reaction product of cocoalkyldiethanolamides and cocoalkylmonoglycerides and molybdenumtrioxide (1.75-2.2: 0.75-1.0:0.1-1.1)

Boiling point

Link to relevant study record(s)

Reference

Endpoint:

boiling point

Type of information:

experimental study

Adequacy of study:

key study

Study period:

2 February 1997 to 19 March 1998

Reliability:

1 (reliable without restriction)

Rationale for reliability incl. deficiencies:

guideline study

Qualifier:

according to guideline

Guideline:

EU Method A.2 (Boiling Temperature)

Version / remarks:

1992

Deviations:

no

Qualifier:

according to guideline

Guideline:

other: ASTM E537-86

Deviations:

no

GLP compliance:

yes

Type of method:

differential scanning calorimetry

Specific details on test material used for the study:

Name: Molyvan® 855 (Oil-Free)
Description: Dark brown paste
Storage conditions: Room temperature in the dark

Boiling pt.:

> 633 K

Atm. press.:

102 kPa

Decomposition:

yes

Decomp. temp.:

365 K

As the test item decomposed prior to boiling, no value for the boiling temperature could be determined.

It is not possible to calculate a definitive boiling temperature from the data obtained in the vapour pressure study on the test item because only an estimate of the maximum vapour pressure was obtained. This is due to the test item being non-volatile and, as such, the vapour pressure study yielded a limit value. Based on these results and the chemical structure, the boiling temperature is estimated to be greater than 360 deg C (> 633 K).

A determination at reduced pressure was not performed as experience has shown that no further useful information is obtained for test materials of this nature which decompose prior to boiling at atmospheric pressure.

Data acquired by DSC:

Thermal event	Temperature
	Determination 1		Determination 2
	deg C	K	deg C	K
Onset of exotherm	91.4	365	98.3	371

Result: decomposed from approximately 365 K at 102 kPa, prior to any boiling.

Conclusions:

The test item decomposed from approximately 365 K at 102 kPa, prior to any boiling.

Executive summary:

In an EU Method A.2 study, conducted according to GLP, the test item decomposed from approximately 365 K at 102 kPa, prior to any boiling. Given the chemical structure(s) of the test item, the fact that the substance is non-volatile, and as such the vapour pressure study yielded a limit value, the boiling temperature is estimated to be greater than 360 deg C (> 633 K) (SafePharm Laboratories Limited, 1998).

Description of key information

Based on the chemical structure(s) of the test item, the fact that the substance is non-volatile, and as such the vapour pressure study yielded a limit value, the boiling temperature is estimated to be greater than 360 deg C (> 633 K).

Key value for chemical safety assessment

Boiling point at 101 325 Pa:

360 °C

Additional information

In an EU Method A.2 study, conducted according to GLP, the test item decomposed from approximately 365 K at 102 kPa, prior to any boiling. Given the chemical structure(s) of the test item, the fact that the substance is non-volatile, and as such the vapour pressure study yielded a limit value, the boiling temperature is estimated to be greater than 360 deg C (> 633 K) (SafePharm Laboratories Limited, 1998).