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Diss Factsheets

Administrative data

Endpoint:
vapour pressure
Type of information:
experimental study
Adequacy of study:
key study
Study period:
Experimental Starting Date: 22 April 2014 Experimental Completion Date: 25 April 2014
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: see 'Remark'
Remarks:
Study conducted in compliance with agreed protocols, with no or minor deviations from standard test guidelines and/or minor methodological deficiencies, which do not affect the quality of the relevant results. The study report was conclusive, done to a valid guideline and the study was conducted under GLP conditions.

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2014
Report date:
2014

Materials and methods

Test guidelineopen allclose all
Qualifier:
according to guideline
Guideline:
EU Method A.4 (Vapour Pressure)
Deviations:
no
Qualifier:
according to guideline
Guideline:
OECD Guideline 104 (Vapour Pressure Curve)
Deviations:
no
GLP compliance:
yes
Type of method:
effusion method: vapour pressure balance

Test material

Constituent 1
Reference substance name:
Reaction mass of N,N’-bis-(3-methoxypropyl)-C22(branched)-alkyldiamide and N,N’-bis-(3-methoxypropyl)-C17(branched)-alkyldiamide
EC Number:
940-953-8
Molecular formula:
not applicable UVCB
IUPAC Name:
Reaction mass of N,N’-bis-(3-methoxypropyl)-C22(branched)-alkyldiamide and N,N’-bis-(3-methoxypropyl)-C17(branched)-alkyldiamide
Test material form:
other: Off white solid block

Results and discussion

Vapour pressure
Temp.:
25 °C
Vapour pressure:
< 0.001 Pa
Transition / decomposition
Transition / decomposition:
no

Any other information on results incl. tables

Results

Recorded temperatures, mass differences and the resulting calculated values of vapour pressure are shown in the following tables:

 

Run 5

Table 3.1 – Vapor Pressure Data

 

Temperature (ºC)

Temperature (K)

Reciprocal Temperature (K-1)

Mass Difference (µg)

Mass Difference (kg)

Vapor Pressure (Pa)

Log10Vp

40

313.15

0.003193358

1.61

1.610E-09

0.002235092

-2.650704503

41

314.15

0.003183193

1.28

1.280E-09

0.001776968

-2.750320409

42

315.15

0.003173092

0.07

7.000E-11

0.000097178

-4.012432339

43

316.15

0.003163056

0.72

7.200E-10

0.000999544

-3.000197882

44

317.15

0.003153082

0.69

6.900E-10

0.000957897

-3.018681288

45

318.15

0.003143171

0.78

7.800E-10

0.001082840

-2.965435776

46

319.15

0.003133323

1.30

1.300E-09

0.001804733

-2.743587026

47

320.15

0.003123536

1.82

1.820E-09

0.002526626

-2.597458991

48

321.15

0.003113810

1.93

1.930E-09

0.002679334

-2.571973070

49

322.15

0.003104144

2.14

2.140E-09

0.002970868

-2.527116605

50

323.15

0.003094538

1.53

1.530E-09

0.002124032

-2.672838948

 

 

No statistical analysis is given due to the nature of the plot


 

Run 7

Table 3.2 – Vapor Pressure Data

 

Temperature (ºC)

Temperature (K)

Reciprocal Temperature (K-1)

Mass Difference (µg)

Mass Difference (kg)

Vapor Pressure (Pa)

Log10Vp

40

313.15

0.003193358

0.81

8.100E-10

0.001124488

-2.949045360

41

314.15

0.003183193

1.11

1.110E-09

0.001540964

-2.812207400

42

315.15

0.003173092

1.06

1.060E-09

0.001471552

-2.832224513

43

316.15

0.003163056

1.05

1.050E-09

0.001457669

-2.836341080

44

317.15

0.003153082

1.09

1.090E-09

0.001513199

-2.820103881

45

318.15

0.003143171

1.37

1.370E-09

0.001901911

-2.720809812

46

319.15

0.003133323

0.94

9.400E-10

0.001304961

-2.884402525

47

320.15

0.003123536

0.64

6.400E-10

0.000888484

-3.051350405

48

321.15

0.003113810

1.46

1.460E-09

0.002026854

-2.693177523

49

322.15

0.003104144

1.48

1.480E-09

0.002054619

-2.687268663

50

323.15

0.003094538

1.52

1.520E-09

0.002110149

-2.675686791

 

