Registration Dossier
Registration Dossier
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EC number: 203-851-8 | CAS number: 111-26-2
Guidance on Safe Use
Administrative data
First-aid measures
4.1. Description of first aid measures
First aid personnel should pay attention to their own safety. If the patient is likely to become
unconscious, place and transport in stable sideways position (recovery position). Immediately
remove contaminated clothing.
If inhaled:
Keep patient calm, remove to fresh air, seek medical attention. Immediately administer a
corticosteroid from a controlled/metered dose inhaler.
On skin contact:
Immediately wash thoroughly with plenty of water, apply sterile dressings, consult a skin specialist.
On contact with eyes:
Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open,
consult an eye specialist.
On ingestion:
Immediately rinse mouth and then drink 200-300 ml of water, seek medical attention.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms: The most important known symptoms and effects are described in the labelling (see
section 2) and/or in section 11., Further symptoms are possible
4.3. Indication of any immediate medical attention and special treatment needed
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific
antidote.
Fire-fighting measures
5.1. Extinguishing media
Suitable extinguishing media:
water spray, dry powder, foam, carbon dioxide
5.2. Special hazards arising from the substance or mixture
nitrogen oxides, carbon oxides
The substances/groups of substances mentioned can be released in case of fire. Under certain
conditions in case of fire other hazardous combustion products may be generated.
5.3. Advice for fire-fighters
Special protective equipment:
Wear self-contained breathing apparatus and chemical-protective clothing.
Further information:
Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.
Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Avoid inhalation. Avoid contact with the skin, eyes and clothing.
6.2. Environmental precautions
Do not discharge into drains/surface waters/groundwater.
6.3. Methods and material for containment and cleaning up
For small amounts: Pick up with absorbent material (e.g. sand, sawdust, general-purpose binder).
For large amounts: Pick up with suitable appliance and dispose of.
Clean contaminated floors and objects thoroughly with water and detergents, observing
environmental regulations. Collect waste in suitable containers, which can be labeled and sealed.
Incinerate or take to a special waste disposal site in accordance with local authority regulations.
Handling and storage
7.1. Precautions for safe handling
Ensure thorough ventilation of stores and work areas. Product should be worked up in closed
equipment as far as possible. Handle in accordance with good industrial hygiene and safety practice.
When using do not eat, drink or smoke. Hands and/or face should be washed before breaks and at
the end of the shift.
Protection against fire and explosion:
Vapours may form explosive mixture with air. Take precautionary measures against static
discharges. Keep away from sources of ignition - No smoking.
7.2. Conditions for safe storage, including any incompatibilities
Segregate from acids and acid forming substances.
Further information on storage conditions: Containers should be stored tightly sealed in a dry place.
Keep container in a well-ventilated place. Avoid all sources of ignition: heat, sparks, open flame.
Storage stability:
Storage duration: 24 Months
Store at ambient temperature.
From the data on storage duration in this safety data sheet no agreed statement regarding the
warrantee of application properties can be deduced.
Transport information
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Marine transport (UN RTDG/IMDG)
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Exposure controls / personal protection
8.1. Control parameters
Components with occupational exposure limits
No occupational exposure limits known.
8.2. Exposure controls
Personal protective equipment
Respiratory protection:
Respiratory protection in case of vapour/aerosol release. Gas filter for gases/vapours of organic
compounds (boiling point >65 °C, e. g. EN 14387 Type A)
Hand protection:
Chemical resistant protective gloves (EN 374)
Suitable materials short-term contact and/or splashes (recommended: At least protective index 2,
corresponding > 30 minutes of permeation time according to EN 374)
nitrile rubber (NBR) - 0.4 mm coating thickness
butyl rubber (butyl) - 0.7 mm coating thickness
Manufacturer's directions for use should be observed because of great diversity of types.
Supplementary note: The specifications are based on tests, literature data and information of glove
manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g.
temperature) it must be considered, that the practical usage of a chemical-protective glove in
practice may be much shorter than the permeation time determined through testing.
Eye protection:
Tightly fitting safety goggles (cage goggles) (e.g. EN 166) and face shield.
Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting
boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case
of dust).
General safety and hygiene measures
Wearing of closed work clothing is required additionally to the stated personal protection equipment.
Handle in accordance with good industrial hygiene and safety practice. Avoid contact with the skin,
eyes and clothing. Avoid inhalation of vapour. Take off immediately all contaminated clothing. Store
work clothing separately.
Stability and reactivity
10.1. Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.
Formation of
flammable gases:
Remarks: Forms no flammable gases in the
presence of water.
10.2. Chemical stability
The product is stable if stored and handled as prescribed/indicated.
10.3. Possibility of hazardous reactions
Strong exothermic reaction with acids.
10.4. Conditions to avoid
Avoid extreme heat. Avoid sources of ignition.
10.5. Incompatible materials
Substances to avoid:
acids, acid anhydrides, oxidizing agents
10.6. Hazardous decomposition products
Possible thermal decomposition products:
carbon monoxide, Carbon dioxide
nitrogen oxides
Disposal considerations
13.1. Waste treatment methods
Incinerate in suitable incineration plant, observing local authority regulations.
A waste code in accordance with the European waste catalog (EWC) cannot be specified, due to
dependence on the usage.
The waste code in accordance with the European waste catalog (EWC) must be specified in
cooperation with disposal agency/manufacturer/authorities.
Contaminated packaging:
Contaminated packaging should be emptied as far as possible; then it can be passed on for
recycling after being thoroughly cleaned.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
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