Registration Dossier
Registration Dossier
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EC number: 219-842-7 | CAS number: 2550-02-9
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
· General information:
Immediately remove any clothing soiled by the product.
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident.
Take note of the following instructions:
· After inhalation:
In case of unconsciousness place patient stably in the recovery position for transportation.
Supply fresh air; consult doctor in case of complaints.
· After skin contact:
Immediately wash with water and soap and rinse thoroughly.
Remove contaminated clothing immediately.
Seek medical treatment.
· After eye contact:
Rinse opened eye for several minutes under running water. Then consult a doctor.
· After swallowing:
Do not induce vomiting; call for medical help immediately.
Rinse out mouth and then drink plenty of water.
Most important symptoms and effects, both acute and delayed:
No further relevant information available.
Indication of any immediate medical attention and special treatment needed:
No further relevant information available.
Immediately remove any clothing soiled by the product.
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident.
Take note of the following instructions:
· After inhalation:
In case of unconsciousness place patient stably in the recovery position for transportation.
Supply fresh air; consult doctor in case of complaints.
· After skin contact:
Immediately wash with water and soap and rinse thoroughly.
Remove contaminated clothing immediately.
Seek medical treatment.
· After eye contact:
Rinse opened eye for several minutes under running water. Then consult a doctor.
· After swallowing:
Do not induce vomiting; call for medical help immediately.
Rinse out mouth and then drink plenty of water.
Most important symptoms and effects, both acute and delayed:
No further relevant information available.
Indication of any immediate medical attention and special treatment needed:
No further relevant information available.
Fire-fighting measures
Extinguishing media
· Suitable extinguishing agents: CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· For safety reasons unsuitable extinguishing agents: Water with full jet
· Special hazards arising from the substance or mixture:
Carbon monoxide and carbon dioxide
Metal oxide fume
Can form explosive gas-air mixtures.
Advice for firefighters
· Protective equipment: Wear personal protective equipment. Mount respiratory protective device.
· Additional information: Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
Collect contaminated fire fighting water separately. It must not enter the sewage system.
Cool endangered container(s) with water spray.
· Suitable extinguishing agents: CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· For safety reasons unsuitable extinguishing agents: Water with full jet
· Special hazards arising from the substance or mixture:
Carbon monoxide and carbon dioxide
Metal oxide fume
Can form explosive gas-air mixtures.
Advice for firefighters
· Protective equipment: Wear personal protective equipment. Mount respiratory protective device.
· Additional information: Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
Collect contaminated fire fighting water separately. It must not enter the sewage system.
Cool endangered container(s) with water spray.
Accidental release measures
Personal precautions, protective equipment and emergency procedures:
Wear personal protective equipment. Keep unprotected persons away.
Keep away from ignition sources.
Ensure adequate ventilation.
Environmental precautions:
Do not allow product to reach sewage system or any water course.
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Clean the affected area carefully; suitable cleaners are:
Dispose of the material collected according to regulations.
Ensure adequate ventilation.
Wear personal protective equipment. Keep unprotected persons away.
Keep away from ignition sources.
Ensure adequate ventilation.
Environmental precautions:
Do not allow product to reach sewage system or any water course.
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Clean the affected area carefully; suitable cleaners are:
Dispose of the material collected according to regulations.
Ensure adequate ventilation.
Handling and storage
Precautions for safe handling:
Keep receptacles tightly sealed.
Store in cool, dry place in tightly closed receptacles.
Prevent static electric sparks.
· Information about fire - and explosion protection:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
Traces of flammable substances may collect in the steam chamber of enclosed systems. Keep clear of ignition sources.
The product is flammable.
Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles: Store in a cool location.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions: Keep container tightly sealed. Store in cool, dry conditions in well sealed receptacles.
Specific end use(s): Not applicable.
Keep receptacles tightly sealed.
Store in cool, dry place in tightly closed receptacles.
Prevent static electric sparks.
· Information about fire - and explosion protection:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
Traces of flammable substances may collect in the steam chamber of enclosed systems. Keep clear of ignition sources.
The product is flammable.
Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles: Store in a cool location.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions: Keep container tightly sealed. Store in cool, dry conditions in well sealed receptacles.
