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Diss Factsheets

Physical & Chemical properties

Oxidising properties

Currently viewing:

Administrative data

Endpoint:
oxidising solids
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
other: Guideline experimental study, not GLP compliant, minor restrictions in design and/or reporting but otherwise adequate for assessment

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2011
Report date:
2011

Materials and methods

Test guideline
Qualifier:
according to guideline
Guideline:
other: UN-Test O.1, UN Recommendations on the Transport of Dangerous Goods, Tests and Criteria, fifth revised edition, 2009.
GLP compliance:
no

Test material

Constituent 1
Reference substance name:
Platinum-(IV)-oxihydrate
IUPAC Name:
Platinum-(IV)-oxihydrate
Test material form:
other: Solid
Details on test material:
The test sample was technical grade (pure) - BAM code: 2.23/190811/01

Study design

Contact with:
powdered cellulose
Duration of test (contact time):
min

Results and discussion

Test results (Oxidising solids)open allclose all
Sample tested:
other: not specified (migrated information) Burning times
Parameter:
other: Burning times
Result:
>= 38 - <= 48 s
Remarks on result:
other: t1 result. 1:1 ratio of test item:cellulose (% by mass); Mean burning times of test mixture; 43.0 s, n = 5
Sample tested:
other: not specified (migrated information) Burning times
Parameter:
other: Burning times
Result:
>= 6 - <= 8 s
Remarks on result:
other: t2 result. 4:1 ratio of test item:cellulose (% by mass); Mean burning times of test mixture; 6.8 s, n = 5

Any other information on results incl. tables

Platinum-IV-oxihydrate (2.23/190811/01)

The sample was used as delivered. 

Mixture ratio sample : cellulose

[ by mass]

Burning time, t [s]

Mean burning time
[s]

 1:1     48.0  42.0  40.0  38.0  47.0  t1: 43.0   
Violent burn-off with yellow flames and formation of smoke
 4.1     7.0  6.0  6.0  7.0  8.0     t2: 6.8
 Violent burn-off with yellow flames and formation of smoke

 

Reference mixtures (measured 14 September 2011)

Ratios of potassium bromate : Cellulose
[by mass]

Burning time t [s]

Mean burning times
[s]

3:7

143.0

129.0

139.0

145.0

116.0

R1: 134,4

Burn-off with yellow flames

2:3

57.0

62.0

52.0

68.0

69.0

R2: 61.6

Violent burn-off with yellow flames

3:2

19.0

19.0

18.0

18.0

15.0

R3: 17.8

Violent burn-off with yellow flames

 

Applicant's summary and conclusion

Interpretation of results:
other: oxidising
Remarks:
Migrated information
Conclusions:
On the basis of the test results and according to the criteria specified in the Regulation (EC) No 1272/2008 (CLP-/GHS-Regulation) platinum dioxide is an oxidising solid of Category 1.
Executive summary:

This is a guideline experimental study and is not GLP compliant, but is otherwise adequate for assessment. On the basis of the test results and according to the criteria specified in the Regulation (EC) No 1272/2008 (CLP-/GHS-Regulation) platinum dioxide is an oxidising solid of Category 1.