Registration Dossier
Registration Dossier
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EC number: 235-741-0 | CAS number: 12645-31-7
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
Description of first aid measures: Request medical assistance immediately, showing the SDS of this product.
By inhalation: This product does not contain substances classified as hazardous for inhalation, however, in case of symptoms of intoxication remove the person affected from the exposure area and provide with fresh air. Seek medical attention if the symptoms get worse or persist.
By skin contact: Remove contaminated clothing and footwear, rinse skin or shower the person affected if appropriate with plenty of cold water and neutral soap. In serious cases see a doctor. If the product causes burns or freezing, clothing should not be removed as this could worsen the injury caused if it is stuck to the skin. If blisters form on the skin, these should never be burst as this will increase the risk of infection.
By eye contact: Rinse eyes thoroughly with lukewarm water for at least 15 minutes. Do not allow the person affected to rub or close their eyes. If the injured person uses contact lenses, these should be removed unless they are stuck to the eyes, as this could cause further damage. In all cases, after cleaning, a doctor should be consulted as quickly as possible with the SDS of the product.
By ingestion/aspiration: Request immediate medical assistance, showing the SDS of this product. Do not induce womiting, because its expulsion from the stomach can be hazardous to the mucus of the main digestive tract, and its inhalation, to the respiratory system. Rinse out the mouth and throat, as they may have been affected during ingestion. In the case of loss of consciousness do not administrate anything orally unless supervised by a doctor. Keep th person affected at rest.
Indication of any immediate medical attention and special treatment needed: Non-applicable
By inhalation: This product does not contain substances classified as hazardous for inhalation, however, in case of symptoms of intoxication remove the person affected from the exposure area and provide with fresh air. Seek medical attention if the symptoms get worse or persist.
By skin contact: Remove contaminated clothing and footwear, rinse skin or shower the person affected if appropriate with plenty of cold water and neutral soap. In serious cases see a doctor. If the product causes burns or freezing, clothing should not be removed as this could worsen the injury caused if it is stuck to the skin. If blisters form on the skin, these should never be burst as this will increase the risk of infection.
By eye contact: Rinse eyes thoroughly with lukewarm water for at least 15 minutes. Do not allow the person affected to rub or close their eyes. If the injured person uses contact lenses, these should be removed unless they are stuck to the eyes, as this could cause further damage. In all cases, after cleaning, a doctor should be consulted as quickly as possible with the SDS of the product.
By ingestion/aspiration: Request immediate medical assistance, showing the SDS of this product. Do not induce womiting, because its expulsion from the stomach can be hazardous to the mucus of the main digestive tract, and its inhalation, to the respiratory system. Rinse out the mouth and throat, as they may have been affected during ingestion. In the case of loss of consciousness do not administrate anything orally unless supervised by a doctor. Keep th person affected at rest.
Indication of any immediate medical attention and special treatment needed: Non-applicable
Fire-fighting measures
Extinguishing media: Product is non-flammable under normal conditions of storage, manipulation and use. In the case of inflammation as a result of improper manipulation, storage or use preferably use polyvalent powder extinguishers (ABC powder), in accordance with the Regulation on fire protection systems. IT IS NOT RECOMMENDED to use tap water as an extinguishing agent.
Special hazards arising from the substance or mixture: As a result of combustion or thermal decomposition reactive sub-products are created that can become highly toxic and, consequently, can present a serious health risk.
Advice for firefighters: Depending on the magnitude of the fire it may be necessary to use full protective clothing and individual respiratory equipment. Minimum emergency facilities and equipment should be available (fire blankets, portable first aid kit,...) in accordance with Directive 89/654/EC.
Additional provisions: Act in accordance with the Internal Emergency Plan and the Information Sheets on actions to take after an accident or other emergencies. Destroy any source of ignition. In case of fire, refrigerate the storage containers and tanks for products susceptible to inflammation, explosion or BLEVE as a result of high temperatures. Avoid spillage of the products used to extinguish the fire into an aqueous medium.
Special hazards arising from the substance or mixture: As a result of combustion or thermal decomposition reactive sub-products are created that can become highly toxic and, consequently, can present a serious health risk.
Advice for firefighters: Depending on the magnitude of the fire it may be necessary to use full protective clothing and individual respiratory equipment. Minimum emergency facilities and equipment should be available (fire blankets, portable first aid kit,...) in accordance with Directive 89/654/EC.
