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Physical & Chemical properties

Auto flammability

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Endpoint:
auto-ignition temperature (liquids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
15 September 2003 to 16 September 2003
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: Study performed in accordance with EU test guidelines in compliance with GLP.
Qualifier:
according to guideline
Guideline:
EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
Deviations:
not specified
Qualifier:
according to guideline
Guideline:
other: DIN 51794 "Bestimmung der Zündtemperatur", January 1978.
Deviations:
not specified
Qualifier:
according to guideline
Guideline:
other: IEC standard 79-4 "Electrical apparatus for explosive gas atmospheres, Part 4, Method of test for igniton temperature", 1975.
Deviations:
not specified
GLP compliance:
yes
Key result
Auto-ignition temperature:
395 °C
Atm. press.:
1 028.8 hPa

Preliminary test: Starting at 186°C and testing every 20°C, a flame was observed at 439°C.

Going down from 439°C and testing every 5°C, an auto-ignition temperature of 405°C was determined.

 

Main study: The lowest measured auto-ignition temperature was 397°C at an injection volume of 85 µl and with a time lag of 10 s. Rounded down to the nearest 5°C gives the auto-ignition temperature for Hatcol 2352: 395°C.

The atmospheric pressure was 1028.8 hPa during the preliminary test and Test 1. The atmospheric pressure was 1025.4 hPa during Test 2 and Test 3.

 

Determination of the auto-ignition (main study)

Test

Auto-ignition Temperature [°C]

Injection volume [µl]

Time lag [s]

Test 1

408

30

9

403

70

10

403

100

10

416

150

11

Test 2

405

30

8

397

85

10

404

125

12

Test 3

411

30

7

404

85

11

417

150

13

 

Conclusions:
In conclusion, Hatcol 2352 is auto-ignitable with an auto-ignition temperature of 395°C.
Executive summary:

The determination of the auto-ignition temperature of Hatcol 2352 was performed in accordance with EEC-Directive 92/69 EEC, A.15 "Auto-Ignition temperature (liquids and gases, 1992)", DIN 51794 "Bestimmung der Zündtemperatur" (1978) and IEC standard 79-4: Method of test for ignition temperature (1975).

Test substance was injected into a test vessel at a temperature range between 186°C and 439°C.

The test was performed in triplicate.

The lowest measured auto-ignition temperature was 397°C at an injection volume of 85 µl.

Rounded down to the nearest 5°C gives the auto-ignition temperature for Hatcol 2352: 395°C.

 

In conclusion, Hatcol 2352 is auto-ignitable with an auto-ignition temperature of 395°C.

Endpoint:
auto-ignition temperature (liquids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
11 to 12 August 2003
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: Study performed in accordance with EU test guidelines in compliance with GLP
Qualifier:
according to guideline
Guideline:
EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
Deviations:
not specified
GLP compliance:
yes
Key result
Auto-ignition temperature:
405 °C
Atm. press.:
1 020.3 hPa

Preliminary test

Starting at 186°C and testing every 20°C, a flame was observed at 419°C.

Going down from 434°C and testing every 5°C, an auto-ignition temperature of 409°C was determined.

 

Main study

The lowest measured auto-ignition temperature was 407°C at an injection volume of 100 µl (Test 1) and at an injection volume of 150 µl (Test 2), each time with a time lag of 12 s.

Rounded down to the nearest 5°C gives the auto-ignition temperature for Hatcol 3331: 405°C.

The atmospheric pressure was 1020.3 hPa during all tests.

 

Summary of the results of the main study

Test number

Auto-ignition Temperature [°C]

Injection volume [µl]

Time lag [s]

Test 1

409

70

14

407

100

12

421

150

11

Test 2

413

70

12

407

150

12

417

200

10

Test 3

414

70

12

411

150

11

413

200

11

 

Conclusions:
Hatcol 3331 is auto-ignitable with an auto-ignition temperature of 405°C.
Executive summary:

The determination of the auto-ignition temperature of Hatcol 3331 was performed in accordance with EEC-Directive 92/69 EEC, A.15 "Auto-Ignition temperature (liquids and gases, 1992)", DIN 51794 "Bestimmung der Zündtemperatur" (1978) and IEC standard 79-4: Method of test for ignition temperature (1975).

Test substance was injected into a test vessel at a temperature range between 186°C and 434°C.

The test was performed in triplicate.

The lowest measured auto-ignition temperature was 407°C at injection volumes of 100 µl and150 µl.

Rounded down to the nearest 5°C gives the auto-ignition temperature for Hatcol 3331: 405°C.

In conclusion, Hatcol 3331 is auto-ignitable with an auto-ignition temperature of 405°C.

