Registration Dossier
Registration Dossier
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EC number: 811-684-2 | CAS number: 1255735-07-9
Guidance on Safe Use
Administrative data
First-aid measures
SECTION 4: FIRST AID MEASURES
4.1 Description of first aid measures
General advice
Move out of dangerous area. Place and transport victim in stable position (lying sideways). Remove contaminated clothing immediately and dispose of safely.
Inhalation
Move to fresh air. Keep patient warm and at rest. Call a physician or poison control center immediately.
Skin contact
Wash off thoroughly with plenty of soap and water, if available with polyethyleneglycol 400, subsequently rinse with water. Call a physician or poison control center immediately.
Eye contact
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a physician or poison control center immediately.
Ingestion
Rinse mouth. Do NOT induce vomiting. Call a physician or poison control center immediately.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms
No symptoms known or expected.
4.3 Indication of any immediate medical attention and special treatment needed
Treatment
Treat symptomatically. In case of ingestion gastric lavage should be considered in cases of significant ingestions only within the first 2 hours. However, the application of activated charcoal and sodium sulphate is always advisable. There is no specific antidote.
Fire-fighting measures
SECTION 5: FIREFIGHTING MEASURES
5.1 Extinguishing media
Suitable
Water spray, Carbon dioxide (CO2), Foam, Sand
5.2 Special hazards arising from the substance or mixture
In the event of fire the following may be released:, Hydrogen cyanide (hydrocyanic acid), Hydrogen fluoride, Carbon monoxide (CO), Nitrogen oxides (NOx)
5.3 Advice for firefighters
Special protective equipment for firefighters
In the event of fire and/or explosion do not breathe fumes. In the event of fire, wear self-contained breathing apparatus.
Further information
Contain the spread of the fire-fighting media. Do not allow run-off from fire fighting to enter drains or water courses.
Accidental release measures
SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures
Precautions
Avoid contact with spilled product or contaminated surfaces. Use personal protective equipment.
6.2 Environmental precautions
Do not allow to get into surface water, drains and ground water.
6.3 Methods and materials for containment and cleaning up
Methods for cleaning up
Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Clean contaminated floors and objects thoroughly, observing environmental regulations. Keep in suitable, closed containers for disposal.
Handling and storage
This substance is handled under Strictly Controlled Conditions in accordance with REACH regulation Article 17(3) for on-site isolated intermediates and, in case the substance is transported to other sites for further processing, the substance should be handled at these sites under the Strictly Controlled Conditions as specified in REACH regulation Article 18(4). Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at each manufacturing site.
Written confirmation of application of Strictly Controlled Conditions has been received from every affected Distributor and Downstream Processor/User of the Registrant’s intermediate.
SECTION 7: HANDLING AND STORAGE
7.1 Precautions for safe handling
Advice on safe handling
Use only in area provided with appropriate exhaust ventilation.
Hygiene measures
Avoid contact with skin, eyes and clothing. Keep working clothes separately. Wash hands immediately after work, if necessary take a shower. Remove soiled clothing immediately and clean thoroughly before using again. Garments that cannot be cleaned must be destroyed (burnt).
7.2 Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers
Store in original container. Keep containers tightly closed in a dry, cool and well-ventilated place. Store in a place accessible by authorized persons only. Protect against moisture.
Advice on common storage
Keep away from food, drink and animal feedingstuffs.
