Registration Dossier

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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Endpoint:
auto-flammability
Type of information:
experimental study
Adequacy of study:
key study
Study period:
Experimental Starting Date: 30 September 2014 Experimental Completion Date: 22 October 2014
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: see 'Remark'
Remarks:
Study conducted in compliance with agreed protocols, with no or minor deviations from standard test guidelines and/or minor methodological deficiencies, which do not affect the quality of the relevant results. The study report was conclusive, done to a valid guideline and the study was conducted under GLP conditions.

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2014
Report date:
2014

Materials and methods

Test guideline
Qualifier:
according to guideline
Guideline:
EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
Deviations:
no
GLP compliance:
yes

Test material

Constituent 1
Reference substance name:
NACET00502
IUPAC Name:
NACET00502
Constituent 2
Reference substance name:
119464-63-0 (planar)
IUPAC Name:
119464-63-0 (planar)
Test material form:
other: Select the test material form from the drop-down list. If the form of the test chemical is not available in the list, select 'other:' and specify in the adjacent field. If the test material form is unknown, select 'no data'.
Details on test material:
Common/Commercial Name: NACET00502
Chemical Name: 3-methyl-5-((1R)-2,2,3-trimethylcyclopentyl)pentane-2-one
CAS Number: 119464-63-0 (planar)
Appearance/Physical State: Clear colorless liquid
Batch: S-13-11-1
Purity: 98.5%
Expiry Date: 24 December 2015
Storage Conditions: Room temperature in the dark

Results and discussion

Auto-ignition temperature (liquids / gases)
Auto-ignition temperature:
340 °C
Atm. press.:
>= 100 - <= 102 kPa
Remarks on result:
other:

Any other information on results incl. tables

Results

Results of the auto-ignition temperature determination are shown in the following table.

 

Table 3.2

 

Test Temperature (ºC)

Test Volume (µL)

Ignition Delay (s)

Observations

200 (clean flask)

70

>300

No ignition. Grey fumes were emitted.

250 (clean flask)

70

>300

No ignition. Grey fumes were emitted.

300 (clean flask)

70

>300

No ignition. Grey fumes were emitted.

350

70

2

A yellow flame. Grey fumes were emitted.

330 (clean flask)

70

>300

No ignition. Grey fumes were emitted.

340 (clean flask)

70

>300

No ignition. Grey fumes were emitted.

346

70

>300

No ignition. Grey fumes were emitted.

348 (clean flask)

70

3

A yellow flame. Grey fumes were emitted.

346 (clean flask)

70

>300

No ignition. Grey fumes were emitted.

346 (clean flask)

200

4

A yellow flame. Grey fumes were emitted.

344 (clean flask)

200

3

A yellow flame. Grey fumes were emitted.

330

200

>300

No ignition. Grey fumes were emitted.

340

200

1

A yellow flame. Grey fumes were emitted.

336

200

>300

No ignition. Grey fumes were emitted.

338 (clean flask)

200

>300

No ignition. Grey fumes were emitted.

338 (clean flask)

400

>300

No ignition. Grey fumes were emitted.

338 (clean flask)

600

>300

No ignition. Grey fumes were emitted.

338 (clean flask)

800

>300

No ignition. Grey fumes were emitted.

338 (clean flask)

1000

>300

No ignition. Grey fumes were emitted.

 

Room temperature: 18 to 20 °C
Atmospheric pressure: 100 to 102 kPa

Applicant's summary and conclusion

Conclusions:
The test item has been determined to have an auto-ignition temperature of 340 ± 5 °C.
Executive summary:
The determination was carried out using a procedure[1]designed to be compatible with Method A15 Auto-Ignition Temperature (Liquids and Gases) of Commission Regulation (EC) No 440/2008 of 30 May 2008.

 

Instrument:                                               Carbolite flask heater


[1]Based on, Anon (1987), Electrical Apparatus for Explosive Gas Atmospheres. Part 4: Method of Test for Ignition Temperature. IEC Publications79-4,P1-19.

Conclusion

The test item has been determined to have an auto-ignition temperature of 340±5 °C.