Registration Dossier
Registration Dossier
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EC number: 237-399-8 | CAS number: 13770-92-8
Guidance on Safe Use
Guidance on Safe Use
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Administrative data
First-aid measures
4.1. Description of first aid measures
First aid personnel should pay attention to their own safety. Immediately remove contaminated
clothing.
If inhaled:
If difficulties occur after vapour/aerosol has been inhaled, remove to fresh air and seek medical
attention.
On skin contact:
After contact with skin, wash immediately with plenty of water and soap. Under no circumstances
should organic solvent be used. If irritation develops, seek medical attention.
On contact with eyes:
Wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an
eye specialist.
On ingestion:
Rinse mouth immediately and then drink plenty of water, seek medical attention. Do not induce
vomiting unless told to by a poison control center or doctor.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms: The most important known symptoms and effects are described in the labelling (see
section 2) and/or in section 11.
4.3. Indication of any immediate medical attention and special treatment needed
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific
antidote.
First aid personnel should pay attention to their own safety. Immediately remove contaminated
clothing.
If inhaled:
If difficulties occur after vapour/aerosol has been inhaled, remove to fresh air and seek medical
attention.
On skin contact:
After contact with skin, wash immediately with plenty of water and soap. Under no circumstances
should organic solvent be used. If irritation develops, seek medical attention.
On contact with eyes:
Wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an
eye specialist.
On ingestion:
Rinse mouth immediately and then drink plenty of water, seek medical attention. Do not induce
vomiting unless told to by a poison control center or doctor.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms: The most important known symptoms and effects are described in the labelling (see
section 2) and/or in section 11.
4.3. Indication of any immediate medical attention and special treatment needed
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific
antidote.
Fire-fighting measures
5.1. Extinguishing media
Suitable extinguishing media:
foam, water spray, dry powder, carbon dioxide
Unsuitable extinguishing media for safety reasons:
water jet
5.2. Special hazards arising from the substance or mixture
Carbon dioxide, carbon monoxide, harmful vapours, nitrogen oxides, fumes/smoke, carbon black
5.3. Advice for fire-fighters
Special protective equipment:
Wear a self-contained breathing apparatus.
Further information:
The degree of risk is governed by the burning substance and the fire conditions. If exposed to fire,
keep containers cool by spraying with water. Collect contaminated extinguishing water separately, do
not allow to reach sewage or effluent systems. Contaminated extinguishing water must be disposed
of in accordance with official regulations.
Suitable extinguishing media:
foam, water spray, dry powder, carbon dioxide
Unsuitable extinguishing media for safety reasons:
water jet
5.2. Special hazards arising from the substance or mixture
Carbon dioxide, carbon monoxide, harmful vapours, nitrogen oxides, fumes/smoke, carbon black
5.3. Advice for fire-fighters
Special protective equipment:
Wear a self-contained breathing apparatus.
Further information:
The degree of risk is governed by the burning substance and the fire conditions. If exposed to fire,
keep containers cool by spraying with water. Collect contaminated extinguishing water separately, do
not allow to reach sewage or effluent systems. Contaminated extinguishing water must be disposed
of in accordance with official regulations.
Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Do not breathe vapour/aerosol/spray mists. Wear eye/face protection. If exposed to high vapour
concentration, leave area immediately. Use personal protective clothing. Handle in accordance with
good building materials hygiene and safety practice.
6.2. Environmental precautions
Contain contaminated water/firefighting water. Do not discharge into drains/surface
waters/groundwater.
Page: 4/11
BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 25.06.2015 Version: 1.0
Product: Calciumdisulfamat Lösung 31% (SF)
(ID no. 717563/SDS_GEN_EU/EN)
Date of print 04.03.2018
6.3. Methods and material for containment and cleaning up
For small amounts: Pick up with inert absorbent material (e.g. sand, earth etc.). Dispose of
contaminated material as prescribed.
For large amounts: Pump off product.
6.4. Reference to other sections
Information regarding exposure controls/personal protection and disposal considerations can be
found in section 8 and 13.
Do not breathe vapour/aerosol/spray mists. Wear eye/face protection. If exposed to high vapour
concentration, leave area immediately. Use personal protective clothing. Handle in accordance with
good building materials hygiene and safety practice.
6.2. Environmental precautions
Contain contaminated water/firefighting water. Do not discharge into drains/surface
waters/groundwater.
Page: 4/11
BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 25.06.2015 Version: 1.0
Product: Calciumdisulfamat Lösung 31% (SF)
(ID no. 717563/SDS_GEN_EU/EN)
Date of print 04.03.2018
6.3. Methods and material for containment and cleaning up
For small amounts: Pick up with inert absorbent material (e.g. sand, earth etc.). Dispose of
contaminated material as prescribed.
For large amounts: Pump off product.
6.4. Reference to other sections
Information regarding exposure controls/personal protection and disposal considerations can be
found in section 8 and 13.
Handling and storage
7.1. Precautions for safe handling
Avoid aerosol formation. Avoid inhalation of mists/vapours. Avoid skin contact. No special measures
necessary provided product is used correctly.
