Registration Dossier

Diss Factsheets

Administrative data

First-aid measures

In case of inhalation

- Move to fresh air.

- Get medical attention immediately if symptoms occur.

In case of skin contact

- Use appropriate protective equipment when treating a contaminated person.

In case of eye contact

- Rinse with running water whilst keeping the eyes wide open.

In case of ingestion

- Do NOT induce vomiting.

- Rinse mouth with water.

Most important symptoms and effects, both acute and delayed

Effects

- No hazards to be specially mentioned.

Repeated or prolonged exposure

- slight irritation

- Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhoea.

Symptoms

- At high concentrations:

- slight irritation

- Redness

- Redness of the conjunctiva

Indication of any immediate medical attention and special treatment needed

Notes to physician

- When symptoms persist or in all cases of doubt seek medical advice.

Fire-fighting measures

Extinguishing media

Suitable extinguishing media

- Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Special hazards arising from the substance or mixture

- Under fire conditions:

- Will burn

- On combustion, toxic gases are released.

Advice for firefighters

Special protective equipment for firefighters

- In the event of fire, wear self-contained breathing apparatus.

Specific fire fighting methods

- Cool containers/tanks with water spray.

- Do not use a solid water stream as it may scatter and spread fire.

Further information

- Standard procedure for chemical fires.

- Collect contaminated fire extinguishing water separately. This must not be discharged into drains.

- Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.

Accidental release measures

Personal precautions, protective equipment and emergency procedures

- For further information refer to section 8 "Exposure controls/personal protection".

Environmental precautions

- Stop the leak. Turn leaking containers leak-side up to prevent the escape of liquid.

- Contain the spilled material by bunding.

- Do not let product enter drains.

- Do not allow uncontrolled discharge of product into the environment.

Methods and materials for containment and cleaning up

- Stop leak if safe to do so.

- Sweep up and shovel into suitable containers for disposal.

- Keep in properly labelled containers.

- Keep in suitable, closed containers for disposal.

- Wash non-recoverable remainder with large amounts of water.

- Soak up with inert absorbent material.

- Decontaminate tools, equipment and personal protective equipment in a segregated area.

- Dispose of in accordance with local regulations.

- Never return spills in original containers for re-use.

Handling and storage

Precautions for safe handling

Hygiene measures

- Handle in accordance with good industrial hygiene and safety practice.

- Wash hands before breaks and at the end of workday.

- When using do not eat, drink or smoke.

- Eye wash bottles or eye wash stations in compliance with applicable standards.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
2845
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Labels:
4.2
SpecialProvisionsopen allclose all
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Marine transport (UN RTDG/IMDG)

UN number:
2845
Shipping information
Proper shipping name and description:
Pyrophoric liquids, organic, n.o.s.
Chemical name:
Diphenylphosphine
Marine pollutant
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Air transport (UN RTDG/ICAO/IATA)

UN number:
2845
Shipping information
Proper shipping name and description:
Pyrophoric liquid, organic, n.o.s.
Chemical name:
Diphenylphosphine
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Additional transport information

Additional information
Special provisions / remarks / other:
DOT (US)
UN number: 2845 Class: 4.2 Packing group: I
Proper shipping name: Pyrophoric liquids, organic, n.o.s. (Diphenylphosphine)
Poison Inhalation Hazard: No

Exposure controls / personal protection

Exposure controls

Control measures

Engineering measures

- Ensure adequate ventilation.

- Apply technical measures to comply with the occupational exposure limits.

Individual protection measures

Respiratory protection

- Keep in a well-ventilated place.

Hand protection

- Take note of the information given by the producer concerning permeability and break through times, and of special workplace conditions (mechanical strain, duration of contact).

- Impervious gloves

Eye protection

- If splashes are likely to occur, wear:

- Chemical resistant goggles must be worn.

Skin and body protection

- If splashes are likely to occur, wear:

- Protective suit

Hygiene measures

- Handle in accordance with good industrial hygiene and safety practice.

- Wash hands before breaks and at the end of workday.

- When using do not eat, drink or smoke.

- Eye wash bottles or eye wash stations in compliance with applicable standards.

Environmental exposure controls

- Dispose of rinse water in accordance with local and national regulations.

This substance is handled under Strictly Controlled Conditions in accordance with REACH regulation Article 17(3) for on-site isolated intermediates and, in case the substance is transported to other sites for further processing, the substance should be handled at these sites under the Strictly Controlled Conditions as specified in REACH regulation Article 18(4). Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at each manufacturing site. Written confirmation of the application of Strictly Controlled Conditions has been received from every affected distributor and downstream manufacturer/user of the registrant’s intermediate.

Stability and reactivity

Reactivity: The substance or mixture is pyrophoric with the category 1.                                   

Stability: Decomposes upon contact with air. Stable under recommended storage conditions.

Incompatibility:  Strong oxidizing agents, air

Disposal considerations

Product Disposal

- The Company encourages the recycle, recovery and reuse of materials, where permitted.  If disposal is necessary, The Company recommends that organic materials, especially when classified as hazardous waste, be disposed of by thermal treatment or incineration at approved facilities. All local and national regulations should be followed.