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Diss Factsheets

Physical & Chemical properties

Melting point / freezing point

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Reference
Endpoint:
melting point/freezing point
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2010
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
other: Visual observation in line with ECHA guidance docuemnts.
Reason / purpose for cross-reference:
reference to same study
Qualifier:
no guideline followed
Principles of method if other than guideline:
Tangerine oil is a mixture of substances and transition from liquid to solid will not be sharp. The „Guidance on information requirements and chemical safety assessment Chapter R.7a: Endpoint specific guidance” from ECHA mentions in chapter R7.1.2.3, that «Melting points are not normally carried out for mixtures ». Therefore it is recommended in the EFFA/EFEO guideline „The Registration for REACH of Natural Complex Substances used as Fragrance Ingredients” to describe the state of the essential oil after two days at +5°C and -20 °C rather than determining a transition temperature. As it is common knowledge that citrus oils are liquid at +5 °C only a test at -25 °C was carried out in this examination.
GLP compliance:
not specified
Type of method:
other: Visual observation
Melting / freezing pt.:
< -25 °C

Results:

Temperature

+20 °C

-25 °C for 72 h

State of sample

clear mobile liquid

slightly turbid mobile liquid

See also attached photographs.

Conclusions:
Tangerine oil is a clear mobile liquid at 20°C and a slightly turbid mobile liquid at -25°C after 72h.
Executive summary:

Tangerine oil is a mixture of substances and transition from liquid to solid will not be sharp. The „Guidance on information requirements and chemical safety assessment Chapter R.7a: Endpoint specific guidance” from ECHA mentions in chapter R7.1.2.3, that «Melting points are not normally carried out for mixtures ». Therefore it is recommended in the EFFA/EFEO guideline „The Registration for REACH of Natural Complex Substances used as Fragrance Ingredients” to describe the state of the essential oil after two days at +5°C and -20 °C rather than determining a transition temperature. As it is common knowledge that citrus oils are liquid at +5 °C only a test at -25 °C was carried out in this examination.

Tangerine oil was found to be a clear mobile liquid at 20°C and a slightly turbid mobile liquid at -25°C after 72h.

Description of key information

Tangerine oil is a slightly turbid mobile liquid at -25°C after 72h. Hence, the melting point is <-25ºC

Key value for chemical safety assessment

Melting / freezing point at 101 325 Pa:
-25 °C

Additional information

Tangerine oil is a slightly turbid mobile liquid at -25°C after 72h. Hence, the melting point is <-25ºC