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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Endpoint:
vapour pressure
Type of information:
experimental study
Adequacy of study:
key study
Study period:
26 - 28 Sep. 2017
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2017
Report date:
2017

Materials and methods

Test guidelineopen allclose all
Qualifier:
according to guideline
Guideline:
OECD Guideline 104 (Vapour Pressure Curve)
Qualifier:
according to guideline
Guideline:
EU Method A.4 (Vapour Pressure)
GLP compliance:
yes (incl. QA statement)
Remarks:
Hess. Ministerium für Umwelt, Klimaschutz, Landwirtschaft und Verbraucherschutz, Wiesbaden, Germany
Type of method:
effusion method: Knudsen cell

Test material

Constituent 1
Chemical structure
Reference substance name:
Oleic acid, compound with (Z)-octadec-9-enylamine (1:1)
EC Number:
248-813-1
EC Name:
Oleic acid, compound with (Z)-octadec-9-enylamine (1:1)
Cas Number:
28065-97-6
Molecular formula:
C34H69NO2 C36H67NO2 C36H69NO2 C36H71NO2 C36H73NO2
IUPAC Name:
oleic acid, compound with (Z)-octadec-9-enylamine (1:1)

Results and discussion

Vapour pressureopen allclose all
Test no.:
#1
Temp.:
20 °C
Vapour pressure:
0.001 Pa
Test no.:
#2
Temp.:
25 °C
Vapour pressure:
0.002 Pa
Test no.:
#3
Temp.:
50 °C
Vapour pressure:
0.013 Pa

Any other information on results incl. tables

The vapour pressure was measured in the temperature range of 60 °C to 120 °C. The measured vapour pressures at the corresponding temperatures are listed in the table 1. After the measurement a mass loss of aprrox. 74% (w/w) was determined.

Table 1 Measured vapour pressures and corresponding temperatures

Temperature / °C

Vapour pressure / hPa

60

1.7 x 10-4

70

5.6 x 10-4

80

1.3 x 10-3

90

1.6 x 10-3

100

2.1 x 10-3

110

3.4 x 10-3

120

6.5 x 10-3

 

The values for 20, 25 and 50 °C are calculated using the Antoine constants A, B and C as shown in Table 2.

Table 2 Antonie parameters and extrapolated vapour pressures

T/ °C

p / hPa

log (p/hPa) = A + B/(C+T[°C])

20

1.3 x 10-5

A = 5.68618

25

2.0 x 10-5

B = -3097.98

50

1.3 x 10-3

C = 273.15

Applicant's summary and conclusion