Additional provisions: Act in accordance with the Internal Emergency Plan and the Information Sheets on actions to take after an accident or other emergencies. Destroy any source of ignition. In case of fire, refrigerate the storage containers and tanks for products susceptible to inflammation, explosion or BLEVE as a result of high temperatures. Avoid spillage of the products used to extinguish the fire into an aqueous medium.
Accidental release measures
Personal precautions, protective equipment and emergency procedures: Isolate leaks provided that there is no additional risk for the people performing this task. Personal protection equipment must be used against potential contact with the spilt product. Evacuate the area and keep out those who do not have protection.
Environmental precautions: This product is not classified as hazardous to the environment. Keep product away from drains, surface and underground water.
Methods and material for containment and cleaning up: It is recommended: Absorb the spillage using sand or inert absorbent and move it to a safe place. Do not absorb in sawdust or other combustible absorbents.
Environmental precautions: This product is not classified as hazardous to the environment. Keep product away from drains, surface and underground water.
Methods and material for containment and cleaning up: It is recommended: Absorb the spillage using sand or inert absorbent and move it to a safe place. Do not absorb in sawdust or other combustible absorbents.
Handling and storage
Precautions for safe handling:
A.- Precautions for safe manipulation: Comply with the current legislation concerning the prevention of industrial risks. Keep containers hermetically sealed. Control spills and residues, destroying them with safe methods (Accidental and release measures section). Avoid leakages from the container. Maintain order and cleanliness where dangerous products are used.
B.- Technical recommendations for the prevention of fires and explosions: Product is non-flammable under normal conditions of storage, manipulation and use. It is recommended to transfer at slow speeds to avoid the generation of electrostaic charges that can affect flammable products.
C.- Technical recommendations to prevent ergonomic and toxicological risks: Do not eat or drink during the process, washing hands afterwards with suitable cleaning products.
D.- Technical recommendations to prevent environmental risks: It is recommended to have absorbent material available at close proximity to the product.
Conditions for safe storage, including any incompatibilities:
A.- Technical measures for storage: Minimum Temp.: 5ºC. Maximum Temp.: 40ºC. Maximum time: 12 Months.
B.- General conditions for storage: Avoid sources of heat, radiation, static electricity and contact with food.
Specific end use(s): Except for the instructions already specified it is not necessary to provide any special recommendation regarding the uses of this product.
Handle the substance under strictly controlled conditions according to Article 17(3) of REACH Regulation. Rigorous containment should be achieved.
A.- Precautions for safe manipulation: Comply with the current legislation concerning the prevention of industrial risks. Keep containers hermetically sealed. Control spills and residues, destroying them with safe methods (Accidental and release measures section). Avoid leakages from the container. Maintain order and cleanliness where dangerous products are used.
B.- Technical recommendations for the prevention of fires and explosions: Product is non-flammable under normal conditions of storage, manipulation and use. It is recommended to transfer at slow speeds to avoid the generation of electrostaic charges that can affect flammable products.
C.- Technical recommendations to prevent ergonomic and toxicological risks: Do not eat or drink during the process, washing hands afterwards with suitable cleaning products.
D.- Technical recommendations to prevent environmental risks: It is recommended to have absorbent material available at close proximity to the product.
Conditions for safe storage, including any incompatibilities:
A.- Technical measures for storage: Minimum Temp.: 5ºC. Maximum Temp.: 40ºC. Maximum time: 12 Months.
B.- General conditions for storage: Avoid sources of heat, radiation, static electricity and contact with food.
Specific end use(s): Except for the instructions already specified it is not necessary to provide any special recommendation regarding the uses of this product.
Handle the substance under strictly controlled conditions according to Article 17(3) of REACH Regulation. Rigorous containment should be achieved.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- UN1760
Shipping information
- Proper shipping name and description:
- CORROSIVE LIQUID, N.O.S (Phosphoric acid, 2-ethylhexyl ester)
- Chemical name:
- Phosporic acid, 2-ethylhexyl ester
- Labels:
- 8
SpecialProvisionsopen allclose all
Shippingopen allclose all
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- UN1760
Shipping information
- Proper shipping name and description:
- CORROSIVE LIQUID, N.O.S (Phosphoric acid, 2-ethylhexyl ester)
- Labels:
- 8
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- UN1760
Shipping information
- Proper shipping name and description:
- CORROSIVE LIQUID, N.O.S (Phosphoric acid, 2-ethylhexyl ester)
- Labels:
- 8
Remarksopen allclose all
SpecialProvisionsopen allclose all
Exposure controls / personal protection
Control parameters: Substances whose occupational exposure limits have to be monitored in the work environment. There are no occupational exposure limits for the substance contained in the product.
