Registration Dossier

Data platform availability banner - registered substances factsheets

Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Explosiveness

Currently viewing:

Administrative data

Link to relevant study record(s)

Description of key information

Non explosive

Key value for chemical safety assessment

Explosiveness:
non explosive

Additional information

According to the REACH Regulation adaptations of the standard information requirements, a specific test can be avoided because:

- the substance contains chemical groups associated with explosive properties which include oxygen and the calculated oxygen balance is less than -200 and

- the organic substance contains chemical groups associated with explosive properties but the exothermic decomposition energy is less than 500 J/g and the onset of exothermic decomposition is below 500 °C (i.e. energy of -95 J/g; onset at 153 °C).

Malachite Green Oxalate has been tested for impact sensitivity and dust explosibility. The studies outcomes report that Basic Green 004 Oxalate is not impact sensitive and dust explosibility only occurs in concentrations equal/greater than 100 g/m³ (Ignition source : 10 kV-Induction spark).

Furthermore, this substance is produced and used at the highest level in Europe, transported in ship from outside Europe at various temperature and stoking conditions. Evidences connected to the long experience in handling of the molecule confirm that no explosive properties have never been observed and reported up to now in the usual conditions of production, stock, transport and use.

Justification for classification or non-classification

According to the CLP Regulation (EC 1272/2008), 2.1.4.2. Screening procedure section, the screening procedure is aimed at identifying the presence of such reactive groups and the potential for rapid energy release. If the screening procedure identifies the substance or mixture to be a potential explosive, the acceptance procedure (section 10.3 of the UN Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria) has to be performed.

Screening procedure failed to evidence any reason for concern, on the basis that Malachite Green Oxalate contains chemical groups associated with explosive properties, but the oxygen balance is less than –200; furthermore the decomposition energy isless than 500 J/g and the onset of exothermic decomposition is below 500 °C.

In conclusion, according to the CLP Regulation (EC 1272/2008) substance does not meet the criteria to be classified as explosive.