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Physical & Chemical properties

Auto flammability

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Reference
Endpoint:
auto-ignition temperature (liquids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
26 March 2018 to 27 March 2018
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Specific details on test material used for the study:
- Batch No.of test material: PFW160141
- Purity: 99.5%
- Expiration date of the lot/batch: 30 December 2018
- Stability under test conditions: Room temperature in the dark
Key result
Auto-ignition temperature:
188 °C
Atm. press.:
>= 98.7 - <= 100.4 kPa
Remarks on result:
other: room temperature: 17 - 18°C

Results of the auto-ignition temperature determination are shown in the following table:

Temperature (ºC)

Clean Flask (Yes/No)

Volume (µL)

Ignition Delay (s)

Observations

200

Yes

70

<1

A small blue flame. Grey fumes were emitted.

180

Yes

70

>300

No ignition. Grey fumes were emitted.

190

No

70

>300

No ignition. Grey fumes were emitted.

196

Yes

70

<1

A blue flame. Grey fumes were emitted.

194

Yes

70

1

A blue/orange flame. Grey fumes were emitted.

192

Yes

70

1

A blue/orange flame. Grey fumes were emitted.

190

Yes

70

1

A blue flame. Grey fumes were emitted.

186

Yes

70

>300

No ignition. Grey fumes were emitted.

188

Yes

70

1

A blue flame. Grey fumes were emitted.

186

Yes

200

>300

No ignition. Grey fumes were emitted.

186

Yes

400

>300

No ignition. Grey fumes were emitted.

186

Yes

600

>300

No ignition. Grey fumes were emitted.

186

Yes

800

>300

No ignition. Grey fumes were emitted.

186

Yes

1000

>300

No ignition. Grey fumes were emitted.

Room temperature:17 to 18°C
Atmospheric pressure: 98.7 to 100.4 kPa

Conclusions:
The test item has been determined to have an auto-ignition temperature of 188 ± 5 °C.

Description of key information

The test item has been determined to have an auto-ignition temperature of 188 ± 5 °C at an atmospheric pressure between 98.7 and 100.4 kPa in a GLP-compliant study according to EU A.15 (K1, Envigo, 2018).

Key value for chemical safety assessment

Additional information