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Diss Factsheets

Physical & Chemical properties

Surface tension

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Reference
Endpoint:
surface tension
Type of information:
experimental study
Adequacy of study:
key study
Study period:
From March 07, 2017 to March 15, 2018
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
guideline study with acceptable restrictions
Remarks:
non-GLP and not determined for 90% saturated solution as required by the Guideline
Qualifier:
according to guideline
Guideline:
OECD Guideline 115 (Surface Tension of Aqueous Solutions)
Deviations:
no
Qualifier:
according to guideline
Guideline:
EU Method A.5 (Surface Tension)
Deviations:
no
GLP compliance:
no
Remarks:
The study was conducted in a facility which operates in accordance with Good Laboratory Practice principles; however no claim of GLP compliance was intended nor is made for this study
Type of method:
ring method
Key result
Surface tension:
ca. 48 mN/m
Temp.:
20 °C
Conc.:
1 g/L

Results:

The readings and temperatures for the sample solutions are shown in the following tables:

Concentration (mg/L)

Reading (mN/m)

Temperature (°C)

1.011 x 104

40.5

20.0

38.0

20.0

38.0

20.0

38.0

20.0

3.034 x 103

45.0

20.0

44.0

20.0

44.0

20.0

44.0

20.0

1.011 x 103

49.0

20.0

48.0

20.0

48.0

20.0

48.0

20.0

303.4

54.0

20.0

52.5

20.0

52.0

20.0

52.0

20.0

52.0

20.0

101.1

58.0

20.0

56.5

20.0

56.5

20.0

58.5

20.0

59.0

20.0

59.0

20.0

61.0

20.0

60.0

20.0

60.0

20.0

60.0

20.0

30.34

61.0

20.0

61.0

20.0

61.0

20.0

10.11

66.5

20.0

65.5

20.0

68.0

20.0

67.0

20.0

67.0

20.0

67.0

20.0

3.034

71.5

20.0

69.5

20.0

70.5

20.0

69.5

20.0

69.5

20.0

69.5

20.0

1.011

72.5

20.0

70.5

20.0

70.5

20.0

70.5

20.0

Mean surface tension values were based on the last three readings for a particular concentration which were considered to be constant.

The concentration (mg/L), log10[concentration] and mean surface tension values for the sample solutions are shown in the following table:

Concentration
(mg/L)

Log10Concentration

Mean Surface Tension (mN/m)

Solution pH

1.011 x 104

4.005

38.0

5.71

3.034 x 103

3.482

44.0

5.40

1.011 x 103

3.005

48.0

5.17

303.4

2.482

52.0

5.09

101.1

2.005

60.0

4.85

30.34

1.482

61.0

5.24

10.11

1.005

67.0

5.44

3.034

0.482

69.5

5.57

1.011

0.005

70.5

5.84

The surface tension at 1 g/L was determined to be 48.0 ± 0.5mN/m.

Conclusions:
Under the study conditions, the surface tension of 1 g/L (nominal) aqeuous test concentration was determined to be 48.0 ± 0.5 mN/m at 20 ± 0.5ºC. Therefore, the test substance was considered to be surface-active
Executive summary:

A study was conducted to determine the surface tension of the test substance using ring method, according to OECD Guideline 115 and EU Method A.5. Under the study conditions, the surface tension of 1 g/L (nominal) aqeuous test concentration was determined to be 48.0 ± 0.5 mN/m at 20 ± 0.5ºC. Therefore, the test substance was considered to be surface-active (Envigo, 2018).

Description of key information

The surface tension of the test substance was determined using the ring method, according to OECD Guideline 115 and EU Method A.5 (Envigo, 2018).

Key value for chemical safety assessment

Surface tension:
48
in mN/m at 20°C and concentration in mg/L:
1 000

Additional information

(surface active)