DNEL (Workers):
Dermal - Long exposure - Systemic: 10.42 mg/kg
Inhalation - Long exposure - Systemic: 36.73 mg/m3.
DNEL (General population):
Oral - Long exposure - Systemic: 6.25 mg/kg
Dermal - Long exposure - Systemic: 6.25 mg/kg
Inhalation - Long exposure - Systemic: 10.87 mg/m3
PNEC:
STP: 15 mg/L
Intermittent: 0.49 mg/L
Fresh water: 0.049 mg/L
Marine water: 0.0015 mg/L
Sediment (Marine water): 0.35 mg/kg
Exposure controls:
A.- General security and hygiene measures in the work place: As a preventive measure it is recommended to use basic Personal Protection Equipment, with the corresponding <> in accordance with Directive 89/686/EC. All information contained herein is a recommendation which needs some specification from the labour risk prevention services as it is not known whether the company has additional measures at its disposal.
B.- Respiratory protection: The use of protection equipment will be necessary if a mist forms or if the occupational exposure limits are exceeded.
C.- Specific protection for the hands: NON-disposable chemical protective gloves CE CAT III. EN 374-1:2003, EN 374-3:2003/AC:2006, EN 420:2003+A1:2009. The Breakthrough Time indicated by the manufacturer mus exceed the period during which the product is being used. Do not use protective creams after the product has come into contact with skin.
D.- Ocular and facial protection: Face mask CE CAT II. EN 166:2001, EN 167:2001, EN 168:2001, EN ISO 4007:2012. Clean daily and disinfect periodically according to the manufacturer's instructions. Use if there is a risk of splashing.
E.- Bodily protection: Disposable Clothing for protection against chemical risks CE CAT III. EN 13034:2005+A1:2009, EN 168:2001, EN ISO 13982-1:2004/A1:2010, EN ISO 6529:2001, EN ISO 6530:2005, EN 464:1994. For professional use only. Clean periodically according to the manufacturer's instructions. Safety footwear for protection against chemical risk CE CAT III, EN ISO 20345:2011, EN 13832-1:2006. Replace boots ant any sign of deterioration
F.- Additional emergency measures: Emergency showerANSI Z358-1, ISO 3864-1:2002. Eyewash stations DIN 12 899, ISO 3864-1:2002.
Environmental exposure controls: In accordance with the community legislation for the protection of the environment it is recommended to avoid environmental spillage of both the product and its container.
Volatile organic compounds: With regard to Directive 2010/75/EU, this product has the following characteristics:
V.O.C (Supply): 0% weight
V.OC density at 20ºC: 0 kg/m3 (0g/L)
Average carbon number: Non-applicable
Average molecular weight: Non-applicable
The substance is used under strictly controlled conditions during its whole lifecycle as described under Article 17(3) and Section 2.1 of the Guidance for Intermediates. The substance should be rigorously contained by technical means during its whole lifecycle and procedural and control technologies should be in place in order to minimize emissions and any resulting exposure as described under Article 17(3). Personal protective equipment (PPE) should be used in cases of accidents and where waste is generated. The PPE may be also used as a good practice.
DNEL (Workers):
Dermal - Long exposure - Systemic: 10.42 mg/kg
Inhalation - Long exposure - Systemic: 36.73 mg/m3.
DNEL (General population):
Oral - Long exposure - Systemic: 6.25 mg/kg
Dermal - Long exposure - Systemic: 6.25 mg/kg
Inhalation - Long exposure - Systemic: 10.87 mg/m3
PNEC:
STP: 15 mg/L
Intermittent: 0.49 mg/L
Fresh water: 0.049 mg/L
Marine water: 0.0015 mg/L
Sediment (Marine water): 0.35 mg/kg
Exposure controls:
A.- General security and hygiene measures in the work place: As a preventive measure it is recommended to use basic Personal Protection Equipment, with the corresponding <
B.- Respiratory protection: The use of protection equipment will be necessary if a mist forms or if the occupational exposure limits are exceeded.
C.- Specific protection for the hands: NON-disposable chemical protective gloves CE CAT III. EN 374-1:2003, EN 374-3:2003/AC:2006, EN 420:2003+A1:2009. The Breakthrough Time indicated by the manufacturer mus exceed the period during which the product is being used. Do not use protective creams after the product has come into contact with skin.
