Registration Dossier
Registration Dossier
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EC number: 931-670-0 | CAS number: -
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
Inhalation:
-In case of accident by inhalation: remove casualty to fresh air and keep at rest
-Victim to lie down in the recovery position, cover and keep him warm
-Oxygen or artificial respiration if needed
-If symptoms persist, call a physician
Eye contact:
-Rinse immediately with plenty of water, also under the eyelids, for at least 15 mniutes
-In the case of difficulty of opening the lids, administer an analgesic eye wash (oxybyprocaine)
-Immediate medical attention is required
Skin contact:
Remove and wash contaminated clothing before re-use
-Wash off with soap and water
-If symptoms persist, call a physician
Ingestion:
-Consult a physician
-Take victim immediately to hospital
If victim is conscious:
-If swallowed, rinse mouth with water (only if the person is conscious)
-Do NOT induce vomiting
-Do not give anything to drink
-Artificial respiration and/or oxygen may be necessary
If victim is unconscious but breathing:
-Artificial respiration and/or oxygen may be nessary
-In case of accident by inhalation: remove casualty to fresh air and keep at rest
-Victim to lie down in the recovery position, cover and keep him warm
-Oxygen or artificial respiration if needed
-If symptoms persist, call a physician
Eye contact:
-Rinse immediately with plenty of water, also under the eyelids, for at least 15 mniutes
-In the case of difficulty of opening the lids, administer an analgesic eye wash (oxybyprocaine)
-Immediate medical attention is required
Skin contact:
Remove and wash contaminated clothing before re-use
-Wash off with soap and water
-If symptoms persist, call a physician
Ingestion:
-Consult a physician
-Take victim immediately to hospital
If victim is conscious:
-If swallowed, rinse mouth with water (only if the person is conscious)
-Do NOT induce vomiting
-Do not give anything to drink
-Artificial respiration and/or oxygen may be necessary
If victim is unconscious but breathing:
-Artificial respiration and/or oxygen may be nessary
Fire-fighting measures
Suitable extinguishing media:
-Powder
-Foam, AFFF
-Carbon dioxide (CO2)
Extinguishing media which shall not be used for safety reasons:
-Water spray jet
Special exposure hazards in a fire:
-Highly flammable
-Vapours are havier than air and may spread along floors
-Risk of ignition
-Vapours may form explosive mixtures with air
-Hazardous decomposition products formed under fire conditions
Special protective equipment for fire-fighters:
-Evacuate personnel to safe areas
-Wear self-contained breathing apparatus and protective suit
-Fire fighters must wear fire resistant personnel protective equipment
-Protect intervention team with a water spray as they approach the fire
-Clean contamined surface thoroughly
Other information:
-Cool containers/tanks with water spray
-Flood the product with water
-Avoid propagating the fire when directing the extinguishing agent as a jet onto the surface of the burning liquid
-Powder
-Foam, AFFF
-Carbon dioxide (CO2)
Extinguishing media which shall not be used for safety reasons:
-Water spray jet
Special exposure hazards in a fire:
-Highly flammable
-Vapours are havier than air and may spread along floors
-Risk of ignition
-Vapours may form explosive mixtures with air
-Hazardous decomposition products formed under fire conditions
Special protective equipment for fire-fighters:
-Evacuate personnel to safe areas
-Wear self-contained breathing apparatus and protective suit
-Fire fighters must wear fire resistant personnel protective equipment
-Protect intervention team with a water spray as they approach the fire
-Clean contamined surface thoroughly
Other information:
-Cool containers/tanks with water spray
-Flood the product with water
-Avoid propagating the fire when directing the extinguishing agent as a jet onto the surface of the burning liquid
Accidental release measures
Personal precautions:
-Prevent further leakage or spillage if safe to do so
-Vapours are havier than air and can cause suffocation by reducing oxygen available for breathing
-Wear self-contained breathing apparatus in confined spaces, in cases where the oxygen level is depleted, or in case of significant emissions
