Registration Dossier

Administrative data

First-aid measures

The substance is very toxic by inhalation and harmful by ingestion
Inhalation
If exposure has occurred and any discomfort is noticed, remove the exposed person to fresh air. If discomfort increases, obtain medical attention immediately and prepare for emergency action: artificial respiration or cardiopulmonary resuscitation as required, preferably by trained personnel, and transport the victim to an emergency care facility.

If breathing has stopped, immediately start artificial respiration and maintain until a physician takes charge of the exposed person. Use
a bag valve mask or similar device to perform artificial respiration.

Skin contact
Immediately remove contaminated clothing and footwear and wash with water and soap. Get medical attention if irritation develops.

Eye contact
Immediately rinse eyes with much water or eyewash solution, occasionally opening eyelids, until no evidence of chemical remains. Remove contact lenses after a few minutes and rinse again. Get medical attention if irritation develops.

Ingestion
Let the exposed person rinse mouth and let him/her drink several glasses of water or milk. Inducing vomiting is not recommended. If vomiting does occur, let him/her rinse mouth and give fluids again. Never give anything by mouth to an unconscious person. Get medical attention immediately.

Most important symptoms and effects, both acute and delayed
Redness and sores

Indication of any immediate medical attention and special treatment needed
In case of inhalation, ingestion or eye contact, call a doctor (physician), clinic or hospital immediately.

It may be helpful to show this safety data sheet to physician.

Note to physician
There is no specific antidote against this substance. Gastric lavage and administration of activated charcoal can be considered.

Fire-fighting measures

Extinguishing media
Dry chemical, carbon dioxide, water spray or foam. Avoid heavy hose streams.

Special hazards arising from the substance or mixture
The essential breakdown products on combustion are hydrogen fluoride, nitrogen oxides, sulphur dioxide, carbon monoxide, carbon dioxide and various fluorinated organic compounds.

Advice for firefighters
If appropriate, keep fire-exposed containers cool with water spray. Fight fire from maximum possible distance. In case of large fire, firemen should wear self-contained breathing apparatus and protective clothing.

Accidental release measures

The substance is very toxic by inhalation and harmful by ingestion
Personal precautions, protective equipment and emergency procedures
Respiratory protection
Provide local exhaust ventilation system. The possibility of inhalation of vapour or dust must be excluded as much as possible.

Protective gloves
Wear long chemical resistant gloves such as barrier laminate, butyl rubber, nitrile rubber or viton for all manual work with the substance. Before removing gloves, wash them with water and soap.

Eye protection
Wear safety glasses or face mask. The possibility of eye contact must be excluded.

Other skin protection
Wear appropriate chemical resistant clothing to avoid all skin contact. Remove contaminated clothing immediately. Wash protective clothing after each use.

Avoid and reduce dust formation as much as possible.

Environmental precautions
Do not release to the environment.

Methods and materials for containment and cleaning up
Spills on the floor or other impervious surface should be swept up with an absorptive material such as universal binder, hydrated lime or absorbent clay. Collect the contaminated absorbent in closable container for disposal. Wet clean area with detergent and water

Handling and storage

Precautions to be taken in handling: It is recommended to avoid all personal contact with the product, if possible by use of closed systems and remote system control. Otherwise it is recommended to handle the material by mechanical means as much as possible. Adequate ventilation or local exhaust ventilation is required. The exhaust gases should be filtered or treated otherwise.
The substance is very toxic by inhalation and harmful by ingestion
Personal protection:
Respiratory protection
Provide local exhaust ventilation system. The possibility of inhalation of vapour or dust must be excluded as much as possible.

Protective gloves
Wear long chemical resistant gloves such as barrier laminate, butyl rubber, nitrile rubber or viton for all manual work with the substance. Before removing gloves, wash them with water and soap.

Eye protection
Wear safety glasses or face mask. The possibility of eye contact must be excluded.

Other skin protection
Wear appropriate chemical resistant clothing to avoid all skin contact. Remove contaminated clothing immediately. Wash protective clothing after each use.


Precautions to be taken in storing: Store dry in closed, labelled containers. The storage room should be constructed of incombustible material, closed, ventilated and with impermeable floor, without access of unauthorised persons or children. The room should exclusively be used for storage of chemicals. Food, drink, feed or seed should not be present. A warning sign reading “POISON” is recommended. A hand wash station should be available.

Specific use: The substance is a chemical intermediate for industrial use.

Fire and explosion precautions: NA

Transport information

Land transport (ADR/RID)

Shippingopen allclose all
Remarks:
Substance is not transported, since it is an onsite isolated intermediate.

Inland waterway transport (ADN(R))

Shippingopen allclose all
Remarks
Substance is not transported, since it is an onsite isolated intermediate.

Marine transport (IMDG)

Remarks
Substance is not transported, since it is an onsite isolated intermediate.

Air transport ICAO/IATA

Remarks
Substance is not transported, since it is an onsite isolated intermediate.

Additional transport information

Additional transport information
Substance is not transported, since it is an onsite isolated intermediate.

Exposure controls / personal protection

The substance is very toxic by inhalation and harmful by ingestion
Personal exposure limits: To our knowledge, exposure limits have not been established for this compound. However, exposure limits defined by local regulations may exist and must be observed.

Personal protection: When used in a closed system, personal protection equipment will not be required. The following is meant for other situations, when the use of a closed system is not possible, or when it is necessary to open the system. Consider the need to render equipment or piping systems non-hazardous before opening.

Respiratory protection
Provide local exhaust ventilation system. The possibility of inhalation of vapour or dust must be excluded as much as possible.

Protective gloves
Wear long chemical resistant gloves such as barrier laminate, butyl rubber, nitrile rubber or viton for all manual work with the substance. Before removing gloves, wash them with water and soap.

Eye protection
Wear safety glasses or face mask. The possibility of eye contact must be excluded.

Other skin protection
Wear appropriate chemical resistant clothing to avoid all skin contact. Remove contaminated clothing immediately. Wash protective clothing after each use.

Stability and reactivity

Reactivity The substance reacts with water.

Chemical stability The substance is stable during normal handling and storage at ambient temperatures.

Possibility of hazardous reactions None known

Conditions to avoid Heating of the substance may evolve very toxic and irritant vapours.

Incompatible materials None known

Hazardous decomposition products: See Fire-fighting measures.

Disposal considerations

Waste treatment methods
Remains and unclean packagings should be treated as hazardous material. Waste can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not discharge to sewer systems.

Disposal of waste and packagings must always be in accordance with all applicable local regulations.