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Physical & Chemical properties

Flash point

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Reference
Endpoint:
flash point of flammable liquids
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2009-09-16 and 2009-12-29
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
other: Test procedure in accordance with national standard methods (ASTM) without GLP.
Qualifier:
according to guideline
Guideline:
ISO No., other: ASTM-D93 Standard Test Method for Flash Point by Pensky-Martens Closed Cup Tester
Deviations:
not specified
GLP compliance:
no
Type of method:
closed cup
Flash point:
ca. 149 °C
Atm. press.:
101.3 kPa
Remarks on result:
other: corrected to standard pressure

Measurement parameters:

Rotation speed of the sample stirrer: 100 rpm

Expected Flash point of the sample: 149.0 °C

Measurement:

Temperature of initial ignition source application: 130.0 °C / 130 °C

Atmosphreic pressure: 101.4 kPa / 103.0 kPa

Flash point (uncorrrected): 148.9 °C / 148.9 °C

Falsh point (corrected): 149.0 °C / 148.5 °C

Conclusions:
The flash point of Alfol 16- Alcohol was determined to be 149 °C at 101.3 kPa.
Executive summary:

The Flash point of Hexadecan-1-ol was determined according to ASTM-D93 Standard Test Methods for Flash Point by Pensky-Martens Closed Cup Tester. The flash point was measured in duplicate at 2 different days. The value for the corrected flash point was determined to be 149 °C.

Description of key information

The closed-cup flash point of hexadecan-1-ol is ca. 149°C (ASTM-D93).

Key value for chemical safety assessment

Flash point at 101 325 Pa:
149 °C

Additional information

The flash point of ca. 149°C was determined with the use of a closed-cup method in accordance with ASTM-D93. The result is considered to be reliable and is selected as key study.

A flash point value of 149°C and boiling point of 319°C indicate that hexadecan-1-ol should not be classified for flammability in accordance with Regulation (EC) No. 1272/2008.

Discussion of trends in the Category of C6-24 linear and essentially-linear aliphatic alcohols:

The flash point of Category substances follow a predictable trend of increasing flash point temperature with increasing chain length together with increasing boiling point and decreasing vapour pressure.