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Physical & Chemical properties

Vapour pressure

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Reference
Endpoint:
vapour pressure
Type of information:
experimental study
Adequacy of study:
key study
Study period:
April 25, 2019 to May 22, 2019
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.4 (Vapour Pressure)
Version / remarks:
European Community (EC), EC No. 761/2009, A.4: “Vapour Pressure”, 2009
Deviations:
no
Qualifier:
according to guideline
Guideline:
OECD Guideline 104 (Vapour Pressure Curve)
Version / remarks:
Organisation for Economic Co-operation and Development (OECD), OECD Guidelines for the Testing of Chemicals No. 104: “Vapour Pressure”, 2006
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Type of method:
effusion method: isothermal thermogravimetry
Specific details on test material used for the study:
No further details specified in the study report.
Key result
Temp.:
20 °C
Vapour pressure:
0 Pa

Weight loss of the test item in the temperature range of 150 °C to 180 °C

Temperature [°C]

1/T [K]

1000/T [K]

Weight loss [µg/min]

VT[/cm2/h]

Log VT

150

150

150

0.00236

0.00236

0.00236

2.36407

2.36407

2.36407

1.571

1.568

1.569

0.000189

0.000188

0.000188

-3.724643

-3.725473

-3.725196

160

160

160

0.00231

0.00231

0.00231

2.30947

2.30947

2.30947

3.101

3.147

3.130

0.000372

0.000378

0.000376

-3.429317

-3.422922

-3.425274

170

170

170

0.00226

0.00226

0.00226

2.25734

2.25734

2.25734

6.428

6.322

6.114

0.000771

0.000759

0.000734

-3.122743

-3.119964

-3.134493

180

180

180

0.00221

0.00221

0.00221

2.20751

2.20751

2.20751

12.54

12.48

12.41

0.001505

0.001498

0.001489

-2.822521

-2.824604

-2.827047

Estimation of VTand PT:

Log VT/at 20 °C

Log PT/at 20 °C

PT/at 20 °C

-9.7691273

-6.2602293

0.0000005

PT[Pa]/at 20 °C

5.49E-07

 

Values of log VTand log PTof the reference items

Reference Items

PT20 °C Literature/Pa

VT20 °C extrapolation

Water

Naphthalene

Hexachlorobenzene

Chrysene

2.34E+03

6.50E+00

1.45E-03

8.40E-07

3.10E-02

4.22E-04

4.43E-07

1.37E-10

 

Conclusions:
The isothermal thermogravimetrical effusion method was applied for the deter-mination of the vapour pressure of SynNova Base Oil™.
A value of the vapour pressure of the test item was determined using the data obtained between 150 °C and 180 °C. The vapour pressure of the test item was estimated to be 5.49e-7 Pa at 20 °C.
Executive summary:

SynNova Base Oil™: Determination of the Vapour Pressure by Iso-thermal Thermogravimetry.

The purpose of this study was to determine the vapour pressure of the test item using the isothermal thermogravimetrical effusion method.

This study was performed in a GLP accredited laboratory and designed to comply with the following methods:

European Community (EC), EC No. 761/2009, A.4: “Vapour Pressure”, 2009

Organisation for Economic Co-operation and Development (OECD), OECD Guidelines for the Testing of Chemicals No. 104: “Vapour Pressure”, 2006

 

The isothermal thermogravimetrical effusion method was applied for the determination of the vapour pressure of SynNova Base Oil™.

A value of the vapour pressure of the test item was determined using the data obtained between 150 °C and 180 °C. The vapour pressure of the test item was estimated to be 5.49 x 10-7 Pa at 20 °C.

Description of key information

The vapour pressure of the test item was estimated to be 5.49 x 10-7 Pa at 20 °C.

 

Key value for chemical safety assessment

Vapour pressure:
0 Pa
at the temperature of:
20 °C

Additional information

The isothermal thermogravimetrical effusion method was applied for the determination of the vapour pressure of SynNova Base Oil™.

A value of the vapour pressure of the test item was determined using the data obtained between 150 °C and 180 °C. The vapour pressure of the test item was estimated to be 5.49 x 10-7Pa at 20 °C.