D.- Ocular and facial protection: Face mask CE CAT II. EN 166:2001, EN 167:2001, EN 168:2001, EN ISO 4007:2012. Clean daily and disinfect periodically according to the manufacturer's instructions. Use if there is a risk of splashing.
E.- Bodily protection: Disposable Clothing for protection against chemical risks CE CAT III. EN 13034:2005+A1:2009, EN 168:2001, EN ISO 13982-1:2004/A1:2010, EN ISO 6529:2001, EN ISO 6530:2005, EN 464:1994. For professional use only. Clean periodically according to the manufacturer's instructions. Safety footwear for protection against chemical risk CE CAT III, EN ISO 20345:2011, EN 13832-1:2006. Replace boots ant any sign of deterioration
F.- Additional emergency measures: Emergency showerANSI Z358-1, ISO 3864-1:2002. Eyewash stations DIN 12 899, ISO 3864-1:2002.
Environmental exposure controls: In accordance with the community legislation for the protection of the environment it is recommended to avoid environmental spillage of both the product and its container.
Volatile organic compounds: With regard to Directive 2010/75/EU, this product has the following characteristics:
V.O.C (Supply): 0% weight
V.OC density at 20ºC: 0 kg/m3 (0g/L)
Average carbon number: Non-applicable
Average molecular weight: Non-applicable
The substance is used under strictly controlled conditions during its whole lifecycle as described under Article 17(3) and Section 2.1 of the Guidance for Intermediates. The substance should be rigorously contained by technical means during its whole lifecycle and procedural and control technologies should be in place in order to minimize emissions and any resulting exposure as described under Article 17(3). Personal protective equipment (PPE) should be used in cases of accidents and where waste is generated. The PPE may be also used as a good practice.
Stability and reactivity
Reactivity: No hazardous reactions are expected because the product is stable under recommended storage conditions.
Chemical stability: Chemically stable under the conditions of storage, handling and use.
Possibility of hazardous reactions: Under the specified conditions, hazardous reactions that lead to excessive temperatures or pressure are not expected.
Conditions to avoid: Applicable for handling and storage at room temperature: Not applicable
Incompatible materials: Precaution with combustive materials. Avoid alkalis or strong bases.
Hazardous decomposition products: See previous information. Depending on the decomposition conditions, complex mixtures of chemical substances can be released: carbon dioxide (CO2), carbon monoxide and othe organic compounds.
Chemical stability: Chemically stable under the conditions of storage, handling and use.
Possibility of hazardous reactions: Under the specified conditions, hazardous reactions that lead to excessive temperatures or pressure are not expected.
Conditions to avoid: Applicable for handling and storage at room temperature: Not applicable
Incompatible materials: Precaution with combustive materials. Avoid alkalis or strong bases.
Hazardous decomposition products: See previous information. Depending on the decomposition conditions, complex mixtures of chemical substances can be released: carbon dioxide (CO2), carbon monoxide and othe organic compounds.
Disposal considerations
Waste treatment methods:
Code: 16 03 05*
Description: Organic wastes containing dangerous substances
Waste class (Regulation (EU) No 1357/2014): Dangerous
Waste management (disposal and evaluation): Consult the authorized waste service manager on the assessment and disposal operations in accordance with Annex 1 and Annex 2 (Directive 2008/98/EC). As under 15 01 (2014/955/EC) of the code andin case the container has been in direct contact with the product, it will be processed the same way as the actual product. Otherwise, it will be processed as non-dangerous residue. We do not recommended disposal down the drain.
Regulations related to waste management: In accordance with Annex II of Regulation (EC) nº1907/2006 (REAHC) the community or state provisions related to waste management are stated.
Community legislation: Directive 2008/98/EC, 2014/955/EU, Regulation (EU) No 1357/2014
Code: 16 03 05*
Description: Organic wastes containing dangerous substances
Waste class (Regulation (EU) No 1357/2014): Dangerous
Waste management (disposal and evaluation): Consult the authorized waste service manager on the assessment and disposal operations in accordance with Annex 1 and Annex 2 (Directive 2008/98/EC). As under 15 01 (2014/955/EC) of the code andin case the container has been in direct contact with the product, it will be processed the same way as the actual product. Otherwise, it will be processed as non-dangerous residue. We do not recommended disposal down the drain.
Regulations related to waste management: In accordance with Annex II of Regulation (EC) nº1907/2006 (REAHC) the community or state provisions related to waste management are stated.
Community legislation: Directive 2008/98/EC, 2014/955/EU, Regulation (EU) No 1357/2014
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
