Registration Dossier

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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Auto flammability

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Administrative data

Link to relevant study record(s)

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Endpoint:
auto-flammability
Type of information:
other: Peer reviewed data
Adequacy of study:
supporting study
Reliability:
4 (not assignable)
Rationale for reliability incl. deficiencies:
secondary literature
Qualifier:
no guideline followed
Principles of method if other than guideline:
Not applicable - Peer reviewed data
GLP compliance:
not specified
Na2SO3 is stable up to 600 °C.
Conclusions:
Self-ignition is not considered to be of relevance for this substance, since this would require heat to be developed either by reaction of this substance with oxygen or by exothermic decomposition and which is not lost rapidly enough to the surroundings. Since sodium sulfite is stable up to a temperature of 600 °C, it can safely be assumed that this compound will not ignite under the conditions given in EU-Method A.16. In conclusion, the conduct of further experimental verification is not considered to be required (in accordance with section 1, Annex XI of Regulation (EC) 1907/2006 (REACH)).
Endpoint:
relative self-ignition temperature (solids)
Data waiving:
study scientifically not necessary / other information available
Justification for data waiving:
other:

Description of key information

Self-ignition is not considered to be of relevance for sodium sulfite

Key value for chemical safety assessment

Additional information

Self-ignition is not considered to be of relevance for this substance, since this would require heat to be developed either by reaction of this substance with oxygen or by exothermic decomposition and which is not lost rapidly enough to the surroundings. Since sodium sulfite represents high and stable oxidation states of all elements included it is intrinsically not combustible and can safely be assumed not to be ignitable under the conditions given Test N4 Part III, sub-section 33.4.1.6 of the “UN Recommendations on the Transport of Dangerous Good, Manual of Tests and Criteria”. Furthermore, long-term industrial experience in handling shows that the substance has no self heating properties. In accordance with section 7.12, Column 2, Annex VII of Regulation (EC) 1907/2006, a study does not need to be conducted, if preliminary results exclude self- heating of the substance up to 400 °C. The substance ist stable up to 600 °C (see supporting information "s_IARC1992.Auto flammability").

In conclusion, the conduct of further experimental verification is not considered to be required.