A mixture of: 2,2,6,6-tetramethylpiperidin-4-yl-hexadecanoate; 2,2,6,6-tetramethylpiperidin-4-yl-octadecanoate

Guidance on Safe Use

First-aid measures

Description of first aid measures

Remove contaminated or saturated clothing.

Inhalation

In case product dust is released:

Possible discomfort: irritation of mucous lining (nose, throat, eyes) cough, sneezing, flow of tears.

Move victims into fresh air.

If symptoms persist, consult a physician for treatment.

Skin contact

Wash off immediately with plenty of water.

If symptoms persist, consult a physician for treatment.

Eye contact

Keeping eyelid open, immediately rinse thoroughly for at least 5 minutes using plenty of water or, if necessary, eye rinsing solution.

Consult an ophthalmologist.

Ingestion

Have the mouth rinsed with water.

Have patient drink plenty of water in small sips.

Consult a physician immediately.

Indication of any immediate medical attention and special treatment needed

If required, therapy of irritative effect.

If substance has been swallowed:

Early endoscopy in order to assess mucosa lesions in the oesophagus and stomach which may appear. If necessary, aspirate leftover substance.

Fire-fighting measures

Suitable extinguishing media

Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Unsuitable extinguishing media

high volume water jet

Special hazards arising from the substance or mixture

In case of fire cool endangered containers with water.

In the case of fire, the following hazardous smoke fumes may be produced:

Carbon oxides

nitrogen oxides (NOx)

Special protective equipment for fire-fighters

In case of fire: full protective suit and wear a self contained respiratory apparatus

Advice for firefighters

Keep away from sources of ignition - No smoking.

With large-scale fire, violent decomposition or even explosion is possible.

Water used to extinguish fire should not enter drainage systems, soil, or stretches of water Ensure there are sufficient retaining facilities for water used to extinguish fire. Contaminated fire-extinguishing water must be disposed of in accordance with the regulations issued by the appropriate local authorities.

Fire residues should be disposed of in accordance with the regulations.

Accidental release measures

Personal precautions, protective equipment and emergency procedures

Wear personal protective equipment.

Keep unauthorized persons away.

Environmental precautions

Prevent product from entering drains.

Do not allow entrance in sewage water, soil or stretches of water.

Methods and material for containment and cleaning up

Pick up mechanically and collect in a suitable container. Avoid formation of dust.

Handling and storage

Handling

Precautions for safe handling

Observe the rules usually applicable when handling chemicals.

Wear personal protective equipment.

Advice on protection against fire and explosion

If dusts develop, explosive dust/air mixtures may form.

Avoid dust formation.

Storage

Conditions for safe storage, including any incompatibilities

Keep container away from flammable and explosive substances.

German storage class

11 - Combustible Solids

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:

3077

Shipping information

Proper shipping name and description:

Substituted oligomer on basis of amin

Chemical name:

Mixture of 2,2,6,6-tetramethylpiperidin-4-yl-hexadecaoate, 2,2,6,6-tetramethylpiperidin-4-yl-octadecanoate

Language:

English

Labels:

9

SpecialProvisions

Inland waterway transport (UN RTDG/ADN(R))

UN number:

3077

Shipping

Labels:

9

Remarks

Marine transport (UN RTDG/IMDG)

UN number:

3077

Shipping information

Proper shipping name and description:

Substituted oligomer on basis of amin

Chemical name:

Mixture of 2,2,6,6-tetramethylpiperidin-4-yl-hexadecaoate, 2,2,6,6-tetramethylpiperidin-4-yl-octadecanoate

Labels:

9

Marine pollutant

Remarks

Air transport (UN RTDG/ICAO/IATA)

UN number:

3077

Shipping information

Proper shipping name and description:

Substituted oligomer on basis of amin

Chemical name:

Mixture of 2,2,6,6-tetramethylpiperidin-4-yl-hexadecaoate, 2,2,6,6-tetramethylpiperidin-4-yl-octadecanoate

Labels:

9

Remarks

SpecialProvisions

Exposure controls / personal protection

Control parameters

Engineering measures

If possible, transfer and handle product in closed systems only. Avoid production of dust.

Provide sufficient air exchange and/or exhaust in work rooms.

Local exhaust as needed to control vapor/dust levels to below recommended limits and/or to prevent health and safety effects as indicated in section 3 and elsewhere on the MSDS.

Moisten dust residues with water, then remove them mechanically and dispose of them in suitable containers.

Personal protective equipment

Respiratory protection

In case product dust is released or if workplace exposure limit is exeeded:

use respiratory equipment with suitable filter (combined filter A2-P2) or wear a self contained respiratory apparatus

Do not breathe dust.

suitable respiratory equipment:

Dust protection mask in accordance with EN 149 FFP3

Note time limit for wearing respiratory protective equipment.

Hand protection

Recommendation:

suitable protective gloves

Glove material       nitrile rubber, The material thickness and rupture time data do not apply to non-solute solids / dusts., The rupture time and material thickness data are guideline values! Exact rupture time / material thickness data can be obtained from the protective glove manufacturer.

Eye protection

close-fitting protective goggles (e.g. closed goggles) or face protection

Keep eyewash bottle to hand

Provide for installation of emergency shower and eye bath.

Skin and body protection

Avoid contact with skin, eyes and clothing.

suitable protective clothing - Use disposable clothing if appropriate.

Hygiene measures

In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

In case of skin contact

Wash off with plenty of water and soap.

No eating, drinking, smoking, or snuffing tobacco at work. Wash face and/or hands before break and end of work.

Take off clothing and shoes contaminated with product. Clean before reuse.

Protective measures

The personal protective equipment used must meet the requirements of directive 89/686/EEC and amendments (CE certification).

Stability and reactivity

Conditions to avoid

Prevent the formation of dust.

Hazardous decomposition products

Decomposition products in combustion and thermal decomposition

carbon monoxide, carbon dioxide, nitrogen oxides (NOx)

Further information       

Stable under normal conditions.

hydrolysis with:

water

Disposal considerations

Product

No waste key number as per the European Waste Types List can be assigned to this product, since such classification is based on the (as yet undetermined) use to which the product is put by the consumer.

The waste key number must be determined as per the European Waste Types List (decision on EU Waste Types List 2000/532/EC) in cooperation with the disposal firm / producing firm / official authority.

Uncleaned packaging

With respect to local regulations, e.g.

dispose of to suitable waste incineration plant.