Specific end use(s): Not applicable.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- 1993
Shipping information
- Proper shipping name and description:
- 1993 FLAMMABLE LIQUID, N.O.S. (organic silicon compound)
- Chemical name:
- triethoxy(propyl)silane
- Language:
- English
- Labels:
- 3
Special provisions / remarks
- Special provisions:
- · Excepted quantities (EQ): E1
· Limited quantities (LQ) 5L
· Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 1000 ml
· Transport category 3
· Tunnel restriction code D/E
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- 1993
Shippingopen allclose all
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- 1993
Shipping information
- Proper shipping name and description:
- FLAMMABLE LIQUID, N.O.S. (organic silicon compound)
- Chemical name:
- triethoxy(propyl)silane
- Labels:
- 3
Special provisions / remarks
- Remarks:
- · Limited quantities (LQ) 5L
· Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 1000 ml
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- 1993
Shipping information
- Proper shipping name and description:
- FLAMMABLE LIQUID, N.O.S. (organic silicon compound)
- Chemical name:
- triethoxy(propyl)silane
- Labels:
- 3
Special provisions / remarks
- Remarks:
- UN No. 1993
Special provisions: -
Danger Code: 3L
UN packing group: III
PASSENGER AND CARGO AIRCRAFT:
Excepted Quantities: E1
Packing instruction: 355
max. net quantity per package: 60 L
Limited Quantity:
Packing instruction: Y344
max. net quantity per package: 10 L
CARGO AIRCRAFT:
Packing instruction: 366
max. net quantity per package: 220 L
GRACE recommends CARGO AIRCRAFT only.
SpecialProvisionsopen allclose all
Exposure controls / personal protection
· Additional information about design of technical facilities: No further data; see "handling and storage".
Control parameters
· Ingredients with limit values that require monitoring at the workplace: Not required.
· Additional information: Valid lists at time of creation were used as basis.
Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
· Respiratory protection: Suitable respiratory protective device recommended.
· Recommended filter device for short term use: Filter AX
· Protection of hands:Protective gloves.
Check the condition of the gloves prior to each use.
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation.
Preventive skin protection by use of skin-protecting agents is recommended.
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application.
EN 388: Minimum requirements for efficiency level 1 for all groups.
Butyl rubber, BR
Nitrile rubber, NBR
Recommended thickness of the material: >= 0.35 mm
· Penetration time of glove material
EN 420: Minimum requirements for efficiency level 1 for all groups.
The exact break through time has to be obtained from the manufacturer of the protective gloves and has to be observed.
For the mixture of chemicals mentioned below the penetration time has to be at least 480 minutes (Permeation according to EN 374 Part 3: Level 6).
· For the permanent contact gloves made of the following materials are suitable: Butyl rubber, BR
· Not suitable are gloves made of the following materials:
Leather gloves
cloth gloves
· Eye protection: Tightly sealed goggles
· Body protection: Protective work clothing.
Control parameters
· Ingredients with limit values that require monitoring at the workplace: Not required.
· Additional information: Valid lists at time of creation were used as basis.
Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
· Respiratory protection: Suitable respiratory protective device recommended.
· Recommended filter device for short term use: Filter AX
· Protection of hands:Protective gloves.
Check the condition of the gloves prior to each use.
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation.
Preventive skin protection by use of skin-protecting agents is recommended.
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application.
EN 388: Minimum requirements for efficiency level 1 for all groups.
Butyl rubber, BR
Nitrile rubber, NBR
Recommended thickness of the material: >= 0.35 mm
· Penetration time of glove material
EN 420: Minimum requirements for efficiency level 1 for all groups.
The exact break through time has to be obtained from the manufacturer of the protective gloves and has to be observed.
For the mixture of chemicals mentioned below the penetration time has to be at least 480 minutes (Permeation according to EN 374 Part 3: Level 6).
· For the permanent contact gloves made of the following materials are suitable: Butyl rubber, BR
· Not suitable are gloves made of the following materials:
Leather gloves
cloth gloves
· Eye protection: Tightly sealed goggles
· Body protection: Protective work clothing.
Stability and reactivity
Reactivity: No further relevant information available.
Chemical stability
No decomposition if used according to specifications.
No decomposition if used and stored according to specifications.
Possibility of hazardous reactions: No dangerous reactions known.
· Conditions to avoid: In case of thermal decomposition caused by smouldering and incomplete combustion toxic fumes may be developed.
Incompatible materials: Protect from contamination.
Hazardous decomposition products:
Metal oxide smoke
Flammable gases/vapours
Carbon monoxide and carbon dioxide
Chemical stability
No decomposition if used according to specifications.
No decomposition if used and stored according to specifications.
Possibility of hazardous reactions: No dangerous reactions known.
· Conditions to avoid: In case of thermal decomposition caused by smouldering and incomplete combustion toxic fumes may be developed.
Incompatible materials: Protect from contamination.
Hazardous decomposition products:
Metal oxide smoke
Flammable gases/vapours
Carbon monoxide and carbon dioxide
Disposal considerations
Waste treatment methods
· Recommendation: Disposal must be made according to official regulations.
· Waste disposal key:
The disposal of the product has to be carried out in accordance with the legal requirements. EWC waste codes are strictly industry-oriented, therefore waste classification has to be done by the waste producer.
Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.
· Recommendation: Disposal must be made according to official regulations.
· Waste disposal key:
The disposal of the product has to be carried out in accordance with the legal requirements. EWC waste codes are strictly industry-oriented, therefore waste classification has to be done by the waste producer.
Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
