Registration Dossier
Registration Dossier
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EC number: 273-752-2 | CAS number: 69012-54-0 Spent copper sulfate electrolyte consisting of copper sulfate and sulfuric acid resulting from the electrolytic refining of copper.
Guidance on Safe Use
Administrative data
First-aid measures
GENERAL INFORMATION:
Instantly remove any clothing soiled by the product.
In case of irregular breathing or respiratory arrest provide artificial respiration.
AFTER INHALATION:
Supply fresh air or oxygen; call for doctor.
In case of unconsciousness bring patient into stable side position for transport.
AFTER SKIN CONTACT:
Instantly wash with water and soap and rinse thoroughly.
Seek medical treatment.
AFTER EYE CONTACT:
Rinse opened eye for several minutes under running water. Then consult doctor.
AFTER SWALLOWING:
Do not induce vomiting; instantly call for medical help.
Drink copious amounts of water and provide fresh air. Instantly call for doctor.
Fire-fighting measures
SUITABLE EXTINGUISHIN AGENTS:
Use fire fighting measures that suit the environment.
PROTECTIVE EQUIPMENT:
Put on breathing apparatus.
ADDITIONAL INFORMATION:
Collect contaminated fire fighting water separately. It must not enter drains.
Accidental release measures
PERSON-RELATED SAFETY PRECAUTIONS:
Wear protective equipment. Keep unprotected persons away.
MEASURES FOR ENVIRONMENTAL PROTECTION:
Prevent material from reaching sewage system, holes and cellars.
MEASURES FOR CLEANING/COLLECTING:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders).
Use neutralizing agent.
Dispose of contaminated material as waste according to item 13.
Ensure adequate ventilation.
Handling and storage
HANDLING
INFORMATION FOR SAFE HANDLING:
Ensure good ventilation/exhaustion at the workplace.
Open and handle container with care.
Ensure that suitable extractors are available on processing machines
Prevent formation of aerosols.
INFORMATION ABOUT PROTECTION AGAINST EXPLOSIONS AND FIRES:
Keep breathing equipment ready.
STORAGE
REQUIREMENTS TO BE MET BY STOREROOMS AND CONTAINERS:
Provide acid-resistant floor
INFORMATION ABOUT STORAGE IN ONE COMMON STORAGE FACILITY:
Store away from foodstuffs.
FURTHER INFORMATION ABOUT STORAGE CONDITIONS:
Keep container tightly sealed.
STORAGE CLASS:
6.1 B
Transport information
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Marine transport (UN RTDG/IMDG)
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Exposure controls / personal protection
ADDITIONAL INFORMATION ABOUT DESING OF TECHNICAL SYSTEMS:
No further data; see item 'handling and storage'.
COMPONENTS WITH CRITICAL VALUES THAT REQUIRE MONITORING AT THE WORKPLACE:
7786-81-4 Nickel sulphate : WEL Long-term value: 0.1 mg/m³ as Ni; Sk; Carc; Sen
Arsenic compounds: WEL Long-term value: 0.1 mg/m³
Antimony compounds: OEL Long-term value: 0.5 mg/m³ as Sb
ADDITIONAL INFORMATION:
The lists that were valid during the compilation were used as basis.
PERSONAL PROTECTIVE EQUIPMENT:
GENERAL PROTECTIVE AND HYGENIC MEASURES:
Keep away from foodstuffs, beverages and food.
Instantly remove any soiled and impregnated garments.
Wash hands during breaks and at the end of the work.
Store protective clothing separately.
Avoid contact with the eyes and skin.
BREATHING EQUIPMENT
Not necessary if room is well-ventilated.
PROTECTION OF HANDS:
Acid resistant gloves
Only use chemical protective gloves with CE-labelling of category III.
MATERIAL OF GLOVES:
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality
and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the
resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the
application.
Nitrile rubber, NBR
Chloroprene rubber, CR
EYE PROTECTION:
Tightly sealed safety glasses.
BODY PROTECTION:
Acid resistant protective clothing
Stability and reactivity
THERMAL DECOMPOSITION/CONDITIONS TO BE AVOIDED:
Stable at ambient temperature
DANGEROUS REACTIONS:
Dangerous reactions Reacts with base metals forming hydrogen
DANGEROUS PRODUCTS OF COMPOSITION:
Dangerous products of composition: Poisonous gases/vapours
Disposal considerations
PRODUCT
RECOMMENDATION:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
EUROPEAN WASTE CATALOGUE
06 03 13 solid salts and solutions containing heavy metals
UNCLEANED PACKAGINGS
RECOMMENDATION:
Disposal must be made according to official regulations.
RECOMMENDED CLEANING AGENT:
Water, if necessary with cleaning agent.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
