Registration Dossier
Registration Dossier
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EC number: 613-011-6 | CAS number: 62350-25-8
Guidance on Safe Use
Administrative data
First-aid measures
4 First aid measures
4.1 Description of first aid measurements:
• General advice:
Remove contaminated clothing even underwear and shoes immediately and wash before next use.
• After inhalation:
Ensure supply of fresh air. Store person in a position comfortable for breath. Summon a doctor immediately if feel unwell.
• After skin contact:
Wash immediately with plenty of soap and water. In case of persistent skin irritation get medical
advice.
• After eye contact:
Rinse opened eye several minutes with fluent water. Remove contact lenses if present and easy to
do.
Continue rinsing. In case of persistent complaints get medical advice.
• After swallowing:
Cause no vomit, rinse the mouth and drink plenty of water; get medical attention immediately.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms: The most known symptoms are described in the labelling and in chapter 11.
4.3 Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
Fire-fighting measures
5 Fire- fighting measures
5.1 Extinguishing agents: Water spray jet, alcohol resistant foam, ABC- powder or carbon dioxide.
Unsuitable extinguishing media: Water full jet.
5.2 Special hazards arising from the substance or mixture: Hazardous steam, smoke or mist.
A fire may form Carbon monoxide (CO), Carbon dioxide (CO2) and nitrogen oxides (NOx).
5.3 Advice for fire-fighters: Use self containing breathing apparatus, protective clothing and rubber
boots.
Do not breathe explosion or combustion gases. Cool down container with water spray jet.
Additional information: Contaminated fire water has to be disposed according to regional regulations.
Accidental release measures
6 Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures:
Use personal protection equipment. Provide for sufficient ventilation.
6.2 Environment precautions:
Do not allow to enter drains or waterways.
Inform respective authorities when entering in waters or the sewerage.
6.3 Methods and material for containment and cleaning- up:
Pick up mechanically with liquid binding materials (sand, kieselgur, wood shavings, universal binding
agent).
Dispose of absorbed material in accordance with the regional regulations.
6.4 Reference to other sections:
For further information on exposure monitoring and disposal see section 8 and 13.
Handling and storage
7 Handling and storage
7.1 Precautions for safe handling
Protective measures:
• Advice on safe handling: When used appropriately there are no further measures necessary.
• Fire preventions: When used appropriately there are no further measures necessary.
• Hygiene measures: Do not eat, drink and smoke when working. Wash hands before break and after
work.
• General safety measures: Don´t inhale aerosole, gas or dust. Avoid contact with skin.
• Environmental precautions: Avoid release to the environment.
7.2 Condition for safe storage, including any incompatibilities
• Technical matters and storage conditions:
Store only in well closed original container, in a cool, well- ventilated place.
• Packaging materials: PE
• Further information on storage rooms and vessels: -
Hints on storage assembly
• German storage class: 12
• Materials to avoid: Exothermal reaction with isocaynates.
7.3 Specific end use(s): No further recommendations (see chapter 1).
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- No dangerous goods according to transport regulations.
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SpecialProvisionsopen allclose all
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- No dangerous goods according to transport regulations.
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Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- No dangerous goods according to transport regulations.
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Air transport (UN RTDG/ICAO/IATA)
- UN number:
- No dangerous goods according to transport regulations.
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SpecialProvisionsopen allclose all
Exposure controls / personal protection
8 Exposure control/ Personal protection
8.1 Control parameter
8.1.1 Occupational exposure limits*
Ethanediol CAS-Nr. 107-21-1
Specification: Working place- air limit TRGS 900 (MAK- value): 10ml/m3 (ppm) / 26 mg/m3
Max. limit: Exceeding factor 2 (I)
Comment: H (scin resorptive), Y, DFG
Specification: Working place regulation: 2000/39/EG
Value: 8 h: 52mg/m3 # 20ppm; Short time: 104mg/m3 # 40ppm
Hint: skin
8.1.2 Biological limit values*
Contains no substances with biological values
8.1.3 Exposure limits at intended use*
No limits known
8.1.4 DNEL/ PNEC values
DNEL: No DNEL/DMEL/PNEC values on file
8.2 Limited and controlled exposition parameters
8.2.1 Appropriate engineering controls:
Ensure adequate ventilation. Provide suitable exhaust ventilation at the processing machines.
8.2.2 Personal safety equipment:
• General safety and hygiene measurements:
Avoid contact with eyes and skin. Don't eat and drink while working. Don´t smoke.
Breathing protection: In case of arise from steam/ aerosol use self containing breathing apparatus.
Hand protection: Glove material has to be impermeable and persistent for product/ mixture.
Choose glove material under observance of break time, permeation rate und degregation.
Glove material: Neopren, Butylkautschuk, Nitrilkautschuk following EN 374
Polychloropren -CR: Thickness > 0,5mm; Breakthrough time > 480 min
Nitrilkautschuk -NBR: Thickness > 0,35mm; Breakthrough time 480 min
Butylkautschuk -IIR: Thickness > 0,5mm; Breakthrough time > 480 min
Fluorkautschuk -FKM: Thickness > 0,4 mm; Breakthrough time > 480 min
Hint: Dispose contaminated gloves
Eye protection: Wear protection glasses
Body protection: One time clothing or chemistry kittle.
Protection gloves Protection glasses Protection clothing
8.2.3 Environmental exposure controls
No data available
Stability and reactivity
10 Stability and reactivity
10.1 Reactivity: No dangerous reactions if stored and handled appropriately.
10.2 Chemical stability:
• Thermal decomposition/ avoidable conditions:
Stable under appropriate conditions (see chapter 7). Avoid temperatures above boiling point.
10.3 Possibility of hazardous reactions: Reaction with isocyanates
10.4 Conditions to avoid: Temperatures above 1000C (see chapter 7)
10.5 Incompatible materials: Isocanates
10.6 Hazardous decomposition products: CO, CO2, NOx, NH3
Disposal considerations
13. Disposal considerations
13.1 Waste treatment methods:
• Product: In accordance with local authority regulations, take a special waste incineration plant.
• Contaminated packages:
If empty contaminated containers are recycled or disposed of, the receiver must be informed about
possible hazards.
Not contaminated packaging can be reused.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
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