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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Endpoint:
adsorption / desorption: screening
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: GLP guideline study according to OECD 121

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2003
Report date:
2003

Materials and methods

Test guideline
Qualifier:
according to guideline
Guideline:
OECD Guideline 121 (Estimation of the Adsorption Coefficient (Koc) on Soil and on Sewage Sludge using High Performance Liquid Chromatography (HPLC))
GLP compliance:
yes
Type of method:
HPLC estimation method
Media:
soil

Test material

Constituent 1
Chemical structure
Reference substance name:
-
EC Number:
444-090-3
EC Name:
-
Cas Number:
204848-45-3
Molecular formula:
C44 H43 N3 O4
IUPAC Name:
Propanoic acid, 2-[4-[4,6-bis([1,1'-biphenyl]-4-yl)-1,3,5-triazin-2-yl]-3-hydroxyphenoxy]-, isooctyl ester
Details on test material:
- Physical state: Slightly yellow powder
- Storage condition of test material: Room temperature {ca 20°C)
Radiolabelling:
no

Study design

Test temperature:
25 °C

HPLC method

Details on study design: HPLC method:
EQUIPMENT
- Apparatus: Hewlett Packard 1050 Liquid Chromatograph
- Column: Hypersil H5CPS (25 cm x 4.6 mm internal diameter)
- Detection system:
UV set at 220 nm (reference mixture)
UV set at 320 nm (test substance)

MOBILE PHASES
- Type: Acetonitrile:pH 4 phosphate buffer (55:45 v/v) and methanol:pH 9 borate buffer (55:45 v/v)
- Experiments with additives carried out on separate columns: no
- pH: 4 and 9

REFERENCE SUBSTANCES
I.D.S.
Acetanilide
Nitrobenzene
Naphthalene
2-Methylnaphthalene
Anthracene
DDT
Internal deadtime standard (I.D.S.): Formamide

DETERMINATION OF RETENTION TIMES
- Quantity of test substance introduced in the column:
- Quantity of reference substances: 6

Results and discussion

Adsorption coefficient
Type:
log Koc
Value:
> 5.4

Applicant's summary and conclusion

Validity criteria fulfilled:
yes
Conclusions:
Adsorption to solid soil phase is expected.