Endpoint:
auto-ignition temperature (liquids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
22 to 23 October 2002
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: Study performed in accordance with EU test guidelines in compliance with GLP.
Qualifier:
according to guideline
Guideline:
EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
Deviations:
not specified
GLP compliance:
yes
Key result
Auto-ignition temperature:
415 °C
Atm. press.:
> 989 - < 991.7 hPa

Summary of the results of the main study

Test number

Auto-ignition Temperature [°C]

Injected volume [µl]

Time lag

Test 1

418

416

423

70

100

150

07

07

09

Test 2

423

418

421

50

100

175

08

07

06

Test 3

422

418

419

50

100

150

08

08

09

 

Conclusions:
Hatcol 334 is auto-ignitable, with an auto-ignition temperature of 415°C.
Executive summary:

The determination of the auto-ignition temperature of Hatcol 3344 was performed in accordance with EEC-Directive 92/69 EEC, A.15 "Auto-Ignition temperature (liquids and gases, 1992)", DIN 51794 "Bestimmung der Zündtemperatur" (1978) and IEC standard 79-4: Method of test for ignition temperature (1975).

Test substance was injected into a test vessel at a temperature range between 200°C and 443°C. The test was performed in triplicate.

A lowest auto-ignition temperature of 416°C was found, with an injection volume of 100 µI.

In conclusion, Hatcol 3344 is auto-ignitable with an auto-ignition temperature of 415°C.

Endpoint:
auto-ignition temperature (liquids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
25 to 26 August 2003
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: Study performed in accordance with EU test guidelines in compliance with GLP.
Qualifier:
according to guideline
Guideline:
EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
Deviations:
not specified
GLP compliance:
yes
Key result
Auto-ignition temperature:
395 °C
Atm. press.:
> 1 017.3 - < 1 020.3 hPa

Preliminary test

Starting at 186°C and testing every 20°C. a flame was observed at419°C.

Going down from 434°C and testing every 5°C, an auto-ignition temperature of 400°C was determined.

 

Main study

The lowest measured auto-ignition temperature was 399°C at an injection volume of 85 µl and with a time lag of 12 s. Rounded down to the nearest 5°C gives the auto-ignition temperature for Hatcol 5236: 395°C.

The atmospheric pressurewas 1020.3 hPa during the preliminary test and Test 1. The atmospheric pressure was 1017.3 hPa during Test 2 and Test 3.

Conclusions:
Hatcol 5236 is auto-ignitable with an auto-ignition temperature of 395°C.
Executive summary:

The determination of the auto-ignition temperature of Hatcol 5236 was performed in accordance with EEC-Directive 92/69 EEC. A.15 "Auto-Ignition temperature (liquids and gases, 1992)",DIN 51794 "Bestimmung der Zündtemperatut' (1978) and IEC standard 79-: Method of test for ignition temperature (1975).

Test substance was injected into a test vessel at a temperature range between 186°C and 434°C.

The test was performed in triplicate.

The lowest measured auto-ignition temperature was 399°C at an injection volume of 85 µl.

Rounded down to the nearest 5°C gives the auto-ignition temperature for Hatcol 5236: 395°C.

In conclusion, Hatcol 5236 is auto-ignitable with an auto-ignition temperature of 395°C.

Description of key information

Result provided using EU Method A15.

Key value for chemical safety assessment

Autoflammability / Self-ignition temperature at 101 325 Pa:
395 °C

Additional information

HATCOL 2352

Test substance was injected into a test vessel at a temperature range between 186°C and 439°C. The test was performed in triplicate.

The lowest measured auto-ignition temperature was 397°C at an injection volume of 85 µl.

Rounded down to the nearest 5°C gives the auto-ignition temperature for Hatcol 2352: 395°C.

In conclusion, Hatcol 2352 is auto-ignitable with an auto-ignition temperature of 395°C.

 

HATCOL 3331

Test substance was injected into a test vessel at a temperature range between 186°C and 434°C. The test was performed in triplicate.

The lowest measured auto-ignition temperature was 407°C at injection volumes of 100 µl and150 µl.

Rounded down to the nearest 5°C gives the auto-ignition temperature for Hatcol 3331: 405°C.

In conclusion, Hatcol 3331 is auto-ignitable with an auto-ignition temperature of 405°C.

 

HATCOL 3344

Test substance was injected into a test vessel at a temperature range between 200°C and 443°C. The test was performed in triplicate.

A lowest auto-ignition temperature of 416°C was found, with an injection volume of 100 µI.

In conclusion, Hatcol 3344 is auto-ignitable with an auto-ignition temperature of 415°C.

 

HATCOL 5236

Test substance was injected into a test vessel at a temperature range between 186°C and 434°C. The test was performed in triplicate.

The lowest measured auto-ignition temperature was 399°C at an injection volume of 85 µl.

Rounded down to the nearest 5°C gives the auto-ignition temperature for Hatcol 5236: 395°C.

In conclusion, Hatcol 5236 is auto-ignitable with an auto-ignition temperature of 395°C.