-Keep away from open flames, hot surfaces and sources of ignition
-Cover the spreading liquid with foam in order to slow down the evaporation
-Keep away from incompatible products
-Ventilate the area
-Refer to protective measures listed below
Environmental precautions:
-Should not be released into the environment
-If the product contaminates rivers and lakes or drains inform respective authorities
Methods for cleaning up:
-Dam up
-Soak up with inert absorbent material
-Prevent product from entering drains
-Keep in properly labelled containers
-Keep in suitable, closed containers for disposal
-Treat recovered material as described in the section "Disposal considerations"
-Prevent further leakage or spillage if safe to do so
-Vapours are havier than air and can cause suffocation by reducing oxygen available for breathing
-Wear self-contained breathing apparatus in confined spaces, in cases where the oxygen level is depleted, or in case of significant emissions
-Keep away from open flames, hot surfaces and sources of ignition
-Cover the spreading liquid with foam in order to slow down the evaporation
-Keep away from incompatible products
-Ventilate the area
-Refer to protective measures listed below
Environmental precautions:
-Should not be released into the environment
-If the product contaminates rivers and lakes or drains inform respective authorities
Methods for cleaning up:
-Dam up
-Soak up with inert absorbent material
-Prevent product from entering drains
-Keep in properly labelled containers
-Keep in suitable, closed containers for disposal
-Treat recovered material as described in the section "Disposal considerations"
Handling and storage
Handling:
-Use only in well-ventilated areas
-Used in closed system
-Handle small quantities under a lab hood
-Keep away from heat and sources of ignition
-Prevent product vapours decomposition from contacting hot spots
-Prevent product vapours decomposition from electric arc action (welding)
-Preferably transfer by pump or gravity
-Transfer using a pump equipped for collection and return of gas/vapour
-Do not use compressed air for transferring or handling the product
-Use only equipment and materials which are compatible with the product
-No sparking tools should be used
-Keep away from sources of ignition - No smoking
-Keep away from incompatible products
Storage:
-Store in orignal container
-Keep contained closed
-Keep in a cool, well-ventilated place
-Keep away from heat and sources of ignition
-Keep away from incompatible products
-Keep in a bunded area
Specific use(s):
-For futher information, please contact: Supplier
Packaging material:
-Steel drum
Other information:
-Keep away from heat/sparks/open flames/hot surfaces - No smoking
-Provide electrical equipment safe for hazardous locations
-Ensure all equipment is electrically grounded before beginning transfer operations
-Take measures to prevent the build up of electrostatic charge
-To avoid thermal decomposition, do not overheat
-Refer to protective measures listed below
-Use only in well-ventilated areas
-Used in closed system
-Handle small quantities under a lab hood
-Keep away from heat and sources of ignition
-Prevent product vapours decomposition from contacting hot spots
-Prevent product vapours decomposition from electric arc action (welding)
-Preferably transfer by pump or gravity
-Transfer using a pump equipped for collection and return of gas/vapour
-Do not use compressed air for transferring or handling the product
-Use only equipment and materials which are compatible with the product
-No sparking tools should be used
-Keep away from sources of ignition - No smoking
-Keep away from incompatible products
Storage:
-Store in orignal container
-Keep contained closed
-Keep in a cool, well-ventilated place
-Keep away from heat and sources of ignition
-Keep away from incompatible products
-Keep in a bunded area
Specific use(s):
-For futher information, please contact: Supplier
Packaging material:
-Steel drum
Other information:
-Keep away from heat/sparks/open flames/hot surfaces - No smoking
-Provide electrical equipment safe for hazardous locations
-Ensure all equipment is electrically grounded before beginning transfer operations
-Take measures to prevent the build up of electrostatic charge
-To avoid thermal decomposition, do not overheat