7.3 Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- UN 1760
Shipping information
- Proper shipping name and description:
- CORROSIVE LIQUID, N.O.S. (5-FLUORO-3-(DIFLUOROMETHYL)-1-METHYL-1 H-PYRAZOLE-4-CARBONYL FLUORIDE)
- Chemical name:
- 5-FLUORO-3-(DIFLUOROMETHYL)-1-METHYL-1 H-PYRAZOLE-4-CARBONYL FLUORIDE
- Language:
- English
- Labels:
- Packaging: 8
Bulk: 8
HazID: 88
SpecialProvisionsopen allclose all
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- UN 1760
Shipping information
- Proper shipping name and description:
- CORROSIVE LIQUID, N.O.S. (5-FLUORO-3-(DIFLUOROMETHYL)-1-METHYL-1 H-PYRAZOLE-4-CARBONYL FLUORIDE)
- Chemical name:
- 5-FLUORO-3-(DIFLUOROMETHYL)-1-METHYL-1 H-PYRAZOLE-4-CARBONYL FLUORIDE
- Language:
- English
- Labels:
- Packaging: 8
Bulk: 8
HazID: 88
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- UN 1760
Shipping information
- Proper shipping name and description:
- CORROSIVE LIQUID, N.O.S. (5-FLUORO-3-(DIFLUOROMETHYL)-1-METHYL-1 H-PYRAZOLE-4-CARBONYL FLUORIDE)
- Chemical name:
- 5-FLUORO-3-(DIFLUOROMETHYL)-1-METHYL-1 H-PYRAZOLE-4-CARBONYL FLUORIDE
- Labels:
- Packaging: 8
Bulk: 8
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- Un 1760
Shipping information
- Proper shipping name and description:
- CORROSIVE LIQUID, N.O.S. (5-FLUORO-3-(DIFLUOROMETHYL)-1-METHYL-1 H-PYRAZOLE-4-CARBONYL FLUORIDE)
- Chemical name:
- 5-FLUORO-3-(DIFLUOROMETHYL)-1-METHYL-1 H-PYRAZOLE-4-CARBONYL FLUORIDE
- Labels:
- Packaging: 8
Remarksopen allclose all
SpecialProvisionsopen allclose all
Exposure controls / personal protection
his substance is handled under Strictly Controlled Conditions in accordance with REACH regulation Article 17(3) for on-site isolated intermediates and, in case the substance is transported to other sites for further processing, the substance should be handled at these sites under the Strictly Controlled Conditions as specified in REACH regulation Article 18(4). Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at each manufacturing site.
Written confirmation of application of Strictly Controlled Conditions has been received from every affected Distributor and Downstream Processor/User of the Registrant’s intermediate.
Respiratory protection
If product is handled while not enclosed, and if contact may occur:
Wear respirator with an organic vapours and gas filter mask
(protection factor 10) conforming to EN140 type A or equivalent.
Respiratory protection should only be used to control residual risk of short duration activities, when all reasonably practicable steps have been taken to reduce exposure at source e.g. containment and/or local extract ventilation. Always follow respirator manufacturer's instructions regarding wearing and maintenance.
Hand protection
Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion, and the contact time.
Wash gloves when contaminated. Dispose of when contaminated inside, when perforated or when contamination on the outside cannot be removed. Wash hands frequently and always before eating, drinking, smoking or using the toilet.
Material
Nitrile rubber
Rate of permeability
> 480 min
Glove thickness
> 0,4 mm
Protective index
Class 6
Directive
Protective gloves complying with EN 374.
Eye protection
Wear goggles (conforming to EN166, Field of Use = 5 or equivalent) and faceshield (conforming to EN166, Field of Use = 3 or equivalent).
Skin and body protection
Wear standard coveralls and Category 3 Type 4 suit.
If there is a risk of significant exposure, consider a higher protective type suit.
Wear two layers of clothing wherever possible. Polyester/cotton or cotton overalls should be worn under chemical protection suit and should be professionally laundered frequently.
If chemical protection suit is splashed, sprayed or significantly contaminated, decontaminate as far as possible, then carefully remove and dispose of as advised by manufacturer.
General protective measures
If product is handled while not enclosed, and if contact may occur:
Complete suit protecting against chemicals
Stability and reactivity
SECTION 10: STABILITY AND REACTIVITY
10.1 Reactivity
Thermal decomposition
135 - 160 °C, Heating rate: 3 K/min, Decomposition energy: 13 kJ/kg
Exothermic decomposition. Determined in glass.
200 - 310 °C, Heating rate: 3 K/min, Decomposition energy: 1.158 kJ/kg
Exothermic decomposition. Determined in glass.
10.2 Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
No hazardous reactions when stored and handled according to prescribed instructions.
Reactions with water.
10.4 Conditions to avoid
Extremes of temperature and direct sunlight. Exposure to moisture.
10.5 Incompatible materials
Store only in the original container.
10.6 Hazardous decomposition products
No decomposition products expected under normal conditions of use.
Disposal considerations
During the whole life cycle of the substance all necessary measures in accordance to art. 18(4) of (EC) 1907/2006 are undertaken. The substance is handled under strictly controlled conditions.
Additional information (from SCC document), e.g.:
No emissions to soil, no landfill waste.
Waste air from the process is being burnt.
Solvents, mother liquors, solid or aqueous waste is being burnt.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
