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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Endpoint:
relative self-ignition temperature (solids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
31July2018-24Dec2018
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2018
Report date:
2018

Materials and methods

Test guideline
Qualifier:
according to guideline
Guideline:
other: UN N.4
Deviations:
no
GLP compliance:
yes

Test material

Constituent 1
Chemical structure
Reference substance name:
2-[[4-(dimethylamino)phenyl]azo]-1,3-dimethyl-1H-imidazolium chloride
EC Number:
278-601-4
EC Name:
2-[[4-(dimethylamino)phenyl]azo]-1,3-dimethyl-1H-imidazolium chloride
Cas Number:
77061-58-6
Molecular formula:
C13H18N5.Cl
IUPAC Name:
2-[[4-(dimethylamino)phenyl]azo]-1,3-dimethyl-1H-imidazolium chloride
Test material form:
solid: particulate/powder
Details on test material:
Batch 1054934
Specific details on test material used for the study:
Identification: Basic red 51
Batch (Lot) Number: 1054934 or 1086207
Expiry date: 29 November 2020 (expiry date) (batch 1054934) or 29 May 2023 (expiry date) (batch 1086207)
Physical Description: Violet powder

Results and discussion

Relative self-ignition temperature (solids)
Key result
Remarks on result:
no self ignition observed under the test conditions

Any other information on results incl. tables

A negative result was obtained. No spontaneous ignition occurred and no exothermic effect of the test item was observed. It demonstrated that the test item is “not a self-heating substance”. According to the UN guideline, no further testing is required.

After the experiment, the consistency of the sample was unchanged, i.e. no reaction and/or decomposition of the test item was observed.

Applicant's summary and conclusion

Conclusions:
Self-heating of Basic red 51 was determined in accordance with UN Test N.4 “Test Method for Self-heating Substances”.

From the negative result obtained at 140°C using a 10 cm sample cube, it was concluded that Basic red 51 is not a self-heating substance.
Executive summary:

The test item was exposed to air at 140°C using a temperature controlled laboratory oven, a cubic stainless steel wire 10 cm sample container, NiCr/Ni thermocouples and a temperature recording device.

A negative result was obtained. No spontaneous ignition occurred and no exothermic effect of the test item was observed. It demonstrated that the test item is “not a self-heating substance”. According to the UN guideline, no further testing is required.

After the experiment, the consistency of the sample was unchanged, i.e. no reaction and/or decomposition of the test item was observed.

Conclusion

Self-heating of Basic red 51 was determined in accordance with UN Test N.4 “Test Method for Self-heating Substances”.

From the negative result obtained at 140°C using a 10 cm sample cube, it was concluded that Basic red 51 is not a self-heating substance.