 

No statistical analysis is given due to the nature of the plot


Figure3.3                  Run 7 - Graph of Log10Vapor Pressure vs Reciprocal Temperature

 

 


Run 9

Table 3.3 – Vapor Pressure Data

 

Temperature (ºC)

Temperature (K)

Reciprocal Temperature (K-1)

Mass Difference (µg)

Mass Difference (kg)

Vapor Pressure (Pa)

Log10Vp

40

313.15

0.003193358

0.69

6.900E-10

0.000957897

-3.018681288

41

314.15

0.003183193

0.44

4.400E-10

0.000610833

-3.214077702

42

315.15

0.003173092

0.88

8.800E-10

0.001221665

-2.913047707

43

316.15

0.003163056

1.45

1.450E-09

0.002012971

-2.696162376

44

317.15

0.003153082

0.61

6.100E-10

0.000846836

-3.072200544

45

318.15

0.003143171

1.39

1.390E-09

0.001929676

-2.714515578

46

319.15

0.003133323

1.40

1.400E-09

0.001943559

-2.711402343

47

320.15

0.003123536

0.75

7.500E-10

0.001041192

-2.982469115

48

321.15

0.003113810

0.60

6.000E-10

0.000832954

-3.079379128

49

322.15

0.003104144

1.44

1.440E-09

0.001999089

-2.699167887

50

323.15

0.003094538

1.88

1.880E-09

0.002609922

-2.583372529

 

 

No statistical analysis is given due to the nature of the plot


Run 10

Table 3.4 – Vapor Pressure Data

 

Temperature (ºC)

Temperature (K)

Reciprocal Temperature (K-1)

Mass Difference (µg)

Mass Difference (kg)

Vapor Pressure (Pa)

Log10Vp

40

313.15

0.003193358

0.78

7.800E-10

0.001082840

-2.965435776

41

314.15

0.003183193

1.57

1.570E-09

0.002179562

-2.661630726

42

315.15

0.003173092

0.93

9.300E-10

0.001291078

-2.889047430

43

316.15

0.003163056

1.15

1.150E-09

0.001596495

-2.796832538

44

317.15

0.003153082

0.79

7.900E-10

0.001096722

-2.959903287

45

318.15

0.003143171

0.85

8.500E-10

0.001180018

-2.928111453

46

319.15

0.003133323

1.50

1.500E-09

0.002082384

-2.681439120

47

320.15

0.003123536

1.43

1.430E-09

0.001985206

-2.702194341

48

321.15

0.003113810

1.27

1.270E-09

0.001763085

-2.753726658

49

322.15

0.003104144

1.48

1.480E-09

0.002054619

-2.687268663

50

323.15

0.003094538

2.42

2.420E-09

0.003359580

-2.473715013

 

 

No statistical analysis is given due to the nature of the plot

Please see Graphs of Log10Vapor Pressure vs Reciprocal Temperature for Runs 5, 7, 9 and 10 in Attachment 2.

 

Applicant's summary and conclusion

Conclusions:
Please see the Executive Summary for the Conclusion.
Executive summary:

The determination was carried out using a procedure designed to be compatible with Method A4 Vapour Pressure of Commission Regulation (EC) No 440/2008 of 30 May 2008 and Method 104 of the OECD Guidelines for Testing of Chemicals, 23 March 2006.

 

Instrument:                                               Vapor pressure balance.

Conclusion

The vapor pressure of the test item has been determined to be less than 1.4 x 10-3Pa at 25 ºC.