, especially when classified as hazardous waste, be disposed of by thermal treatment or incineration at approved facilities. All local and national regulations should be followed.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
