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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Melting point / freezing point

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Description of key information

The melting point was determined to be  -76 °C as per OECD 102.

Key value for chemical safety assessment

Melting / freezing point at 101 325 Pa:
-76 °C

Additional information

The key value of melting point was determined by using differential scanning calorimetry method according to the guideline OECD 102 in accordance with GLP. The inflection point of the glass transition was found at -75.44°C. After the experiment, a black residue was observed on the lid of the sample container and a black residue remained in the sample container. Based on the results, it was concluded that the melting temperature (glass transition) of the test substance is -76°C (197K).

This substance is hydrolytically unstable.When it comes in contact with water or moisture a complete hydrolysis will take place with no significant reaction products other than 2 -methylpropanol and ethyl acetoacetate and insoluble hydrated titanium oxides.

Because of rapid hydrolysis (half-life <10 minutes), the CSA concentrates on the most hazardous degradation product which is 2 -methylpropanol. The read-across data on the melting point of 2 -methylpropanol; -108 deg. Celsius, released from the substance is used as key value in CSA (peer-reviewed secondary source; O'Neil et al. 2006).