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Physical & Chemical properties

Auto flammability

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Reference
Endpoint:
auto-ignition temperature (liquids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
02-05-2017 - 04-05-2017
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
comparable to guideline study
Qualifier:
equivalent or similar to guideline
Guideline:
EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
Version / remarks:
Based on, Anon (1987), Electrical Apparatus for Explosive Gas Atmospheres. Part 4: Method of Test
for Ignition Temperature. IEC Publications 79-4, P1-19.
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Key result
Auto-ignition temperature:
>= 215 - <= 225 °C
Atm. press.:
>= 101.6 - <= 102 kPa

Results of the auto-ignition temperature determination are shown in the following table:

Table1

Test temperature (ºC)

Test volume (µL)

Ignition delay (s)

Observations

200 (clean flask)

70

>300

No ignition. Grey fumes were emitted.

250 (clean flask)

70

8

A yellow/orange flame. Grey fumes were emitted.

240 (clean flask)

70

25

An orange flame. Grey fumes were emitted.

230 (clean flask)

70

>300

No ignition. Grey fumes were emitted.

232 (clean flask)

70

>300

No ignition. Grey fumes were emitted.

234

70

>300

No ignition. Grey fumes were emitted.

236

70

>300

No ignition. Grey fumes were emitted.

238 (clean flask)

70

23

An orange flame. Grey fumes were emitted.

236 (clean flask)

70

>300

No ignition. Grey fumes were emitted.

236 (clean flask)

200

20

An orange/yellow flame. Grey fumes were emitted.

234 (clean flask)

200

21

An orange/yellow flame. Grey fumes were emitted.

232 (clean flask)

200

22

An orange/yellow flame. Grey fumes were emitted.

230 (clean flask)

200

24

An orange/yellow flame. Grey fumes were emitted.

228 (clean flask)

200

34

An orange/yellow flame. Grey fumes were emitted.

224 (clean flask)

200

33

An orange/yellow flame. Grey fumes were emitted.

222 (clean flask)

200

63

An orange/yellow flame. Grey fumes were emitted.

220 (clean flask)

200

47

An orange/yellow flame. Grey fumes were emitted.

218 (clean flask)

200

>300

No ignition. Grey fumes were emitted.

218 (clean flask)

400

>300

No ignition. Grey fumes were emitted.

218 (clean flask)

600

>300

No ignition. Grey fumes were emitted.

218 (clean flask)

800

>300

No ignition. Grey fumes were emitted.

218 (clean flask)

1000

>300

No ignition. Grey fumes were emitted.

Room temperature: 21 to 22°C
Atmospheric pressure: 101.6 to 102.0 kPa

Conclusions:
The test item Intreleven aldehyde has been determined to have an auto-ignition temperature of 220 ± 5 °C.
Executive summary:

The test item Intreleven aldehyde has been determined to have an auto-ignition temperature of 215°C according to a procedure diseigned to be compatible with Method A.15 Auto-Ignition Temperature (Liquids and Gases) of Commission Regulation (EC) No 440/2008 of 30 May 2008.

Description of key information

The test item has been determined to have an auto-ignition temperature of 215°C according to a procedure designed to be compatible with Method A.15 Auto-Ignition Temperature (Liquids and Gases) of Commission Regulation (EC) No 440/2008 of 30 May 2008.

Key value for chemical safety assessment

Autoflammability / Self-ignition temperature at 101 325 Pa:
215 °C

Additional information