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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Melting point / freezing point

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Administrative data

Link to relevant study record(s)

Reference
Endpoint:
melting point/freezing point
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
study well documented, meets generally accepted scientific principles, acceptable for assessment
Qualifier:
equivalent or similar to guideline
Guideline:
OECD Guideline 102 (Melting point / Melting Range)
Deviations:
not specified
Qualifier:
equivalent or similar to guideline
Guideline:
EU Method A.1 (Melting / Freezing Temperature)
Deviations:
not specified
Principles of method if other than guideline:
Thermogravimetric measurements was performed in air at a heating rate of 3 °C/min. by an automatic thermobalance.
GLP compliance:
no
Type of method:
thermal analysis
Decomposition:
yes
Decomp. temp.:
> 287 - < 370 °C

In the thermogravimetric studies by Ma (1964), different forms of ammonium octamolybdate showed only slighly different behaviour regarding decomposition. Evolution of ammonia begins at ca. 200 °C. An endothermic peak relating to dehydration is observed at 287 °C . After continuous heating all ammonium is lost at 370°C and ammonium octamolybdate is converted into molybdenum trioxide (MoO3).

Conclusions:
In the thermogravimetric studies by Ma (1964), different forms of ammonium octamolybdate showed only slighly different behaviour regarding decomposition. An endothermic peak relating to dehydration is observed at 287 °C. After continuous heating all ammonium is lost at 370 °C and ammonium octamolybdate is converted into molybdenum trioxide (MoO3).

Description of key information

Decomposition (evolution of ammonia from ca. 200 °C, complete conversion to MoO3 at 370 °C).

Key value for chemical safety assessment

Additional information