-Refer to protective measures listed below
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- 1993
Shipping information
- Proper shipping name and description:
- FLAMMABLE LIQUID N.O.S. (MIXTURE 1,2-DICHLOROPROPANE/DICHLOROPENES)
- Chemical name:
- MIXTURE 1,2-DICHLOROPROPANE/DICHLOROPENES
- Labels:
- 3
Special provisions / remarks
- Special provisions:
- 640D
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- 1993
Shippingopen allclose all
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- 1993
Shipping information
- Proper shipping name and description:
- FLAMMABLE LIQUID N.O.S. (MIXTURE 1,2-DICHLOROPROPANE/DICHLOROPROPENES)
- Chemical name:
- MIXTURE 1,2-DICHLOROPROPANE/DICHLOROPENES
- Labels:
- Flammable Liquids
- Marine pollutant
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- 1993
Shipping information
- Proper shipping name and description:
- FLAMMABLE LIQUID N.O.S. (MIXTURE 1,2-DICHLOROPROPANE/DICHLOROPROPENES)
- Chemical name:
- MIXTURE 1,2-DICHLOROPROPANE/DICHLOROPENES
- Labels:
- Flammable Liquids
Remarksopen allclose all
SpecialProvisionsopen allclose all
Exposure controls / personal protection
Exposure Limit Values:
1,2-Dichloropropane: US ACGIH Threshold Limit Values 01 2006/ time weighted average = 10ppm
2.3-Dichloropropene: US ACGIH Threshold Limit Values/none established
1,1-Dichloropropene: US ACGIH Threshold Limit Values/ none established
1,3-Dichloropropene: US ACGIH Threshold Limit Values 01 2006/time weighted average = 1 ppm / Remarks: Can be absorbed through skin
3-Chloropropene: US ACGIH Threshold Limit Values 2008/time weighted average = 1 ppm
US ACGIH Threshold Limit Values 2008/Short term exposure limit = 2 ppm
Benzene: OEL (Directive 98/24/EC) 2004/TWA = 1 ppm= 3.25 mg/m3 / Remarks: Skin
UK EH40 Workplace Exposure Limits (WELs) 2005/time weighted average = 1ppm /Remarks: Can be absorbed through skin
US ACGIH Threshold Limit Values 01 2006 /time weighted average = 0.5ppm
US ACGIH Threshold Limit Values 01 2006/Short term exposure limit = 2.5 ppm
US ACGIH Threshold Limit Values 01 2006/Remarks: Can be absorbed though skin
EU OELs, Directive 2004/37/EC on carcinogen and mutagens from Annex III, Part A 06 2004/ time weighted average = 1ppm = 3.25mg/m3 / Remarks: Can be absorbe through skin
Exposure controls:
-Ensure adequate ventilation
-Apply technical measures to comply with the occupational exposure limits
Occupational exposure controls:
Respiratory protection:
-Use respirator when performing operations involving potential exposure to vapour of the product
-Respirator with a vapour filter (EN 141)
-Recommended Filter Type: A
-Self-contained breathing apparatus in medium confinement insufficient oxygen/in case of large uncontrolled emissions/in circumstances when the mask and a cartridge do not give adequate protection
Hand protection:
-Wear suitable gloves
-Take note of the information given by the producer concerning permeability and break through times, and a special workplace conditions (mechanical strain, duration of contact)
-Suitable material: Copolymer VF2-HFP (fluoroelastomer)
Eye protection:
-Chemical resistant goggles must be worn
-If splashes are likely to occur, wear: Tightly fitting safety goggles; Face-shield
Skin and body protection:
-Impervious suit
-If splashes are likely to occur, wear:
-Neoprene
-Apron
-Boots
Hygiene measures
-Ensure that eyewash stations and safety showers are close to the workstation location
-When using do not eat, drink or smoke
-HIgh standards of skin care and personal hygiene should be exercised at all times
-Handle in accordance with good industrial hygiene and safety practice
-STRICT HYGIENE
Environmental exposure controls:
-Dispose of a rinse water in accordance with local and national regulations
1,2-Dichloropropane: US ACGIH Threshold Limit Values 01 2006/ time weighted average = 10ppm
2.3-Dichloropropene: US ACGIH Threshold Limit Values/none established
1,1-Dichloropropene: US ACGIH Threshold Limit Values/ none established
1,3-Dichloropropene: US ACGIH Threshold Limit Values 01 2006/time weighted average = 1 ppm / Remarks: Can be absorbed through skin
3-Chloropropene: US ACGIH Threshold Limit Values 2008/time weighted average = 1 ppm
US ACGIH Threshold Limit Values 2008/Short term exposure limit = 2 ppm
Benzene: OEL (Directive 98/24/EC) 2004/TWA = 1 ppm= 3.25 mg/m3 / Remarks: Skin
