Registration Dossier
Registration Dossier
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EC number: 200-774-1 | CAS number: 72-19-5
Guidance on Safe Use
Administrative data
First-aid measures
Description of first aid measures:
Inhalation:
In case product dust is released:
Possible discomfort: cough, sneezing.
Move victims into fresh air.
Skin contact:
No hazards which require special first aid measures.
Eye contact:
Possible discomfort is due to foreign substance effect.
Rinse thoroughly with plenty of water keeping eyelid open.
In case of persistent discomfort: Consult an ophthalmologist.
Ingestion:
Have the mouth rinsed with water.
After absorbing large amounts of substance.
Consult a physician.
Most important symptoms and effects, both acute and delayed:
Indication of any immediate medical attention and special treatment needed:
After absorbing large amounts of substance:
Acceleration of gastrointestinal passage.
Fire-fighting measures
Extinguishing media:
Suitable extinguishing media:
Water, mist, foam.
Unsuitable extinguishing media:
Quenching powder, carbon dioxide (CO2).
Special hazards arising from the substance or mixture:
In the case of fire, the following hazardous smoke fumes may be produced: carbon monoxide, carbon dioxide, nitric oxides, hydrocyanic acid.
In the event of fire and/or explosion do not breathe fumes.
Advice for firefighters:
Contaminated fire-extinguishing water must be disposed of in accordance with the regulations issued by the appropriate local authorities.
Fire residues should be disposed of in accordance with the regulations.
In the event of fire, wear self-contained breathing apparatus.
Accidental release measures
Accidental release measures:
Personal precautions, protective equipment and emergency procedures:
Wear personal protective equipment.
Keep unauthorized persons away.
Environmental precautions:
Do not allow the product into the following compartments: groundwater.
Methods and material for containment and cleaning up:
Absorb mechanically avoiding production of dust.
Reference to other sections:
Wear personal protective equipment.
Handling and storage
Precautions for safe handling:
Handle in accordance with good industrial hygiene and safety practices.
Conditions for safe storage, including any incompatibilities:
Advice on protection against fire and explosion:
Keep away from sources of ignition - No smoking.
Avoid dust formation.
VDI 2263 "Dust fires and dust explosions; dangers, evaluation, preventive measures."
Storage:
Store in a cool and shaded area.
Keep containers dry and tightly closed to avoid moisture absorption and contamination.
German storage class:
11 - Combustible Solids.
Dust explosion class:
St1 (method: VDI 3673, maximum rate of pressure rise: 66 bar/s, standardized max. rate of pressure increase, KSt: 66 bar x m/s).
Specific end use(s):
We are unaware of any specific end uses which go beyond the data reported.
Transport information
Land transport (UN RTDG/ADR/RID)
Shippingopen allclose all
Special provisions / remarks
- Remarks:
- Not classified as dangerous in the meaning of transport regulations.
Inland waterway transport (UN RTDG/ADN(R))
Shippingopen allclose all
Special provisions / remarks
- Remarks:
- Not classified as dangerous in the meaning of transport regulations.
Marine transport (UN RTDG/IMDG)
Shippingopen allclose all
Special provisions / remarks
- Remarks:
- Not classified as dangerous in the meaning of transport regulations.
Air transport (UN RTDG/ICAO/IATA)
Shippingopen allclose all
Special provisions / remarks
- Remarks:
- Not classified as dangerous in the meaning of transport regulations.
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Exposure controls / personal protection
Control parameters:
Exposure limit for dust:
Control parameters: 10 mg/m³
Exposure limit(s): (TRGS 900)
Type of exposure: Inhalable fraction.
General dust limiting value(s):
Suitable measuring processes are: BIA method 7284
Control parameters: 3 mg/m³
Exposure limit(s): (TRGS 900)
Type of exposure: As alveolar accessible part.
General dust limiting value(s):
Suitable measuring processes are: BIA method 6068, TRGS 901, Part II, Number 96, DIN EN 481
DNEL/DMEL values:
Remarks: No substance-related safety assessment is necessary / has been conducted for this product.
PNEC values:
Remarks: No substance-related safety assessment is necessary / has been conducted for this product.
Exposure controls:
Engineering measures:
Ensure suitable suction/aeration at the work place and with operational machinery.
Earthing of equipment.
Take precautionary measures against static discharges.
Personal protective equipment:
Respiratory protection:
If dust occurs: dust mask with P1 particle filter.
Hand protection:
Glove material Natural rubber (NR), for example, Cama Clean 708, Kächele-Cama Latex GmbH (KCL), Germany
Material thickness: 0.5 mm
Break through time: 8 h
Method: DIN EN 374.
Glove material Nitrile, for example, Dermatril 740, Kächele-Cama Latex GmbH (KCL), Germany
Material thickness: 0.11 mm
Break through time: 8 h
Method: DIN EN 374.
Eye protection:
Safety glasses.
Skin and body protection:
No special protective equipment required.
Hygiene measures:
Wash face and/or hands before break and end of work.
Cleanse and apply cream to skin after work.
Protective measures:
Handle in accordance with good industrial hygiene and safety practices.
If there is the possibility of skin/eye contact, the indicated hand/eye/body protection should be used.
Stability and reactivity
Reactivity:
No further information available.
Chemical stability:
Stable under recommended storage conditions.
Possibility of hazardous reactions:
Dust can form explosive mixtures with air.
Conditions to avoid:
See: Conditions for safe storage, including any incompatibilities.
Incompatible materials:
Avoid contact with oxidizing substances.
Hazardous decomposition products:
No hazardous decomposition products known.
Disposal considerations
Waste treatment methods:
Product:
Disposal according to local authority regulations.
Offer rinsed packaging material to local recycling facilities.
Waste Key Number:
The waste key number must be determined as per the European Waste Types List (decision on EU Waste Types List 2000/532/EC) in cooperation with the disposal firm / producing firm / official authority.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
