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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Endpoint:
vapour pressure
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2008
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
other: guidance followed, no GLP

Data source

Referenceopen allclose all

Reference Type:
study report
Title:
Unnamed
Year:
2008
Report date:
2008
Reference Type:
study report
Title:
Unnamed
Year:
2008
Report date:
2008

Materials and methods

Test guideline
Qualifier:
according to guideline
Guideline:
OECD Guideline 104 (Vapour Pressure Curve)
Deviations:
no
GLP compliance:
no
Type of method:
static method

Test material

Constituent 1
Reference substance name:
Naphtha (coal), distn. residues
EC Number:
292-636-2
EC Name:
Naphtha (coal), distn. residues
Cas Number:
90641-12-6
Molecular formula:
Not applicable for UVCB substances
IUPAC Name:
1,2,3,4-tetrahydronaphthalene; 1,2-dihydroacenaphthylene; 1-methylnaphthalene; 2-methylnaphthalene; naphthalene

Results and discussion

Vapour pressureopen allclose all
Temp.:
ca. 79 °C
Vapour pressure:
ca. 1.16 kPa
Remarks on result:
other: measured value (first sample)
Temp.:
ca. 85 °C
Vapour pressure:
ca. 1.6 kPa
Remarks on result:
other: measured value (second sample)
Temp.:
ca. 20 °C
Vapour pressure:
ca. 61.5 Pa
Remarks on result:
other: estimated value
Temp.:
ca. 20 °C
Vapour pressure:
ca. 63.5 Pa
Remarks on result:
other: estimated value
Transition / decomposition
Transition / decomposition:
yes
Transition temp.:
ca. 30 °C

Any other information on results incl. tables

first sample (nehyzb):

Linear equation: log p = -2229.7*(1/T)+9.3948

Scope: from 72 to 235 °C

Accuracy: <10%

Nature of the change during measuring: none

Nature of the change for estimate: transition liquid-solid

Temperature of transition: <70°C

second sample (hyzb):

Linear equation: log p = -2292.6*(1/T)+9.6232

Scope: from 80 to 223 °C

Accuracy: <10%

Nature of the change during measuring: none

Nature of the change for estimate: transition liquid-solid

Temperature of transition: <50°C

Applicant's summary and conclusion

Conclusions:
The estimate values for 20°C do not take into account that there is a liquid-solid transition at cca 30°C. Real vapour pressure values for 20°C should be ten times lower. However these estimated values could be taken as worst case.