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Diss Factsheets

Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

4.1. Description of first aid measures

If inhaled:

Keep patient calm, remove to fresh air, seek medical attention.

On skin contact:

Wash thoroughly with soap and water.

On contact with eyes:

Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist.

On ingestion:

Rinse mouth immediately and then drink plenty of water, seek medical attention.

4.2. Most important symptoms and effects, both acute and delayed

Symptoms: Further important symptoms and effects are so far not known.

4.3. Indication of any immediate medical attention and special treatment needed

Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote.

Fire-fighting measures

5.1. Extinguishing media

Suitable extinguishing media:

water spray, dry powder, foam

5.2. Special hazards arising from the substance or mixture

harmful vapours

Evolution of fumes/fog. The substances/groups of substances mentioned can be released in case of fire.

5.3. Advice for fire-fighters

Special protective equipment:

Wear a self-contained breathing apparatus.

Further information:

The degree of risk is governed by the burning substance and the fire conditions. Contaminated extinguishing water must be disposed of in accordance with official regulations.

Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Use personal protective clothing. Breathing protection required.

6.2. Environmental precautions

Contain contaminated water/firefighting water. Do not discharge into drains/surface waters/groundwater.

6.3. Methods and material for containment and cleaning up

For large amounts: Pump off product.

For residues: Pick up with suitable absorbent material. Dispose of absorbed material in accordance with regulations.

Handling and storage

7.1. Precautions for safe handling

No special measures necessary provided product is used correctly.

Protection against fire and explosion:

Take precautionary measures against static discharges.

No physical hazards determined at this time. Handle this liquid with care and follow standard industrial practices.

7.2. Conditions for safe storage, including any incompatibilities

Further information on storage conditions: Keep container tightly closed and dry; store in a cool place.

Storage class according to TRGS 510 (originally VCI, Germany): (10) Combustible liquids

Transport information

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Marine transport (UN RTDG/IMDG)

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Exposure controls / personal protection

8.1. Control parameters

PNEC

freshwater: 0,001 mg/l

marine water: 0,0001 mg/l

intermittent release: 0,01 mg/l

STP: 1 mg/l

sediment (freshwater): 4,3572 mg/kg

sediment (marine water): 0,43572 mg/kg

soil: 0,868292 mg/kg

oral (secondary poisoning):

No PNEC oral derived, as accumulation in organisms is not to be expected.

DNEL

worker:

Long-term exposure- systemic effects, Inhalation: 0,59 mg/m3

worker:

Long- and short-term exposure - systemic effects, dermal: 0,08 mg/kg

consumer:

Long-term exposure- systemic effects, Inhalation: 0,04 mg/m3

consumer:

Long- and short-term exposure - systemic effects, dermal: 0,04 mg/kg

consumer:

Long- and short-term exposure - systemic effects, oral: 0,04 mg/kg

8.2. Exposure controls

Personal protective equipment

Respiratory protection:

Respiratory protection in case of vapour/aerosol release. Particle filter with medium efficiency for solid and liquid particles (e.g. EN 143 or 149, Type P2 or FFP2)

Hand protection:

Chemical resistant protective gloves (EN 374)

Suitable materials for short-term contact (recommended: At least protective index 2, corresponding > 30 minutes of permeation time according to EN 374)

butyl rubber (butyl) - 0.7 mm coating thickness

nitrile rubber (NBR) - 0.4 mm coating thickness

Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing.

Manufacturer's directions for use should be observed because of great diversity of types.

Eye protection:

Safety glasses with side-shields (frame goggles) (e.g. EN 166)

Body protection:

Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of dust).

General safety and hygiene measures

Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work clothing is required additionally to the stated personal protection equipment. No eating, drinking, smoking or tobacco use at the place of work. Handle in accordance with good industrial hygiene and safety practice.

Environmental exposure controls

For information regarding environmental exposure controls, see Section 6.

Stability and reactivity

10.1. Reactivity

No hazardous reactions if stored and handled as prescribed/indicated.

Corrosion to metals:

Corrosive effects to metal are not anticipated.

Formation of flammable gases:

Remarks:

Forms no flammable gases in the presence of water.

10.2. Chemical stability

The product is stable if stored and handled as prescribed/indicated.

10.3. Possibility of hazardous reactions

No hazardous reactions when stored and handled according to instructions.

10.4. Conditions to avoid

Avoid open flames.

10.5. Incompatible materials

10.6. Hazardous decomposition products

Hazardous decomposition products:

No hazardous decomposition products known.

Disposal considerations

13.1. Waste treatment methods

Must be disposed of or incinerated in accordance with local regulations.

Contaminated packaging:

Uncontaminated packaging can be re-used.

Packs that cannot be cleaned should be disposed of in the same manner as the contents.