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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Endpoint:
surface tension
Type of information:
experimental study
Adequacy of study:
key study
Study period:
Study plan dated : 25 may 2018 and experimental completion date 05 jun 2018
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2018
Report date:
2019

Materials and methods

Test guidelineopen allclose all
Qualifier:
according to guideline
Guideline:
OECD Guideline 115 (Surface Tension of Aqueous Solutions)
Deviations:
no
Qualifier:
according to guideline
Guideline:
EU Method A.5 (Surface Tension)
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Type of method:
plate method

Test material

Constituent 1
Chemical structure
Reference substance name:
Allyltributylphosphonium chloride
EC Number:
216-231-7
EC Name:
Allyltributylphosphonium chloride
Cas Number:
1530-48-9
Molecular formula:
C15H32P.Cl
IUPAC Name:
tributyl(prop-2-en-1-yl)phosphanium chloride
impurity 1
Chemical structure
Reference substance name:
Tetrahydrothiophene 1,1-dioxide
EC Number:
204-783-1
EC Name:
Tetrahydrothiophene 1,1-dioxide
Cas Number:
126-33-0
Molecular formula:
C4H8O2S
IUPAC Name:
tetrahydrothiophene 1,1-dioxide
impurity 2
Chemical structure
Reference substance name:
Tributyl-1-propen-1-yl-phosphonium chloride
Molecular formula:
C15H32P.Cl
IUPAC Name:
Tributyl-1-propen-1-yl-phosphonium chloride
Test material form:
other: solid : wax like
Details on test material:
Homogeneity : homogeneous if totally melted
Note: For every use the test item was completely melted and the melted test item
was used for the test.
Specific details on test material used for the study:
Test Item
Designation in Test Facility: 18032901G
Date of Receipt: 29. Mar. 2018
Condition at Receipt Room temperature, in proper conditions
Homogeneity homogeneous if totally melted
Vapour pressure <0.1 hPa at 30 °C
Stability in solvents H2O: unknown; EtOH: unknown; acetone: unknown;
CH3CN: unknown; DMSO: unknown
Solubility in solvents H2O: > 1 g/L; EtOH: unknown; acetone: unknown;
CH3CN: unknown; DMSO: unknown
Expiry date 17. Oct. 2019
Storage Room Temperature (20 ± 5°C)

Results and discussion

Surface tension
Key result
Surface tension:
ca. 67.39 mN/m
Temp.:
20 °C
Conc.:
1 g/L

Applicant's summary and conclusion

Conclusions:
The values of the single determinations show no significant difference (2.00% between
mean values of the two measurement series). All measured values lay above the threshold
for surface tension which is stated in the guidelines.
The surface tension of the negative control was determined with a difference of 0.01 %
from the stated literature value.
Therefore, the result of the test is considered valid and the test item
Allyltributylphosphonium chloride is classified as “not surface active” in a concentration
of 1.00 g/L.
Executive summary:

The surface tension of an aqueous solution of Allyltributylphosphonium chloride was determined

as 67.39 ± 0.12 mN/m at 19.9 °C. One measurement was performed for verification

(after 59 minutes). No significant changes and thus no significant dependence on time

was observed.

As these values were higher than 60 mN/m, Allyltributylphosphonium chloride was classified

as

not surface active.

The surface tension of the negative control lay within the accepted range.