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Physical & Chemical properties

Vapour pressure

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Reference
Endpoint:
vapour pressure
Type of information:
experimental study
Adequacy of study:
key study
Study period:
9 Jan 2018 - 16 Feb 2018
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
OECD Guideline 104 (Vapour Pressure Curve)
Version / remarks:
11 July 2006
Deviations:
no
GLP compliance:
no
Other quality assurance:
other: ISO 9001: 2015
Type of method:
effusion method: isothermal thermogravimetry
Key result
Temp.:
20 °C
Vapour pressure:
0.003 Pa

+Results

A representative weight loss curve of the test item is shown in Figure 6. The results of the isothermal TGA analysis for the test item and the vapour pressure at 20°C and 25°C are given in Table 3 and Table 4.

The vapour pressure regression curve of the log PT of the test item as function of the reciprocal temperatures is shown in Figure 7. The equation of the curve was:
log PT= -5003´1/T + 14.5 (r = 0.9998, n = 8).

Table 3          
Results of the Vapour pressure Isothermal TGA Analysis

Temperature
[°C]

Weight loss
[µg/min]

νT
[g/cm2/h]

logνT

logPT

PT
[Pa]

70

0.696581

8.31´10-5

-4.08

-0.09

0.82

 

0.684083

8.17´10-5

-4.09

-0.10

0.80

80

1.45437

1.74´10-4

-3.76

0.32

2.1

 

1.43183

1.71´10-4

-3.77

0.31

2.1

90

2.94830

3.52´10-4

-3.45

0.72

5.2

 

2.89863

3.46´10-4

-3.46

0.71

5.1

100

5.77648

6.90´10-4

-3.16

1.09

12

 

5.58010

6.66´10-4

-3.18

1.07

12

 

Table 4          
Vapour Pressure of the Test Item

Temperature
[°C]

logPT

PT
[Pa]

PT
[mm Hg]

20

-2.58

2.6´10-3

2.0´10-5

25

-2.29

5.1´10-3

3.8´10-5

Conclusion

The isothermal TGA effusion method was applied for the determination of the vapour pressure ofHetester FAO.

The vapour pressure of the test item at 20°C (293K) and 25°C (298K) was:

 

20°C

25°C

[Pa]

[mm Hg]

[Pa]

[mm Hg]

Test item

2.6´10-3

2.0´10-5

5.1´10-3

3.8´10-5

Conclusions:
The vapour pressure of the test substance was determined to be 0.0026 Pa at 20 °C, under the conditions of the test.
Executive summary:

In this guideline (OECD 104) study, the vapour pressure of the test substance was determined to be 0.0026 Pa at 20 °C.

Description of key information

Study conducted to recognised testing guidelines.

Key value for chemical safety assessment

Vapour pressure:
0.003 Pa
at the temperature of:
20 °C

Additional information