UK EH40 Workplace Exposure Limits (WELs) 2005/time weighted average = 1ppm /Remarks: Can be absorbed through skin
US ACGIH Threshold Limit Values 01 2006 /time weighted average = 0.5ppm
US ACGIH Threshold Limit Values 01 2006/Short term exposure limit = 2.5 ppm
US ACGIH Threshold Limit Values 01 2006/Remarks: Can be absorbed though skin
EU OELs, Directive 2004/37/EC on carcinogen and mutagens from Annex III, Part A 06 2004/ time weighted average = 1ppm = 3.25mg/m3 / Remarks: Can be absorbe through skin
Exposure controls:
-Ensure adequate ventilation
-Apply technical measures to comply with the occupational exposure limits
Occupational exposure controls:
Respiratory protection:
-Use respirator when performing operations involving potential exposure to vapour of the product
-Respirator with a vapour filter (EN 141)
-Recommended Filter Type: A
-Self-contained breathing apparatus in medium confinement insufficient oxygen/in case of large uncontrolled emissions/in circumstances when the mask and a cartridge do not give adequate protection
Hand protection:
-Wear suitable gloves
-Take note of the information given by the producer concerning permeability and break through times, and a special workplace conditions (mechanical strain, duration of contact)
-Suitable material: Copolymer VF2-HFP (fluoroelastomer)
Eye protection:
-Chemical resistant goggles must be worn
-If splashes are likely to occur, wear: Tightly fitting safety goggles; Face-shield
Skin and body protection:
-Impervious suit
-If splashes are likely to occur, wear:
-Neoprene
-Apron
-Boots
Hygiene measures
-Ensure that eyewash stations and safety showers are close to the workstation location
-When using do not eat, drink or smoke
-HIgh standards of skin care and personal hygiene should be exercised at all times
-Handle in accordance with good industrial hygiene and safety practice
-STRICT HYGIENE
Environmental exposure controls:
-Dispose of a rinse water in accordance with local and national regulations
Stability and reactivity
Stability:
-Stable under recommended storage conditions
Conditions to avoid:
-To avoid thermal decomposition, do not overheat
-Keep away from direct sunlight
-Keep away from heat, sparks and flame
-Exposure to moisture
Material to avoid:
-Oxidizing agents, Salts of metals, Metals, Acids, Bases, Amines, Halogenated compounds, Ferric chloride, Certain plastic materials
Hazardous decomposition products
-hydrochloric acid, Carbon monoxide, phosgene, the release of other hazardous decomposition products is possible
-Stable under recommended storage conditions
Conditions to avoid:
-To avoid thermal decomposition, do not overheat
-Keep away from direct sunlight
-Keep away from heat, sparks and flame
-Exposure to moisture
Material to avoid:
-Oxidizing agents, Salts of metals, Metals, Acids, Bases, Amines, Halogenated compounds, Ferric chloride, Certain plastic materials
Hazardous decomposition products
-hydrochloric acid, Carbon monoxide, phosgene, the release of other hazardous decomposition products is possible
Disposal considerations
Waste from residues/unused products:
-In accordance with local and national regulations
-Refer to manufacture/supplier fro information on recovery/recycling
-or
-Must be incinerated in a suitable incineration plant holding a permit delivered by the competent authorities
-The incinerator must be equipped with a system for the neutralization or recovery of HCl
Packaging treatment:
-Empty containers
-Dispose of as unused product
-To avoid treatments, as far as possible, use dedicated containers
-or
-Rinse the empty containers with a low volatility hydrocarbon and treat the effluent in the same way as waste
-In accordance with local and national regulations
-Refer to manufacture/supplier fro information on recovery/recycling
-or
-Must be incinerated in a suitable incineration plant holding a permit delivered by the competent authorities
-The incinerator must be equipped with a system for the neutralization or recovery of HCl
Packaging treatment:
-Empty containers
-Dispose of as unused product
-To avoid treatments, as far as possible, use dedicated containers
-or
-Rinse the empty containers with a low volatility hydrocarbon and treat the effluent in the same way as waste
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
