Registration Dossier
Registration Dossier
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EC number: 235-698-8 | CAS number: 12542-85-7
Explosiveness
Administrative data
- Endpoint:
- explosiveness
- Type of information:
- experimental study
- Adequacy of study:
- supporting study
- Study period:
- not reported
- Reliability:
- 2 (reliable with restrictions)
- Rationale for reliability incl. deficiencies:
- other: Study conducted in accordance with generally accepted scientific principles, possibly with incomplete reporting or methodological deficiencies, which do not affect the quality of the relevant results.
Data source
Reference
- Reference Type:
- study report
- Title:
- Unnamed
- Year:
- 1 996
- Report date:
- 1996
Materials and methods
- Principles of method if other than guideline:
- Determination of the thermal stability of methylaluminium sesquichloride (MASC), by means of Diffrential Scanning Calorimetry (DSC).
- GLP compliance:
- not specified
Test material
- Reference substance name:
- Trichlorotrimethyldialuminium
- EC Number:
- 235-698-8
- EC Name:
- Trichlorotrimethyldialuminium
- Cas Number:
- 12542-85-7
- Molecular formula:
- C3H9Al2Cl3
- IUPAC Name:
- trichlorotrimethyldialuminium
- Test material form:
- not specified
- Details on test material:
- - Name of test material (as cited in study report): Methylaluminium sesquichloride (MASC)
Constituent 1
Results and discussion
Any other information on results incl. tables
Table 1: DSC isothermal data of MASC
Temperature (°C) |
Intake (mg) |
Max. heat production (w/kg) |
300 |
9.37 |
9.95 |
320 |
8.78 |
34.5 |
330 |
8.45 |
56.3 |
340 |
8.23 |
81.6 |
The isothermal curves are shown in Figure 2.
From these data a Arrhenius curve is made in Figure 3. From the Arrhenius curve it appears that for MASC the Ln C is 35.1 and the activation energy (EA) is 155.8 kJ/mol.
Applicant's summary and conclusion
- Conclusions:
- MASC is stable below 200 °C. From the Arrhenius curve it appears that for MASC the Ln C is 35.1 and the activation energy (Ea) is 155.8 kJ/mol.
- Executive summary:
Determination of the thermal stability of methylaluminium sesquichloride (MASC), by means of Diffrential Scanning Calorimetry (DSC).
MASC is stable below 200 °C. From the Arrhenius curve it appears that for MASC the Ln C is 35.1 and the activation energy (Ea) is 155.8 kJ/mol.
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