Registration Dossier
Registration Dossier
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EC number: 500-033-5 | CAS number: 25068-38-6
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
. Eye Contact
- Do not rub your eyes.
- Immediately flush eyes with plenty of water for at least 15 minutes and call a doctor
- Go to the hospital immediately if symptoms (flare, irritate) occur.
- Remove contact lenses if worn.
B. Skin Contact
- Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
- Launder contaminated clothing before reuse.
- Go to the hospital immediately if symptoms (flare, irritate) occur.
- Wash hands/skin thoroughly after handling.
C. Inhalation
- Move exposed person to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.
- Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if symptoms occur.
D. Ingestion
- Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical
attention if symptoms occur.
- Rinse your mouth with water immediately.
E. Delayed and immediate effects and also chronic effects from short and long term exposure
- Not available
F. Notes to Physician
- Notify medical personnel of contaminated situations and have them take appropriate precautions.
- Do not rub your eyes.
- Immediately flush eyes with plenty of water for at least 15 minutes and call a doctor
- Go to the hospital immediately if symptoms (flare, irritate) occur.
- Remove contact lenses if worn.
B. Skin Contact
- Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
- Launder contaminated clothing before reuse.
- Go to the hospital immediately if symptoms (flare, irritate) occur.
- Wash hands/skin thoroughly after handling.
C. Inhalation
- Move exposed person to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.
- Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if symptoms occur.
D. Ingestion
- Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical
attention if symptoms occur.
- Rinse your mouth with water immediately.
E. Delayed and immediate effects and also chronic effects from short and long term exposure
- Not available
F. Notes to Physician
- Notify medical personnel of contaminated situations and have them take appropriate precautions.
Fire-fighting measures
A. Suitable (Unsuitable) extinguishing media
- Avoid use of water jet for extinguishing
B. Specific hazards arising from the chemical
- Not available
C. Special protective actions for fire-fighters
- Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
- Move containers from fire area, if this can be done without risk.
- Keep unauthorized personnel out.
- Withdraw immediately in case of rising sound from venting safety devices.
- Do not access if the tank is on fire.
- Vapor or gas can cause fires to spread quickly.
- Avoid use of water jet for extinguishing
B. Specific hazards arising from the chemical
- Not available
C. Special protective actions for fire-fighters
- Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
- Move containers from fire area, if this can be done without risk.
- Keep unauthorized personnel out.
- Withdraw immediately in case of rising sound from venting safety devices.
- Do not access if the tank is on fire.
- Vapor or gas can cause fires to spread quickly.
Accidental release measures
A. Personal Precautions, protective equipment and emergency procedures
- Wear proper personal protective apparatus as indicated in "Exposure controls/personal protection" and avoid skin contact and inhalation.
- Work shoudl be carried our against the wind, people should be evacuated upwind.
- Move containers to a safe area from the site of spillage.
- Remove all sources of ignition.
- Do not direct water at spill or source of leak.
- Avoid skin contact and inhalation.
B. Environmental precautions
- Prevent runoff and contact with waterways, drains or sewers.
- if large amounts have been spilled, inform the relevant authorities.
C. Methods and materials for containment and cleaning up
- Large spill : Stay upwind and keep out of low areas. Dike for later disposal.
- Notify central government, local government, where emissions exceeding the standard are expected.
- Dispose of waste in accordance with local regulations and via a licensed waste disposal contractor.
- Use an appropriate container to collect and dispose of spilled material.
- Small leak: use sand or other non-combustible material to absorp spilled material.
- Wipe off the solvent.
- Dike for later disposal.
- Prevent the influx to waterways, sewers, basements or confined spaces.
- Wear proper personal protective apparatus as indicated in "Exposure controls/personal protection" and avoid skin contact and inhalation.
- Work shoudl be carried our against the wind, people should be evacuated upwind.
- Move containers to a safe area from the site of spillage.
- Remove all sources of ignition.
- Do not direct water at spill or source of leak.
- Avoid skin contact and inhalation.
B. Environmental precautions
- Prevent runoff and contact with waterways, drains or sewers.
- if large amounts have been spilled, inform the relevant authorities.
C. Methods and materials for containment and cleaning up
- Large spill : Stay upwind and keep out of low areas. Dike for later disposal.
- Notify central government, local government, where emissions exceeding the standard are expected.
- Dispose of waste in accordance with local regulations and via a licensed waste disposal contractor.
- Use an appropriate container to collect and dispose of spilled material.
- Small leak: use sand or other non-combustible material to absorp spilled material.
- Wipe off the solvent.
- Dike for later disposal.
- Prevent the influx to waterways, sewers, basements or confined spaces.
Handling and storage
A. Precautions for safe handling
- Avoid contact with incompatible materials.
- Handle only in well-ventilated areas.
- Do not handle until all safety precautions have been read and understood.
- Operators should wear antistatic footwear and clothing.
- Do not inhale the steam for prolonged or repeated periods of time.
B. Conditions for safe storage, including any incompatibilities
- Store in cool, dry and well ventilated conditions.
- Store in accordance with applicable laws and regulations.
- Avoid direct sunlight.
- Avoid naked flames.
- Prevent static electricity and keep away from combustible materials or heat sources.
- Keep container tightly closed and sealed until ready for use.
- Store away from water and sewer.
- Avoid contact with incompatible materials.
- Handle only in well-ventilated areas.
- Do not handle until all safety precautions have been read and understood.