7.2. Conditions for safe storage, including any incompatibilities
Further information on storage conditions: Keep only in the original container in a cool, dry, wellventilated
place away from ignition sources, heat or flame. Protect from direct sunlight.
Storage class according to TRGS 510 (originally VCI, Germany): (12) Non-combustible liquids.
Avoid aerosol formation. Avoid inhalation of mists/vapours. Avoid skin contact. No special measures
necessary provided product is used correctly.
7.2. Conditions for safe storage, including any incompatibilities
Further information on storage conditions: Keep only in the original container in a cool, dry, wellventilated
place away from ignition sources, heat or flame. Protect from direct sunlight.
Storage class according to TRGS 510 (originally VCI, Germany): (12) Non-combustible liquids.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- Not classified as a dangerous good under transport regulations
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SpecialProvisionsopen allclose all
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- Not classified as a dangerous good under transport regulations
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Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- Not classified as a dangerous good under transport regulations
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Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- Not classified as a dangerous good under transport regulations
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Remarksopen allclose all
SpecialProvisionsopen allclose all
Exposure controls / personal protection
8.1. Control parameters
Components with occupational exposure limits
No occupational exposure limits known.
8.2. Exposure controls
Personal protective equipment
Respiratory protection:
Wear respiratory protection if ventilation is inadequate. Combination filter for gases/vapours of
organic, inorganic, acid inorganic and alkaline compounds (e.g. EN 14387 Type ABEK).
Hand protection:
impermeable gloves
Synthetic rubber gloves
Manufacturer's directions for use should be observed because of great diversity of types.
Eye protection:
Safety glasses with side-shields (frame goggles) (e.g. EN 166)
Body protection:
light protective clothing
General safety and hygiene measures
Do not inhale gases/vapours/aerosols. Avoid contact with the skin, eyes and clothing. Avoid
exposure - obtain special instructions before use. Handle in accordance with good building materials
hygiene and safety practice. Wearing of closed work clothing is recommended. When using, do not
eat, drink or smoke. Hands and/or face should be washed before breaks and at the end of the shift.
At the end of the shift the skin should be cleaned and skin-care agents applied. Gloves must be
inspected regularly and prior to each use. Replace if necessary (e.g. pinhole leaks).
Components with occupational exposure limits
No occupational exposure limits known.
8.2. Exposure controls
Personal protective equipment
Respiratory protection:
Wear respiratory protection if ventilation is inadequate. Combination filter for gases/vapours of
organic, inorganic, acid inorganic and alkaline compounds (e.g. EN 14387 Type ABEK).
Hand protection:
impermeable gloves
Synthetic rubber gloves
Manufacturer's directions for use should be observed because of great diversity of types.
Eye protection:
Safety glasses with side-shields (frame goggles) (e.g. EN 166)
Body protection:
light protective clothing
General safety and hygiene measures
Do not inhale gases/vapours/aerosols. Avoid contact with the skin, eyes and clothing. Avoid
exposure - obtain special instructions before use. Handle in accordance with good building materials
hygiene and safety practice. Wearing of closed work clothing is recommended. When using, do not
eat, drink or smoke. Hands and/or face should be washed before breaks and at the end of the shift.
At the end of the shift the skin should be cleaned and skin-care agents applied. Gloves must be
inspected regularly and prior to each use. Replace if necessary (e.g. pinhole leaks).
Stability and reactivity
10.1. Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.
10.2. Chemical stability
The product is stable if stored and handled as prescribed/indicated.
10.3. Possibility of hazardous reactions
The product is stable if stored and handled as prescribed/indicated.
10.4. Conditions to avoid
See MSDS section 7 - Handling and storage.
10.5. Incompatible materials
Substances to avoid:
strong acids, strong bases, strong oxidizing agents, strong reducing agents
10.6. Hazardous decomposition products
No hazardous decomposition products if stored and handled as prescribed/indicated.
No hazardous reactions if stored and handled as prescribed/indicated.
10.2. Chemical stability
The product is stable if stored and handled as prescribed/indicated.
10.3. Possibility of hazardous reactions
The product is stable if stored and handled as prescribed/indicated.
10.4. Conditions to avoid
See MSDS section 7 - Handling and storage.
10.5. Incompatible materials
Substances to avoid:
strong acids, strong bases, strong oxidizing agents, strong reducing agents
10.6. Hazardous decomposition products
No hazardous decomposition products if stored and handled as prescribed/indicated.
Disposal considerations
13.1. Waste treatment methods
Observe national and local legal requirements.
Residues should be disposed of in the same manner as the substance/product.
Contaminated packaging:
Contaminated packaging should be emptied as far as possible; then it can be passed on for
recycling after being thoroughly cleaned.
Observe national and local legal requirements.
Residues should be disposed of in the same manner as the substance/product.
Contaminated packaging:
Contaminated packaging should be emptied as far as possible; then it can be passed on for
recycling after being thoroughly cleaned.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
