Registration Dossier

Data platform availability banner - registered substances factsheets

Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Endpoint:
auto-ignition temperature (liquids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
March 30 - April 07 2017
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2017
Report date:
2017

Materials and methods

Test guideline
Qualifier:
according to guideline
Guideline:
DIN 51794 (Testing of mineral oil hydrocarbons - Determination of ignition temperature)
GLP compliance:
no

Test material

Constituent 1
Chemical structure
Reference substance name:
[1R-(1α,2α,5β,8β)]-4,4,8-trimethyltricyclo[6.3.1.02,5]dodecan-1-yl acetate
EC Number:
260-555-1
EC Name:
[1R-(1α,2α,5β,8β)]-4,4,8-trimethyltricyclo[6.3.1.02,5]dodecan-1-yl acetate
Cas Number:
57082-24-3
Molecular formula:
C17H28O2
IUPAC Name:
4,4,8-trimethyltricyclo[6.3.1.0~2,5~]dodec-1-yl acetate
Constituent 2
Chemical structure
Reference substance name:
1-((1S,2S,5R)-1,4,4-trimethyltricyclo[6.3.1.02,5]dodec-8-en-9-yl)ethan-1-one
Molecular formula:
C17H26O
IUPAC Name:
1-((1S,2S,5R)-1,4,4-trimethyltricyclo[6.3.1.02,5]dodec-8-en-9-yl)ethan-1-one
Constituent 3
Chemical structure
Reference substance name:
(3S,3aS,7R,9aS)-1,1,7-trimethyldecahydro-3a,7-methanocyclopenta[8]annulen-3-yl acetate
Cas Number:
77346-43-1
Molecular formula:
C17H28O2
IUPAC Name:
(3S,3aS,7R,9aS)-1,1,7-trimethyldecahydro-3a,7-methanocyclopenta[8]annulen-3-yl acetate
Constituent 4
Chemical structure
Reference substance name:
1-((1S,2S,5R,9S)-1,4,4-trimethyltricyclo[6.3.1.02,5]dodec-7-en-9-yl)ethan-1-one
Cas Number:
Not applicable
Molecular formula:
C17H26O
IUPAC Name:
1-((1S,2S,5R,9S)-1,4,4-trimethyltricyclo[6.3.1.02,5]dodec-7-en-9-yl)ethan-1-one
Constituent 5
Chemical structure
Reference substance name:
4,4,8-trimethyltricyclo[6.3.1.02,5]dodecan-1-ol
EC Number:
207-458-2
EC Name:
4,4,8-trimethyltricyclo[6.3.1.02,5]dodecan-1-ol
Cas Number:
472-97-9
Molecular formula:
C15H26O
IUPAC Name:
4,4,8-trimethyltricyclo[6.3.1.0~2,5~]dodecan-1-ol
Constituent 6
Chemical structure
Reference substance name:
(3S,3aS,7R,9aS)-1,1,7-trimethyldecahydro-3a,7-methanocyclopenta[8]annulen-3-ol
Cas Number:
62560-57-0
Molecular formula:
C15H26O
IUPAC Name:
(3S,3aS,7R,9aS)-1,1,7-trimethyldecahydro-3a,7-methanocyclopenta[8]annulen-3-ol
Constituent 7
Chemical structure
Reference substance name:
2,2,4,7a-tetramethyl-1,2,3,6,7,7a-hexahydro-1,3a-ethanoindene
Cas Number:
4545-68-0
Molecular formula:
C15H24
IUPAC Name:
2,2,4,7a-tetramethyl-1,2,3,6,7,7a-hexahydro-1,3a-ethanoindene
Constituent 8
Reference substance name:
not applicable
Cas Number:
not applicable
Molecular formula:
not applicable
IUPAC Name:
not applicable
Test material form:
liquid
Specific details on test material used for the study:
Name (as stated in the report): VETYNAL
Batch: VE00473596
Expiration date: March 05, 2019

Results and discussion

Auto-ignition temperature (liquids / gases)
Key result
Auto-ignition temperature:
255 °C
Atm. press.:
1 013 hPa

Applicant's summary and conclusion

Conclusions:
The lowest temperature giving a positive effect was 259°C. The injected volume was 100 µl. the ignition delay was 25 s. At a temperature of 254°C no ignition was observed.
 
Therefore, after rounding-off to the next-lower multiple of 5°C:
 
Auto-ignition temperature of Vetynal: 255±5°C
Executive summary:

The Auto-ignition temperature of Vetynal was determined in a SUR BERLIN oven equipped with a 250 ml glass ignition vessel according to the DIN 51794.

The lowest temperature giving a positive effect was 259°C. The injected volume was 100 µl. the ignition delay was 25 s. At a temperature of 254°C no ignition was observed.

 

Therefore, after rounding-off to the next-lower multiple of 5°C:

 

Auto-ignition temperature of Vetynal: 255±5°C