- Operators should wear antistatic footwear and clothing.
- Do not inhale the steam for prolonged or repeated periods of time.
B. Conditions for safe storage, including any incompatibilities
- Store in cool, dry and well ventilated conditions.
- Store in accordance with applicable laws and regulations.
- Avoid direct sunlight.
- Avoid naked flames.
- Prevent static electricity and keep away from combustible materials or heat sources.
- Keep container tightly closed and sealed until ready for use.
- Store away from water and sewer.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- 3082
Proper shipping name and description
- Environmentally hazardous substances, liquid, n.o.s.
Shippingopen allclose all
SpecialProvisionsopen allclose all
Shippingopen allclose all
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
Shippingopen allclose all
Remarksopen allclose all
Shippingopen allclose all
Remarksopen allclose all
Additional transport information
Additional information
- Special provisions / remarks / other:
- Special precautions for user related to transport or transportation measures
- Local transport follows in accordance with Dangerous goods Safety Management Law.
- Package and transport follow in accordance with Department of Transportation (DOT) and other regulatory agency requirements.
- EmS FIRE SCHEDULE : F-A (General fire schedule)
- EmS SPILLAGE SCHEDULE : S-F (Water-soluble marine pollutants)
Exposure controls / personal protection
1. Technical protection measures
Engineering Controls:
- A system of local and/or general exhaust is recommended to keep employee exposures above the Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. The use of local exhaust ventilation is recommended to control emissions near the source.
2. Organisational protection measures
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
3. Hand protection
- Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary.
4. Body protection
- Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
5. Eye protection
- Wear primary eye protection such as splash resistant safety goggles with a secondary protection face shield.
- Provide an emergency eye wash station and quick drench shower in the immediate work area.
6. Respiratory protection
- Respiratory protection shoudl be used under conditions of frequent use or heavy exposure.
- Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator e.g.
- Any chemical cartridge respirator with organic vapor cartridge(s).
- Any chemical cartridge respirator with a full facepiece and organic vapor cartridge(s).
- Any air-purifying respirator with a full facepiece and an organic vapor canister.
- For Unknown Concentration or Immediately Dangerous to Life or Health : Any supplied-air respirator with full facepiece and operated in a pressure-demand or other positive-pressure mode in combination with a separate escape supply. Any self-contained breathing apparatus.
Engineering Controls:
- A system of local and/or general exhaust is recommended to keep employee exposures above the Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. The use of local exhaust ventilation is recommended to control emissions near the source.
2. Organisational protection measures
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
3. Hand protection
- Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary.
4. Body protection
- Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
5. Eye protection
- Wear primary eye protection such as splash resistant safety goggles with a secondary protection face shield.
- Provide an emergency eye wash station and quick drench shower in the immediate work area.
6. Respiratory protection
- Respiratory protection shoudl be used under conditions of frequent use or heavy exposure.
- Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator e.g.
- Any chemical cartridge respirator with organic vapor cartridge(s).
- Any chemical cartridge respirator with a full facepiece and organic vapor cartridge(s).
- Any air-purifying respirator with a full facepiece and an organic vapor canister.
- For Unknown Concentration or Immediately Dangerous to Life or Health : Any supplied-air respirator with full facepiece and operated in a pressure-demand or other positive-pressure mode in combination with a separate escape supply. Any self-contained breathing apparatus.
Stability and reactivity
A. Chemical stability
- This material is stable under recommended storage and handling conditions.
B. Possibility of hazardous reactions
- Hazardous Polymerization will not occur.
C. Conditions to avoid
- Avoid contact with incompatible materials and condition.
D. Incompatible materials
- Not available
E. Hazardous decomposition products
- Not available
- This material is stable under recommended storage and handling conditions.
B. Possibility of hazardous reactions
- Hazardous Polymerization will not occur.
C. Conditions to avoid
- Avoid contact with incompatible materials and condition.
D. Incompatible materials
- Not available
E. Hazardous decomposition products
- Not available
Disposal considerations
A. Disposal methods
- Where more than two kinds of designated waste is mixed, it is difficult to treat seperately, in which case reduction or stabilization by incineration or similar process is recommended.
- if water separation is possible, pre-process with Water separation process.
- Dispose by incineration.
- Incinerate the oil by separating the oil and water
- The remainder of the water after separation will be processed in a water pollution prevention facilities.
- Remaining residues from incineration or stabilization can be dealt with by evaporation and concentration.
- Remaining residues from incineration can be dealt with by agglomeration.
- Any remaining material after incineration or stabilization should be purified by means of Separation/distillation/extraction/filtration/pyrolysis
B. Special precautions for disposal
- Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements.
- Disposal of waste should be in accordance with all applicable laws and regulations.
- Where more than two kinds of designated waste is mixed, it is difficult to treat seperately, in which case reduction or stabilization by incineration or similar process is recommended.
- if water separation is possible, pre-process with Water separation process.
- Dispose by incineration.
- Incinerate the oil by separating the oil and water
- The remainder of the water after separation will be processed in a water pollution prevention facilities.
- Remaining residues from incineration or stabilization can be dealt with by evaporation and concentration.
- Remaining residues from incineration can be dealt with by agglomeration.
- Any remaining material after incineration or stabilization should be purified by means of Separation/distillation/extraction/filtration/pyrolysis
B. Special precautions for disposal
- Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements.
- Disposal of waste should be in accordance with all applicable laws and regulations.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
